Nonvolatile memory with molecule-engineered tunneling barriers

We report a novel field-sensitive tunneling barrier by embedding C60 in SiO2 for nonvolatile memory applications. C60 is a better choice than ultra-small nanocrystals due to its monodispersion. Moreover, C60 provides accessible energy levels to prompt resonant tunneling through SiO2 at high fields. However, this process is quenched at low fields due to HOMO-LUMO gap and large charging energy of C60. Furthermore, we demonstrate an improvement of more than an order of magnitude in retention to program/erase time ratio for a metal nanocrystal memory. This shows promise of engineering tunnel dielectrics by integrating molecules in the future hybrid molecular-silicon electronics.Comment: to appear in Applied Physics Letter

Estimation of Buttiker-Landauer traversal time based on the visibility of transmission current

We present a proposal for the estimation of B\"uttiker-Landauer traversal time based on the visibility of transmission current. We analyze the tunneling phenomena with a time-dependent potential and obtain the time-dependent transmission current. We found that the visibility is directly connected to the traversal time. Furthermore, this result is valid not only for rectangular potential barrier but also for general form of potential to which the WKB approximation is applicable . We compared these results with the numerical values obtained from the simulation of Nelson's quantum mechanics. Both of them fit together and it shows our method is very effective to measure experimentally the traversal time.Comment: 12 pages, REVTeX, including 7 eps figure

Water as a potential molecular probe for functional groups on carbon surfaces

A new and simple method, using water as a potential molecular probe, is proposed for the determination of the concentration of surface oxygen groups on carbon adsorbents. The procedure is based on a determination of the Henry constant between a water molecule and a functional group from the volume integration of the Boltzmann factor over the accessible space around the functional group. Three porous carbons are used in this study to test the new method: A-5, RF-100 and RF-200. The results obtained are in good agreement with those measured by Boehm titration. This new method can be applied to adsorbents containing small concentrations of oxygen groups where the Boehm titration method may give unreliable results

Magnetization of alpha\u27 iron nitride produced through the fcc->bct martensitic transformation in high magnetic field

The gamma iron nitride (nitrogen austenite) was subjected to high magnetic field process in order to drive the fcc-->bct martensitic transformation. Molar fraction of martensite monotonically increased with increasing the magnetic field and reached 94% at 35 T. With a combination of magnetization and 57Fe Mössbauer spectroscopy data, magnetization of bulk processed alpha[prime] phase with 9.6 at. % N is determined to be 229 emu/g, the same as that for dc sputtered thin films

Exact results of the mixed-spin Ising model on a decorated square lattice with two different decorating spins of integer magnitudes

The mixed-spin Ising model on a decorated square lattice with two different decorating spins of the integer magnitudes S_B = 1 and S_C = 2 placed on horizontal and vertical bonds of the lattice, respectively, is examined within an exact analytical approach based on the generalized decoration-iteration mapping transformation. Besides the ground-state analysis, finite-temperature properties of the system are also investigated in detail. The most interesting numerical result to emerge from our study relates to a striking critical behaviour of the spontaneously ordered 'quasi-1D' spin system. It was found that this quite remarkable spontaneous order arises when one sub-lattice of the decorating spins (either S_B or S_C) tends towards their 'non-magnetic' spin state S = 0 and the system becomes disordered only upon further single-ion anisotropy strengthening. The effect of single-ion anisotropy upon the temperature dependence of the total and sub-lattice magnetization is also particularly investigated.Comment: 17 pages, 6 figure

Static black holes with a negative cosmological constant: Deformed horizon and anti-de Sitter boundaries

Using perturbative techniques, we investigate the existence and properties of a new static solution for the Einstein equation with a negative cosmological constant, which we call the deformed black hole. We derive a solution for a static and axisymmetric perturbation of the Schwarzschild-anti-de Sitter black hole that is regular in the range from the horizon to spacelike infinity. The key result is that this perturbation simultaneously deforms the two boundary surfaces--i.e., both the horizon and spacelike two-surface at infinity. Then we discuss the Abbott-Deser mass and the Ashtekar-Magnon one for the deformed black hole, and according to the Ashtekar-Magnon definition, we construct the thermodynamic first law of the deformed black hole. The first law has a correction term which can be interpreted as the work term that is necessary for the deformation of the boundary surfaces. Because the work term is negative, the horizon area of the deformed black hole becomes larger than that of the Schwarzschild-anti-de Sitter black hole, if compared under the same mass, indicating that the quasistatic deformation of the Schwarzschild-anti-de Sitter black hole may be compatible with the thermodynamic second law (i.e., the area theorem).Comment: 31 pages, 5 figures, one reference added, to be published in PR

Self-folding of supramolecular polymers into bioinspired topology.

Folding one-dimensional polymer chains into well-defined topologies represents an important organization process for proteins, but replicating this process for supramolecular polymers remains a challenging task. We report supramolecular polymers that can fold into protein-like topologies. Our approach is based on curvature-forming supramolecular rosettes, which affords kinetic control over the extent of helical folding in the resulting supramolecular fibers by changing the cooling rate for polymerization. When using a slow cooling rate, we obtained misfolded fibers containing a minor amount of helical domains that folded on a time scale of days into unique topologies reminiscent of the protein tertiary structures. Thermodynamic analysis of fibers with varying degrees of folding revealed that the folding is accompanied by a large enthalpic gain. The self-folding proceeds via ordering of misfolded domains in the main chain using helical domains as templates, as fully misfolded fibers prepared by a fast cooling rate do not self-fold

Quantum-well states in ultrathin Ag(111) films deposited onto H-passivated Si(111)-(1x1) surfaces

Ag(111) films were deposited at room temperature onto H-passivated Si(111)-(1x1) substrates, and subsequently annealed at 300 C. An abrupt non-reactive Ag/Si interface is formed, and very uniform non-strained Ag(111) films of 6-12 monolayers have been grown. Angle resolved photoemission spectroscopy has been used to study the valence band electronic properties of these films. Well-defined Ag sp quantum-well states (QWS) have been observed at discrete energies between 0.5-2eV below the Fermi level, and their dispersions have been measured along the GammaK, GammaMM'and GammaL symmetry directions. QWS show a parabolic bidimensional dispersion, with in-plane effective mass of 0.38-0.50mo, along the GammaK and GammaMM' directions, whereas no dispersion has been found along the GammaL direction, indicating the low-dimensional electronic character of these states. The binding energy dependence of the QWS as a function of Ag film thickness has been analyzed in the framework of the phase accumulation model. According to this model, a reflectivity of 70% has been estimated for the Ag-sp states at the Ag/H/Si(111)-(1x1) interface.Comment: 6 pages, 6 figures, submitted to Phys. Rev.

A new molecular model for water adsorption on graphitized carbon black

Adsorption of water on graphitized carbon black at various temperatures has been studied with a new molecular model of graphitized carbon black using Monte Carlo simulation. The model is a collection of graphene layers, modelled by the Steele potential, and a number of phenol groups forming clusters of various sizes which are placed randomly at the graphene edge sites to give an O/C ratio of 0.006. The results are compared with experimental data reported by Kiselev et al. [1] in 1968 for a range of temperatures, and for the first time a reconciliation between the experimental data and simulation has been successfully achieved. The simulation results show that water adsorbs preferentially around the functional groups to form clusters, which then grow and merge at the edges of the graphene layers, rather than adsorbing onto the basal planes of the graphene because the electrostatic interactions (hydrogen bonding) between water molecules are stronger than the basal plane-water dispersion interactions