384 research outputs found
Monte Carlo Study of Relaxor Systems: A Minimum Model for Pb(InNb)O}
We examine a simple model for Pb(InNb)O (PIN), which
includes both long-range dipole-dipole interaction and random local anisotropy.
A improved algorithm optimized for long-range interaction has been applied for
efficient large-scale Monte Carlo simulation. We demonstrate that the phase
diagram of PIN is qualitatively reproduced by this minimum model. Some
properties characteristic of relaxors such as nano-scale domain formation, slow
dynamics and dispersive dielectric responses are also examined.Comment: 5 pages, 4 figure
Neutron Diffraction Study of Field Cooling Effects on Relaxor Ferroelectrics Pb[(Zn_{1/3} Nb_{2/3})_{0.92} Ti_{0.08}] O_{3}
High-temperature (T) and high-electric-field (E) effects on Pb[(Zn_{1/3}
Nb_{2/3})_{0.92} Ti_{0.08}]O_3 (PZN-8%PT) were studied comprehensively by
neutron diffraction in the ranges 300 <= T <= 550 K and 0 <= E <= 15 kV/cm. We
have focused on how phase transitions depend on preceding thermal and
electrical sequences. In the field cooling process (FC, E parallel [001] >= 0.5
kV/cm), a successive cubic (C) --> tetragonal (T) --> monoclinic (M_C)
transition was observed. In the zero field cooling process (ZFC), however, we
have found that the system does not transform to the rhombohedral (R) phase as
widely believed, but to a new, unidentified phase, which we call X. X gives a
Bragg peak profile similar to that expected for R, but the c-axis is always
slightly shorter than the a-axis. As for field effects on the X phase, we found
an irreversible X --> M_C transition via another monoclinic phase (M_A) as
expected from a previous report [Noheda et al. Phys. Rev. Lett. 86, 3891
(2001)]. At a higher electric field, we confirmed a c-axis jump associated with
the field-induced M_C --> T transition, which was observed by strain and x-ray
diffraction measurements.Comment: 8 pages, 9 figures, revise
Mott gap excitations in twin-free YBa2Cu3O7-d (Tc = 93 K) studied by RIXS
Mott gap excitations in the high-Tc superconductor of the optimal doped
YBa2Cu3O7-d (Tc = 93 K) have been studied by the resonant inelastic x-ray
scattering method. Anisotropic spectra in the ab-plane are observed in a
twin-free crystal. The excitation from the one-dimensional CuO chain is
enhanced at 2 eV near the zone boundary of the b* direction, while the
excitation from the CuO2 plane is broad at 1.5-4 eV and almost independent of
the momentum transfer. Theoretical calculation based on the one-dimensional and
two-dimensional Hubbard model reproduces the observed spectra by taking the
different parameters of the on-site Coulomb energy. The fact of the Mott gap of
the CuO chain site is much smaller than that of CuO2 plane site is observed for
the first time
Resonant inelastic x-ray scattering study of hole-doped manganites La1-xSrxMnO3 (x=0.2 and 0.4)
Electronic excitations near the Fermi energy in the hole doped manganese
oxides (La1-xSrxMnO3, x=0.2 and 0.4) have been elucidated by using the resonant
inelastic x-ray scattering (RIXS) method. A doping effect in the strongly
correlated electron systems has been observed for the first time. The
scattering spectra show that a salient peak appears in low energies indicating
the persistence of the Mott gap. At the same time, the energy gap is partly
filled by doping holes and the energy of the spectral weight shifts toward
lower energies. The excitation spectra show little change in the momentum space
as is in undoped LaMnO3, but the scattering intensities in the low energy
excitations of x=0.2 are anisotropic as well as temperature dependent, which
indicates a reminiscence of the orbital nature
NâSubstituted Nipecotic Acids as (S )âSNAPâ5114 Analogues with Modified Lipophilic Domains
Potential mGAT4 inhibitors derived from the lead substance (S )âSNAPâ5114 have been synthesized and characterized for their inhibitory potency. Variations from the parent compound included the substitution of one of its aromatic 4âmethoxy and 4âmethoxyphenyl groups, respectively, with a more polar moiety, including a carboxylic acid, alcohol, nitrile, carboxamide, sulfonamide, aldehyde or ketone function, or amino acid partial structures. Furthermore, it was investigated how the substitution of more than one of the aromatic 4âmethoxy groups affects the potency and selectivity of the resulting compounds. Among the synthesized test substances (S )â1â{2â[(4âformylphenyl)bis(4âmethoxyphenyl)âmethoxy]ethyl}piperidineâ3âcarboxylic acid, that features a carbaldehyde function in place of one of the aromatic 4âmethoxy moieties of (S )âSNAPâ5114, was found to have a pIC50 value of 5.89±0.07, hence constituting a slightly more potent mGAT4 inhibitor than the parent substance while showing comparable subtype selectivity
Polarization-analyzed resonant inelastic x-ray scattering of the orbital excitations in KCuF3
We report a Cu K-edge resonant inelastic x-ray scattering (RIXS) study of
orbital excitations in KCuF3 . By performing the polarization analysis of the
scattered photons, we disclose that the excitation between the eg orbitals and
the excitations from t2g to eg exhibit distinct polarization dependence. The
polarization dependence of the respective excitations is interpreted based on a
phenomenological consideration of the symmetry of the RIXS process that yields
a necessary condition for observing the excitations. In addition, we show that
the orbital excitations are dispersionless within our experimental resolution.Comment: 5 pages, 3 figure
Symmetry of high-piezoelectric Pb-based complex perovskites at the morphotropic phase boundary I. Neutron diffraction study on Pb(Zn1/3Nb2/3)O3 -9%PbTiO3
The symmetry was examined using neutron diffraction method on
Pb(Zn1/3Nb2/3)O3 -9%PbTiO3 (PZN/9PT) which has a composition at the
morphotropic phase boundary (MPB) between Pb(Zn1/3Nb2/3)O3 and PbTiO3. The
results were compared with those of other specimens with same composition but
with different prehistory. The equilibrium state of all examined specimens is
not the mixture of rhombohedral and tetragonal phases of the end members but
exists in a new polarization rotation line Mc# (orthorhombic-monoclinic line).
Among examined specimens, one exhibited tetragonal symmetry at room temperature
but recovered monoclinic phase after a cooling and heating cycle
X-ray anomalous scattering investigations on the charge order in -NaVO
Anomalous x-ray diffraction studies show that the charge ordering in
-NaVO is of zig-zag type in all vanadium ladders. We
have found that there are two models of the stacking of layers along
\emph{c-}direction, each of them consisting of 2 degenerated patterns, and that
the experimental data is well reproduced if the 2 patterns appears
simultaneously. We believe that the low temperature structure contains stacking
faults separating regions corresponding to the four possible patterns.Comment: Submitted to Phys. Rev. Lett., 4 pages, 4 eps figures inserted in the
tex
Extended hydrodynamics from Enskog's equation for a two-dimensional system general formalism
Balance equations are derived from Enskog's kinetic equation for a
two-dimensional system of hard disks using Grad's moment expansion method. This
set of equations constitute an extended hydrodynamics for moderately dense
bi-dimensional fluids. The set of independent hydrodynamic fields in the
present formulations are: density, velocity, temperature {\em and
also}--following Grad's original idea--the symmetric and traceless pressure
tensor and the heat flux vector . An approximation
scheme similar in spirit to one made by Grad in his original work is made. Once
the hydrodynamics is derived it is used to discuss the nature of a simple
one-dimensional heat conduction problem. It is shown that, not too far from
equilibrium, the nonequilibrium pressure in this case only depends on the
density, temperature and heat flux vector.Comment: :9 pages, 1 figure, This will appear in J. Stat. Phys. with minor
corrections and corresponds to Ref[9] of cond-mat/050710
Momentum-resolved charge excitations in high-Tc cuprates studied by resonant inelastic x-ray scattering
We report a Cu K-edge resonant inelastic x-ray scattering (RIXS) study of
high-Tc cuprates. Momentum-resolved charge excitations in the CuO2 plane are
examined from parent Mott insulators to carrier-doped superconductors. The Mott
gap excitation in undoped insulators is found to commonly show a larger
dispersion along the [pi,pi] direction than the [pi,0] direction. On the other
hand, the resonance condition displays material dependence. Upon hole doping,
the dispersion of the Mott gap excitation becomes weaker and an intraband
excitation appears as a continuum intensity below the gap at the same time. In
the case of electron doping, the Mott gap excitation is prominent at the zone
center and a dispersive intraband excitation is observed at finite momentum
transfer
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