82 research outputs found
Quantum Correlations in Multipartite Quantum Systems
We review some concepts and properties of quantum correlations, in particular
multipartite measures, geometric measures and monogamy relations. We also
discuss the relation between classical and total correlationsComment: to be published as a chapter of the book "Lectures on general quantum
correlations and their applications" edited by F. Fanchini, D. Soares-Pinto,
and G. Adesso (Springer, 2017
Structure and mechanism of acetolactate decarboxylase
Acetolactate decarboxylase catalyzes the conversion of both enantiomers of acetolactate to the (R)-enantiomer of acetoin, via a mechanism that has been shown to involve a prior rearrangement of the non-natural (R)-enantiomer substrate to the natural (S)-enantiomer. In this paper, a series of crystal structures of ALDC complex with designed transition state mimics are reported. These structures, coupled with inhibition studies and site-directed mutagenesis provide an improved understanding of the molecular processes involved in the stereoselective decarboxylation/protonation events. A mechanism for the transformation of each enantiomer of acetolactate is proposed
Conditions for the freezing phenomena of geometric measure of quantum discord for arbitrary two-qubit X states under non-dissipative dephasing noises
We study the dynamics of geometric measure of quantum discord (GMQD) under
the influences of two local phase damping noises. Consider the two qubits
initially in arbitrary X-states, we find the necessary and sufficient
conditions for which GMQD is unaffected for a finite period. It is further
shown that such results also hold for the non-Markovian dephasing process.Comment: 4 pages, 2 figure
Geometric measure of quantum discord and total quantum correlations in a N-partite quantum state
Quantum discord, as introduced by Olliver and Zurek [Phys. Rev. Lett.
\textbf{88}, 017901 (2001)], is a measure of the discrepancy between quantum
versions of two classically equivalent expressions for mutual information and
is found to be useful in quantification and application of quantum correlations
in mixed states. It is viewed as a key resource present in certain quantum
communication tasks and quantum computational models without containing much
entanglement. An early step toward the quantification of quantum discord in a
quantum state was by Dakic, Vedral, and Brukner [Phys. Rev. Lett. 105,190502
(2010)] who introduced a geometric measure of quantum discord and derived an
explicit formula for any two-qubit state. Recently, Luo and Fu [Phys. Rev. A
\textbf{82}, 034302 (2010)] introduced a generic form of the geometric measure
of quantum discord for a bipartite quantum state. We extend these results and
find generic forms of the geometric measure of quantum discord and total
quantum correlations in a general N-partite quantum state. Further, we obtain
computable exact formulas for the geometric measure of quantum discord and
total quantum correlations in a N-qubit quantum state. The exact formulas for
the -qubit quantum state are experimentally implementable.Comment: 18 pages, 3 figure
Geometric global quantum discord
Geometric quantum discord, proposed by Dakic, Vedral, and Brukner [Phys. Rev.
Lett. 105 (2010) 190502], is an important measure for bipartite correlations.
In this paper, we generalize it to multipartite states, we call the generalized
version geometric global quantum discord (GGQD). We characterize GGQD in
different ways, and provide some special states which allow analytical GGQD.Comment: 8 pages,no figure;added a lower bound for GGQD to version
Dynamics of multipartite quantum correlations under decoherence
Quantum discord is an optimal resource for the quantification of classical
and non-classical correlations as compared to other related measures. Geometric
measure of quantum discord is another measure of quantum correlations.
Recently, the geometric quantum discord for multipartite states has been
introduced by Jianwei Xu [arxiv:quant/ph.1205.0330]. Motivated from the recent
study [Ann. Phys. 327 (2012) 851] for the bipartite systems, I have
investigated global quantum discord (QD) and geometric quantum discord (GQD)
under the influence of external environments for different multipartite states.
Werner-GHZ type three-qubit and six-qubit states are considered in inertial and
non-inertial settings. The dynamics of QD and GQD is investigated under
amplitude damping, phase damping, depolarizing and flipping channels. It is
seen that the quantum discord vanishes for p>0.75 in case of three-qubit GHZ
states and for p>0.5 for six qubit GHZ states. This implies that multipartite
states are more fragile to decoherence for higher values of N. Surprisingly, a
rapid sudden death of discord occurs in case of phase flip channel. However,
for bit flip channel, no sudden death happens for the six-qubit states. On the
other hand, depolarizing channel heavily influences the QD and GQD as compared
to the amplitude damping channel. It means that the depolarizing channel has
the most destructive influence on the discords for multipartite states. From
the perspective of accelerated observers, it is seen that effect of environment
on QD and GQD is much stronger than that of the acceleration of non-inertial
frames. The degradation of QD and GQD happens due to Unruh effect. Furthermore,
QD exhibits more robustness than GQD when the multipartite systems are exposed
to environment.Comment: 15 pages, 4 figures, 4 table
Predominance of entanglement of formation over quantum discord under quantum channels
We present a study of the behavior of two different figures of merit for
quantum correlations, entanglement of formation and quantum discord, under
quantum channels showing how the former can, counterintuitively, be more
resilient to such environments spoiling effects. By exploiting strict
conservation relations between the two measures and imposing necessary
constraints on the initial conditions we are able to explicitly show this
predominance is related to build-up of the system-environment correlations.Comment: 7 pages, 5 figures, RevTeX
Difference in expression between AQP1 and AQP5 in porcine endometrium and myometrium in response to steroid hormones, oxytocin, arachidonic acid, forskolin and cAMP during the mid-luteal phase of the estrous cycle and luteolysis
BACKGROUND: Recently, we demonstrated in vitro that AQP1 and AQP5 in the porcine uterus are regulated by steroid hormones (P4, E2), arachidonic acid (AA), forskolin (FSK) and cAMP during the estrous cycle. However, the potential of the porcine separated uterine tissues, the endometrium and myometrium, to express these AQPs remains unknown. Thus, in this study, the responses of AQP1 and AQP5 to P4, E2 oxytocin (OT), AA, FSK and cAMP in the porcine endometrium and myometrium were examined during the mid-luteal phase of the estrous cycle and luteolysis.METHODS: Real-time PCR and western blot analysis.RESULTS: Progesterone up-regulated the expression of AQP1/AQP5 mRNAs and proteins in the endometrium and myometrium, especially during luteolysis. Similarly, E2 also stimulated the expression of both AQPs, but only in the endometrium. AA led to the upregulation of AQP1/AQP5 in the endometrium during luteolysis. In turn, OT increased the expression of AQP1/AQP5 mRNAs and proteins in the myometrium during mid-luteal phase. Moreover, a stimulatory effect of forskolin and cAMP on the expression of AQP1/AQP5 mRNAs and proteins in the endometrium and myometrium dominated during luteolysis, but during the mid-luteal phase their influence on the expression of these AQPs was differentiated depending on the type of tissue and the incubation duration.CONCLUSIONS: These results seem to indicate that uterine tissues; endometrium and myometrium, exhibit their own AQP expression profiles in response to examined factors. Moreover, the responses of AQP1/AQP5 at mRNA and protein levels to the studied factors in the endometrium and myometrium are more pronounced during luteolysis. This suggests that the above effects of the studied factors are connected with morphological and physiological changes taking place in the pig uterus during the estrous cycle.</p
Flexibility of a biotinylated ligand in artificial metalloenzymes based on streptavidin—an insight from molecular dynamics simulations with classical and ab initio force fields
In the field of enzymatic catalysis, creating activity from a non catalytic scaffold is a daunting task. Introduction of a catalytically active moiety within a protein scaffold offers an attractive means for the creation of artificial metalloenzymes. With this goal in mind, introduction of a biotinylated d6-piano-stool complex within streptavidin (SAV) affords enantioselective artificial transfer-hydrogenases for the reduction of prochiral ketones. Based on an X-ray crystal structure of a highly selective hybrid catalyst, displaying significant disorder around the biotinylated catalyst [η6-(p-cymene)Ru(Biot-p-L)Cl], we report on molecular dynamics simulations to shed light on the protein–cofactor interactions and contacts. The results of these simulations with classical force field indicate that the SAV-biotin and SAV-catalyst complexes are more stable than ligand-free SAV. The point mutations introduced did not affect significantly the overall behavior of SAV and, unexpectedly, the P64G substitution did not provide additional flexibility to the protein scaffold. The metal-cofactor proved to be conformationally flexible, and the S112K or P64G mutants proved to enhance this effect in the most pronounced way. The network of intermolecular hydrogen bonds is efficient at stabilizing the position of biotin, but much less at fixing the conformation of an extended biotinylated ligand. This leads to a relative conformational freedom of the metal-cofactor, and a poorly localized catalytic metal moiety. MD calculations with ab initio potential function suggest that the hydrogen bonds alone are not sufficient factors for full stabilization of the biotin. The hydrophobic biotin-binding pocket (and generally protein scaffold) maintains the hydrogen bonds between biotin and protein
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