Really Cool Stars and the Star Formation History at the Galactic Center

We present R=550 to 1200 near infrared H and K spectra for a magnitude limited sample of 79 asymptotic giant branch and cool supergiant stars in the central ~ 5 pc (diameter) of the Galaxy. We use a set of similar spectra obtained for solar neighborhood stars with known Teff and Mbol that is in the same range as the Galactic center (GC) sample to derive Teff and Mbol for the GC sample. We then construct the Hertzsprung--Russell (HRD) diagram for the GC sample. Using an automated maximum likelihood routine, we derive a coarse star formation history of the GC. We find (1) roughly 75% of the stars formed in the central few pc are older than 5 Gyr; (2) the star formation rate (SFR) is variable over time, with a roughly 4 times higher star formation rate in the last 100 Myr compared to the average SFR; (3) our model can only match dynamical limits on the total mass of stars formed by limiting the IMF to masses above 0.7 M$_\odot$. This could be a signature of mass segregation or of the bias toward massive star formation from the unique star formation conditions in the GC; (4) blue supergiants account for 12 % of the total sample observed, and the ratio of red to blue supergiants is roughly 1.5; (5) models with isochrones with [Fe/H] = 0.0 over all ages fit the stars in our HRD better than models with lower [Fe/H] in the oldest age bins, consistent with the finding of Ramirez et al. (2000) that stars with ages between 10 Myr and 1 Gyr have solar [Fe/H].Comment: ApJ, accepted. Latex, 65 pages including 19 figure

First principles structures and circular dichroism spectra for the close-packed and the 7/2 motif of collagen

The recently proposed close-packed motif for collagen is investigated using first principles semi-empirical wave function theory and Kohn-Sham density functional theory. Under these refinements the close-packed motif is shown to be stable. For the case of the 7/2 motif a similar stability exists. The electronic circular dichroism of the close-packed model has a significant negative bias and a large signal. An interesting feature of the close-packed structure is the existence of a central channel. Simulations show that, if hydrogen atoms are placed in the cavity, a chain of molecular hydrogens is formed suggesting a possible biological function for molecular hydrogen.Comment: 12 pages, 3 figures; 3(PPG)_6 xyz file attached; v2: minor modification

Bright tripartite entanglement in triply concurrent parametric oscillation

We show that a novel optical parametric oscillator, based on concurrent $\chi^{(2)}$ nonlinearities, can produce, above threshold, bright output beams of macroscopic intensities which exhibit strong tripartite continuous-variable entanglement. We also show that there are {\em two} ways that the system can exhibit a new three-mode form of the Einstein-Podolsky-Rosen paradox, and calculate the extra-cavity fluctuation spectra that may be measured to verify our predictions.Comment: title change, expanded intro and discussion of experimental aspects, 1 new figure. Conclusions unaltere

Quantum field effects in coupled atomic and molecular Bose-Einstein condensates

This paper examines the parameter regimes in which coupled atomic and molecular Bose-Einstein condensates do not obey the Gross-Pitaevskii equation. Stochastic field equations for coupled atomic and molecular condensates are derived using the functional positive-P representation. These equations describe the full quantum state of the coupled condensates and include the commonly used Gross-Pitaevskii equation as the noiseless limit. The model includes all interactions between the particles, background gas losses, two-body losses and the numerical simulations are performed in three dimensions. It is found that it is possible to differentiate the quantum and semiclassical behaviour when the particle density is sufficiently low and the coupling is sufficiently strong.Comment: 4 postscript figure

SIGAME simulations of the [CII], [OI] and [OIII] line emission from star forming galaxies at z ~ 6

Of the almost 40 star forming galaxies at z>~5 (not counting QSOs) observed in [CII] to date, nearly half are either very faint in [CII], or not detected at all, and fall well below expectations based on locally derived relations between star formation rate (SFR) and [CII] luminosity. Combining cosmological zoom simulations of galaxies with SIGAME (SImulator of GAlaxy Millimeter/submillimeter Emission) we have modeled the multi-phased interstellar medium (ISM) and its emission in [CII], [OI] and [OIII], from 30 main sequence galaxies at z~6 with star formation rates ~3-23Msun/yr, stellar masses ~(0.7-8)x10^9Msun, and metallicities ~(0.1-0.4)xZsun. The simulations are able to reproduce the aforementioned [CII]-faintness at z>5, match two of the three existing z>~5 detections of [OIII], and are furthermore roughly consistent with the [OI] and [OIII] luminosity relations with SFR observed for local starburst galaxies. We find that the [CII] emission is dominated by the diffuse ionized gas phase and molecular clouds, which on average contribute ~66% and ~27%, respectively. The molecular gas, which constitutes only ~10% of the total gas mass is thus a more efficient emitter of [CII] than the ionized gas making up ~85% of the total gas mass. A principal component analysis shows that the [CII] luminosity correlates with the star formation activity as well as average metallicity. The low metallicities of our simulations together with their low molecular gas mass fractions can account for their [CII]-faintness, and we suggest these factors may also be responsible for the [CII]-faint normal galaxies observed at these early epochs.Comment: 24 pages, 14 figures. Accepted for publication in the Astrophysical Journa

Thermodynamic properties of Pb determined from pressure-dependent critical-field measurements

We have carried out extensive low-temperature (1.5 to 10 K) measurements of the critical field, $H_c$, for the element Pb up to a pressure of $P=1.2$ GPa. From this data the electronic entropy, specific heat, thermal expansion coefficient and compressibility is calculated as a function of temperature, pressure and magnetic field. The zero-field data is consistent with direct thermodynamic measurements and the $P$-dependence of $T_c$ and specific heat coefficient, $\gamma(T,P)$ allows the determination of the $P$-dependence of the pairing interaction.Comment: 5 pages, 6 figures, in press Phys. Rev.

Delta Self-Consistent Field as a method to obtain potential energy surfaces of excited molecules on surfaces

We present a modification of the $\Delta$SCF method of calculating energies of excited states, in order to make it applicable to resonance calculations of molecules adsorbed on metal surfaces, where the molecular orbitals are highly hybridized. The $\Delta$SCF approximation is a density functional method closely resembling standard density functional theory (DFT), the only difference being that in $\Delta$SCF one or more electrons are placed in higher lying Kohn-Sham orbitals, instead of placing all electrons in the lowest possible orbitals as one does when calculating the ground state energy within standard DFT. We extend the $\Delta$SCF method by allowing excited electrons to occupy orbitals which are linear combinations of Kohn-Sham orbitals. With this extra freedom it is possible to place charge locally on adsorbed molecules in the calculations, such that resonance energies can be estimated. The method is applied to N$_2$, CO and NO adsorbed on different metallic surfaces and compared to ordinary $\Delta$SCF without our modification, spatially constrained DFT and inverse-photoemission spectroscopy (IPES) measurements. This comparison shows that the modified $\Delta$SCF method gives results in close agreement with experiment, significantly closer than the comparable methods. For N$_2$ adsorbed on ruthenium (0001) we map out a 2-dimensional part of the potential energy surfaces in the ground state and the 2$\pi$-resonance. Finally we compare the $\Delta$SCF approach on gas-phase N$_2$ and CO, to higher accuracy methods. Excitation energies are approximated with accuracy close to that of time-dependent density functional theory, and we see very good agreement in the minimum shift of the potential energy surfaces in the excited state compared to the ground state.Comment: 11 pages, 7 figure