Mandibular reconstruction: a new defect classification system

This paper presents a new mandibular segmental defect classification system (La-Co-CE) with a view to highlight the complexity and difficulty of the reconstruction with free autogenous bone grafts which the most frequently used method for surgeons practicing in developing countries. We submit that defect classification systems will continue to remain relevant if surgeons are to is pre-operatively classify the envisaged operative difficulty and objectively compare the outcome postoperatively. Key words: Mandibular reconstruction, defect, classification

Incidence and risk factors for nerve injuries in mandibular third molar surgery

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Ameloblastic fibroma: Presentation and management at two Nigerian tertiary hospitals

Background: Ameloblastic fibroma (AMF) is a relatively uncommon neoplasm of odontogenic origin. Aim: To appraise the prevalence, presentation and management of AMF in two major tertiary hospitals in Nigeria. Methods: Histopathology records of the Departments of Oral and Maxillofacial Surgery of the two hospitals were reviewed and histologically confirmed cases of AMF seen over a 23- year period were selected. The case records of the selected cases were retrieved and the presentation and management of the disease were analyzed and discussed. Results: Seventeen cases of histologically confirmed AMF were seen over the period under study. The age range was 10 - 63 years and mean age of occurrence was 27.1 + 16  years, there was no sex predilection but the mandible was the commonest site of occurrence. Most cases were treated by conservative excision but some cases had more extensive resection. No tumour recurrence was observed over an average follow up period of 2 years. Conclusion: AMF with a prevalence of 3.1% in this study, remains a rare variety of odontogenic tumour and is amenable to conservative surgical excision preptrrrase. Large lesions may warrant more radical resection but recurrence is generally rare.   Key words: Ameloblastic, Fibroma, Presentation, Managemen

Clinical options for mandibular reconstruction: A review

This paper reviewed the different clinical options for reconstruction of segmental defects of the mandible. The options reviewed included no reconstruction; the use of prosthetic implants (alloplasts); autogenous bone grafts; combination of allopplasts with autografts; free pedicled compound grafts;combination of homografts and autografts; distraction osteogenesis; and tissue engineering. The goal, objectives, criteria for success of autogenous and alloplastic reconstructions were highlighted as well as the factors that may influence the choice of a particular method

Electrochemical Detection of Bisphenol A Using Graphene-Modified Glassy Carbon Electrode

Graphene's nano-dimensional nature and excellent electron transfer properties underlie its electrocatalytic behavior towards certain substances. In this light, we have used graphene in the electrochemical detection of bisphenol A. Graphene sheets were produced via soft chemistry route involving graphite oxidation and chemical reduction. X-ray diffraction, Fourier transform infra-red (FT-IR) and Raman spectroscopy were used for the characterization of the as-synthesized graphene. Graphene exhibited amorphous structure in comparison with pristine graphite from XRD spectra. FTIR showed that graphene exhibits OH and COOH groups due to incomplete reduction. Raman spectroscopy revealed that multi-layered graphene was produced due to low intensity of the 2D-peak. Glassy carbon electrode was modified with graphene by a simple drop and dry method. Cyclic voltammetry was used to study the electrochemical properties of the prepared graphene-modified glassy carbon electrode using potassium ferricyanide as a redox probe. The prepared graphene- modified glassy carbon electrode exhibited more facile electron kinetics and enhanced current of about 75% when compared to the unmodified glassy carbon electrode. The modified electrode was used for the detection of bisphenol A. Under the optimum conditions, the oxidation peak current of bisphenol A varied linearly with concentration over a wide range of 5 x 10(-8) mol L-1 to 1 x 10(-6) mol L-1 and the detection limit of this method was as low as 4.689 x 10(-8) M. This method was also employed to determine bisphenol A in a real sampl

Ondontogenic tumours in Nigerian children and adolescents

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Synthesis and characterization of generation 2 and 3 poly(propylene imine) dendrimer capped NiFe nanoalloy

NatuurwetenskappeChemie & PolimeerwetenskapPlease help us populate SUNScholar with the post print version of this article. It can be e-mailed to: [email protected]

Reactivities of Modified and Unmodified Exfoliated Graphite Electrodes in Selected Redox Systems

The electrochemical profiles of exfoliated graphite electrodes (EG) and glassy carbon electrodes (GCE) were recorded using cyclic voltammetry and square wave voltammetry in the presence of various supporting electrolytes and Fe(CN)(6)](3-/4-), Ru(NH3)(6)](2+/3+), ferrocene redox probes. In the supporting electrolytes (KCl, H2SO4, NaOH, tetrabutylammoniumtetraflouroborate, phosphate buffers), the potential windows of EG were found in some cases to be about 200 mV larger than that of GCE. The electroactive surface area of EG was estimated to be 19.5 % larger than the GCE which resulted in higher peak currents on the EG electrode. Furthermore, EG was modified with various nanomaterials such as poly (propylene imine) dendrimer, gold nanoparticles, and dendrimer-gold nanoparticles composite. The morphologies of the modified electrodes were studied using scanning electron microscopy and their electrochemical reactivities in the three redox probes were investigated. The current and the reversibility of redox probes were enhanced with the presence of modifiers in different degrees with dendrimer and gold nanoparticles having a favorable edge

Cyclodextrin-dendrimer functionalized polysulfone membrane for the removal of humic acid in water

Please help populate SUNScholar with the full text of SU research output. Also - should you need this item urgently, please send us the details and we will try to get hold of the full text as quick possible. E-mail to [email protected]. Thank you.Journal Articles (subsidised)NatuurwetenskappeChemie & Polimeerwetenska

Photoelectrochemical degradation of eosin yellowish dye on exfoliated graphite-ZnO nanocomposite electrode

In the quest for harnessing more power from the sun for water treatment by photoelectrochemical degradation, we prepared a novel photoanode of exfoliated graphite (EG)-ZnO nanocomposite. The nanocomposite was characterised by X-ray diffractometry, energy dispersive spectroscopy, Brunauer-Emmett-Teller surface area analyser, thermal gravimetric analyser, and X-ray photoelectron spectroscopy. The EG-ZnO nanocomposite was fabricated into a photoanode and applied for the photoelectrochemical degradation of 0.1 x 10(-4) M eosin yellowish dye in 0.1 M Na2SO4 under visible light irradiation. The degradation was monitored with a visible spectrophotometer. The photoelectrochemical degradation process resulted in enhanced degradation efficiency of ca. 93 % with kinetic rate of 11.0 x 10(-3) min(-1) over photolysis and electrochemical oxidation processes which exhibited lower degradation efficiencies of 35 and 40 % respectively