High-temperature (T) and high-electric-field (E) effects on Pb[(Zn_{1/3}
Nb_{2/3})_{0.92} Ti_{0.08}]O_3 (PZN-8%PT) were studied comprehensively by
neutron diffraction in the ranges 300 <= T <= 550 K and 0 <= E <= 15 kV/cm. We
have focused on how phase transitions depend on preceding thermal and
electrical sequences. In the field cooling process (FC, E parallel [001] >= 0.5
kV/cm), a successive cubic (C) --> tetragonal (T) --> monoclinic (M_C)
transition was observed. In the zero field cooling process (ZFC), however, we
have found that the system does not transform to the rhombohedral (R) phase as
widely believed, but to a new, unidentified phase, which we call X. X gives a
Bragg peak profile similar to that expected for R, but the c-axis is always
slightly shorter than the a-axis. As for field effects on the X phase, we found
an irreversible X --> M_C transition via another monoclinic phase (M_A) as
expected from a previous report [Noheda et al. Phys. Rev. Lett. 86, 3891
(2001)]. At a higher electric field, we confirmed a c-axis jump associated with
the field-induced M_C --> T transition, which was observed by strain and x-ray
diffraction measurements.Comment: 8 pages, 9 figures, revise