Diurnal temperature range over Europe between 1950 and 2005

International audienceIt has been widely accepted that diurnal temperature range (DTR) decreased on a global scale during the second half of the twentieth century. Here we show however, that the long-term trend of annual DTR has reversed from a decrease to an increase during the 1970s in Western Europe and during the 1980s in Eastern Europe. The analysis is based on the high-quality dataset of the European Climate Assessment and Dataset Project, from which we selected approximately 200 stations, covering the area from Iceland to Algeria and from Turkey to Russia for 1950 to 2005. We investigate national and regional annual means as well as the pan-European mean with respect to trends and reversal periods. 17 of the 24 investigated regions including the pan-European mean show a statistical significant increase since 1990 at the latest. Of the remaining 7 regions, 2 show a non-significant increase, 3 a significant decrease and the remaining 2 no significant trend. The long-term change in DTR is governed by both surface shortwave and longwave radiation, the former of which has undergone a change from dimming to brightening. Consequently, we discuss the connections between DTR, shortwave radiation and sulfur emissions which are thought to be amongst the most important factors influencing the incoming solar radiation through the primary and secondary aerosol effect. We find reasonable agreement between trends in SO2 emissions, radiation and DTR in areas affected by high pollution. Consequently, we conclude that the long-term trends in DTR are mostly determined by changes in emissions and the associated changes in incoming solar radiation

Dactylospora anziae, a new lichenicolous ascomycete on Anzia from East Asia

Dactylospora anziae growing on species of Anzia is described from Russia and Japan

Dissociation dynamics of ethylene molecules on a Ni cluster using ab initio molecular dynamics simulations

is investigated by ab initio molecular-dynamics simulations. The activation free energy to dehydrogenate an ethylene molecule on the Ni cluster and the corresponding reaction rate is estimated. A remarkable finding is that the adsorption energy of ethylene molecules on the Ni cluster is considerably larger than the activation free energy, which explains why the actual reaction rate is faster than the value estimated based on only the activation free energy. It is also found from the dynamic simulations that hydrogen molecules and an ethane molecule are formed from the dissociated hydrogen atoms, whereas some exist as single atoms on the surface or in the interior of the Ni cluster. On the other hand, the dissociation of the C-C bonds of ethylene molecules is not observed. On the basis of these simulation results, the nature of the initial stage of carbon nanotube growth is discussed. Keywords: nickel cluster, ethylene molecule, dissociation, ab initio molecular dynamics simulation, activation energy, adsoption energ