3 research outputs found
Tris(1,10-phenanthroline)iron(II) ÎĽ-oxido-bisÂ[trichloridoferrate(III)]
In the title salt, [Fe(C12H8N2)3][Fe2Cl6O], the ionic components are linked into a two-dimensional supraÂmolecular layer by two pairs of C—Hâ‹ŻCl hydrogen bonds and π–π stacking interÂactions [centroid–centroid distances = 3.655 (4) and 3.498 (3) Å]. The salt is characterized as a mixed-valent FeII–FeIII compound, in which an FeII atom is coordinated by three phen ligands, forming a six-coordinated cationic entity and the anionic part is formed by two FeIII atoms in tetraÂhedral coordination environments constructed by three chloride ions and one bridging oxide ligand. IntraÂmolecular C—Hâ‹ŻN hydrogen bonds are observed