Spectrum, Volume 19, Number 6

Highlights include: Mock accident hosted to rise awareness of drunk driving -- Urban Latino magazine founder visits SHU -- Beautification day scheduled to clean up ad unify SHU -- Computer issues causing backup in the printing lab -- All Saint\u27s day and Hallow\u27s Eve have intricate histories -- Men\u27s soccer falls 1-7 to Fairleigh Dickinson -- Woman\u27s rugby take second place title in championship -- Pioneers trample Iona 49-

Pathway to achieve negative CO2 emissions - combining biomass with CCS

The urgency to stabilize the global temperature rise at 1.5°C as highlighted in Paris COP21 and the IPCC Fifth Assessment Report calls for solutions that can remove CO2 from the atmosphere. The ability of carbon negative processes to offset historic emissions and emissions across different sectors is also highlighted in recent scenarios by IEA and WEC. Achieving negative CO2 emissions by removing CO2 from the atmosphere is possible by applying carbon capture in processes utilizing biomass (bio-CCS). Biomass has the capability of withdrawing and storing atmospheric CO2. As a result, CO2 released during biomass thermo-chemical conversion can be captured and stored permanently underground, thus depriving the atmosphere of CO2. The objective of this paper is to assess different deployment opportunities of bio-CCS from GHG emissions and plant economy point of view; to evaluate what is the best way to use constrained biomass resources by assessing the effects that raw materials types, different processes and end products have on carbon stocks and on the overall GHG mitigation from the global point of view. It also describes an implementation pathway incorporating bio-CCU processes as an intermediate step towards low carbon societies in 2050. Bio-CCU applications, incorporating power-to-gas (P2G) and RES boosted hybrid processes as intermediate steps for fully carbon neutral energy supply are seen as a critical bridging technology in business wise deployment pathway. These technologies also have an essential role in bringing new aspects to the sustainability and greenhouse gas impact discussions as biomass, despite being a globally evenly distributed and renewable raw material, is in the end also a constrained resource that should be utilised in the most reasoned applications taking into account all aspects of sustainability. There are three major biomass conversion routes where bio-CCS is applicable; biochemical conversion (fermentation and hydrolysis), thermo-chemical conversion (e.g. gasification and combustion) and industrial processes. In addition to ethanol fermentation the thermo-chemical biomass conversion processes are considered the first-phase targets for applying capture of CO2, both from a logistic and cost point of view. A concrete example on how more thorough deployment of bio-CCS could penetrate in near-term markets is given as a Finnish bio-CCS roadmap with scenarios highlighting the major bottlenecks and constrains. The roadmap assessment is based on power plant, industrial plant and emission database calculations with future projections on existing installations. In this paper a deployment pathway to a low carbon society is described and discussed. The potential technologies for bio-CCS and bio-CCU are introduced with the feasibility of the solutions compared both from the sustainability and cost point of view

Techno-economic evaluation of retrofitting CCS in an integrated pulp and board mill - Case studies

Urgently reducing global greenhouse gas emissions (GHG) could be achieved by carbon sinks or negative emissions, i.e. removing CO2 from the atmosphere and offsetting historical CO2 emissions. Negative emissions can be achieved when CO2 is captured from processes based on biomass feedstock (bio-CCS). Biomass withdraws atmospheric CO2 through natural processes such as the photosynthesis. Capturing and permanently storing this CO2 away from the natural carbon cycle enables a withdrawal of CO2 from the atmosphere. Sustainable growth and harvest of biomass resources is critical to achieve carbon negativity and to allow for sound biomass regrowth. As a result, bio-CCS provides a potential mitigation tool to reduce the CO2 concentration in the atmosphere. The pulp and paper industry is one of the potential candidates for large scale demonstration of bio-CCS and industrial CCS application. In Europe, the pulp and paper industry is the largest user and producer of biomass energy, contributing to around 60% of the biomass based electricity and heat production. There are three main sources of CO2 emissions in the pulp and paper production (via Kraft pulping process): (1.) the Kraft recovery boiler, (2.) the lime kiln and (3.) the multi-fuel boiler (bark boiler). Typically, over 90% of CO2 emissions from a pulp mill are of biogenic origin as fossil fuel is used only for firing the lime kiln. The main function of the recovery boiler is to recover the spent cooking chemicals from the black liquor for reuse in wood chips cooking and the combustion of the organic matter in the black liquor to produce heat for steam and electricity generation. The lime kiln is part of the chemical recycle loop and this includes the calcination of the lime mud (mainly calcium carbonate) to produce CaO that is used in the recovery of the cooking chemicals (i.e. processing of the green liquor). As a result, the lime kiln produces a flue gas with high concentration of CO2. The multi-fuel boiler is typically used to burn any wood waste and residue biomass (i.e. bark and bio-sludge) from the pulp production to produce steam used in the process and for power production. This study addresses the operational costs, capital investment costs and technical aspects of retrofitting a modern Kraft market pulp mill with a split flow post-combustion CO2 capture based on amine absorption. The pulp production units and the CO2 capture units are presented with detailed mass and energy balances. Two types of mills were evaluated; i) Stand-alone pulp mill producing 800 000 adt of softwood pulp annually and ii) Integrated pulp and board mill producing 740 000 adt of softwood pulp and 400 000 3-ply folding boxboard annually. Annual CO2 emissions are 2.1 Mt CO2/a. Six different cases were studied for each mill type; CO2 capture from the three individual point sources and three combinations of these. The implementation of a post-combustion CO2 capture process requires additional steam for the amine reboiler and additional power input for pumps and compressors. In some cases the excess power production at the pulp mill may be sufficient to support the integration of a CO2 capture plant. In other cases an additional auxiliary boiler is required. The split flow MEA-based capture process enables a reduction in the heat duty for the CO2 stripper reboiler. The average reboiler duty was calculated to around 2.7 – 2.8 MJ/kg captured CO2. Steam is provided from the steam turbine island. A major focal point of the study was to investigate the optimal extraction of steam and condensate return. Most pulp and paper mills are self-sufficient with electricity and produce excess electricity that is exported to the local/national grid. 90% CO2 capture was assumed for all cases, but in future evaluations partial CO2 capture might prove more viable, depending on the amount of excess steam or electricity available at the mill. This is also affected by the price of electricity, price of emission allowances and any renewable energy subsidies/incentives. Capturing biogenic CO2 could potentially create additional revenues for the mill operator, depending on whether the emission of biogenic CO2 would be accounted for as negative CO2 emissions in emission allowance trading schemes. As a result, accounting for negative CO2 emissions could potentially be a low-hanging fruit and lead to demonstration or large scale industrial business cases for the implementation of CCS in the near future