370 research outputs found
Superlattice formation lifting degeneracy protected by non-symmorphic symmetry through a metal-insulator transition in RuAs
The single crystal of RuAs obtained by Bi-flux method shows obvious
successive metal-insulator transitions at T_MI1~255 K and T_MI2~195$ K. The
X-ray diffraction measurement reveals a formation of superlattice of 3x3x3 of
the original unit cell below T_MI2, accompanied by a change of the crystal
system from the orthorhombic structure to the monoclinic one. Simple
dimerization of the Ru ions is nor seen in the ground state. The multiple As
sites observed in nuclear quadrupole resonance (NQR) spectrum also demonstrate
the formation of the superlattice in the ground state, which is clarified to be
nonmagnetic. The divergence in 1/T_1 at T_MI1 shows that a symmetry lowering by
the metal-insulator transition is accompanied by strong critical fluctuations
of some degrees of freedom. Using the structural parameters in the insulating
state, the first principle calculation reproduces successfully the reasonable
size of nuclear quadrupole frequencies for the multiple As sites, ensuring the
high validity of the structural parameters. The calculation also gives a
remarkable suppression in the density of states (DOS) near the Fermi level,
although the gap opening is insufficient. A coupled modulation of the
calculated Ru d electron numbers and the crystal structure proposes a formation
of charge density wave (CDW) in RuAs. Some lacking factors remain, but it shows
that a lifting of degeneracy protected by the non-symmorphic symmetry through
the superlattice formation is a key ingredient for the metal-insulator
transition in RuAs.Comment: 10 pages, 10 figure
Quantum Melting of Charge Order due to Frustration in Two-Dimensional Quarter-Filled Systems
The effect of geometrical frustration in a two-dimensional 1/4-filled
strongly correlated electron system is studied theoretically, motivated by
layered organic molecular crystals. An extended Hubbard model on the square
lattice is considered, with competing nearest neighbor Coulomb interaction, V,
and that of next-nearest neighbor along one of the diagonals, V', which favor
different charge ordered states. Based on exact diagonalization calculations,
we find a metallic phase stabilized over a broad window at V' ~ V even for
large Coulomb repulsion strengths as a result of frustrating the charge ordered
states. Slightly modifying the lattice geometry relevant to the actual organic
compounds does not alter the results, suggesting that this `quantum melting' of
charge order is a robust feature of frustrated strongly correlated 1/4-filled
systems.Comment: 5 pages, 4 figures, to be published in Phys. Rev.
Ground state of the spin-1/2 chain of green dioptase at high fields
The gem-stone dioptase Cu6Si6O18.6H2O has a chiral crystal structure of
equilateral triangular helices consisting of Cu-3d spins. It shows an
antiferromagnetic order with an easy axis along c at TN = 15.5 K under zero
field, and a magnetization jump at HC = 13.5 T when the field is applied along
c-axis. By 29Si-NMR measurements, we have revealed that the high-field state is
essentially the two sub-lattice structure, and that the component within
ab-plane is collinear. The result indicates no apparent match with the
geometrical pattern of helical spin chain.Comment: SCES2013, Hongo, Toky
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