156 research outputs found
Application of Slow-Scan Charge-Coupled Device (CCD) Cameras to On-Line Microscope Control
Autotuning methods for transmission electron microscopy are reviewed, and a distinction is drawn between predictive and non-predictive methods. The predictive methods make better use of the input data and therefore need fewer images to carry out complete autotuning. They typically require high quality of input data, which can be best provided by cooled slow-scan charge-coupled device (CCD) cameras. Two predictive methods are considered in more detail. These are the tilt-induced image shift (TIS) method of Koster, van der Mast and de Ruijter, and a new automated diffractogram analysis (ADA) method, which is introduced in this paper. The ADA method is shown to be capable of accurately aligning, stigmating and focussing a TEM in less than 30 seconds using just three high resolution images, and of automatically calibrating all the needed microscope parameters
Atomic Configuration of Nitrogen Doped Single-Walled Carbon Nanotubes
Having access to the chemical environment at the atomic level of a dopant in
a nanostructure is crucial for the understanding of its properties. We have
performed atomically-resolved electron energy-loss spectroscopy to detect
individual nitrogen dopants in single-walled carbon nanotubes and compared with
first principles calculations. We demonstrate that nitrogen doping occurs as
single atoms in different bonding configurations: graphitic-like and
pyrrolic-like substitutional nitrogen neighbouring local lattice distortion
such as Stone-Thrower-Wales defects. The stability under the electron beam of
these nanotubes has been studied in two extreme cases of nitrogen incorporation
content and configuration. These findings provide key information for the
applications of these nanostructures.Comment: 25 pages, 13 figure
Effects of epitaxial strain on the growth mechanism of YBa2Cu3O7-x thin films in [YBa2Cu3O7-x / PrBa2Cu3O7-x] superlattices
We report on the growth mechanism of YBa2Cu3O7-x (YBCO). Our study is based
on the analysis of ultrathin, YBa2Cu3O7-x layers in c-axis oriented YBa2Cu3O7-x
/ PrBa2Cu3O7-x superlattices. We have found that the release of epitaxial
strain in very thin YBCO layers triggers a change in the dimensionality of the
growth mode. Ultrathin, epitaxially strained, YBCO layers with thickness below
3 unit cells grow in a block by block two dimensional mode coherent over large
lateral distances. Meanwhile, when thickness increases, and the strain relaxes,
layer growth turns into three dimensional, resulting in rougher layers and
interfaces.Comment: 10 pages + 9 figures, accepted in Phys. Rev.
Graphene re-knits its holes
Nano-holes, etched under an electron beam at room temperature in singlelayer
graphene sheets as a result of their interaction with metalimpurities, are
shown to heal spontaneously by filling up with either non-hexagon,
graphene-like, or perfect hexagon 2D structures. Scanning transmission electron
microscopy was employed to capture the healing process and study atom-by-atom
the re-grown structure. A combination of these nano-scale etching and
re-knitting processes could lead to new graphene tailoring approaches.Comment: 11 pages, 4 figure
Atomic-resolution spectroscopic imaging of ensembles of nanocatalyst particles across the life of a fuel cell
The thousandfold increase in data-collection speed enabled by
aberration-corrected optics allows us to overcome an electron microscopy
paradox - how to obtain atomic-resolution chemical structure in individual
nanoparticles, yet record a statistically significant sample from an
inhomogeneous population. This allowed us to map hundreds of Pt-Co
nanoparticles to show atomic-scale elemental distributions across different
stages of the catalyst aging in a proton-exchange-membrane fuel cell, and
relate Pt-shell thickness to treatment, particle size, surface orientation, and
ordering.Comment: 28 pages, 5 figures, accepted, nano letter
Light interception principally drives the understory response to boxelder invasion in riparian forests
Since several decades, American boxelder (Acer negundo) is replacing white willow (Salix alba) riparian forests along southern European rivers. This study aims to evaluate the consequences of boxelder invasion on understory community in riparian areas. We determined the understory species richness, composition and biomass in boxelder and white willow stands located in three riparian forests, representative of three rivers with distinct hydrological regimes. We investigated correlation of these variables to soil moisture and particle size, main soil nutrient stocks, potential nitrification and denitrification, tree canopy cover and photosynthetic active radiation (PAR) at the ground level. A greenhouse experiment was then conducted to identify the causal factors responsible for changes in the understory. The effect of soil type, PAR level and water level on the growth and the biomass production of Urtica dioica were examined. A lower plant species richness and biomass, and a modification of community composition were observed for boxelder understory in all sites, regardless of their environmental characteristics. The strongest modification that follows boxelder invasion was the decline in U. dioica, the dominant species of the white willow forest understory. These differences were mainly correlated with a lower incident PAR under boxelder canopy. The greenhouse experiment identified PAR level as the main factor responsible for the changes in U. dioica stem number and biomass. Our results indicate that adult boxelder acts as an ecosystem engineer that decreases light availability. The opportunistic invasion by boxelder leads to important understory changes, which could alter riparian ecosystem functioning
Ptychography
Ptychography is a computational imaging technique. A detector records an extensive data set consisting of many inference patterns obtained as an object is displaced to various positions relative to an illumination field. A computer algorithm of some type is then used to invert these data into an image. It has three key advantages: it does not depend upon a good-quality lens, or indeed on using any lens at all; it can obtain the image wave in phase as well as in intensity; and it can self-calibrate in the sense that errors that arise in the experimental set up can be accounted for and their effects removed. Its transfer function is in theory perfect, with resolution being wavelength limited. Although the main concepts of ptychography were developed many years ago, it has only recently (over the last 10 years) become widely adopted. This chapter surveys visible light, x-ray, electron, and EUV ptychography as applied to microscopic imaging. It describes the principal experimental arrangements used at these various wavelengths. It reviews the most common inversion algorithms that are nowadays employed, giving examples of meta code to implement these. It describes, for those new to the field, how to avoid the most common pitfalls in obtaining good quality reconstructions. It also discusses more advanced techniques such as modal decomposition and strategies to cope with three-dimensional () multiple scattering
NITROGEN METABOLISM OF THE SLIME MOLD DICTYOSTELIUM DISCOIDEUM DURING GROWTH AND MORPHOGENESIS
Volume: 107Start Page: 226End Page: 23
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