147 research outputs found
Advanced Photodetectors for Hyperspectroscopy and Other Applications
Hyperspectroscopy is a new method of surface image taking, providing
simultaneously high position and spectral resolutions which allow one to make
some conclusions about chemical compositions of the surfaces. We are now
studying applications of the hyperspctroscopic technique to be used for
medicine. This may allow one to develop early diagnostics of some illnesses, as
for example, skin cancer. For image taking advanced MCPs are currently used,
sensitive in the spectral interval of 450-850 nm. One of the aims of this work
is to extend the hyperspectrocpic method to the UV region of spectra: 185-280
nm. For this we have developed and successfully tested innovative 1D and 2D UV
sealed photosensitive gaseous detectors with resistive electrodes. These
detectors are superior MCPs due to the very low rate of noise pulses and thus
due to the high signal to noise ratio. Other important features of these
detectors are that they have excellent position resolutions - 30 micron in
digital form, are vibration stable and are spark protected. The first results
from the application of these detectors for spectroscopy, hyperspectroscopy and
the flame detection are presented.Comment: Presented at the IEEE Nuclear Science Syposium, Puerto Rico, October
200
The first applications of novel gaseous detectors for UV visualization
We have demonstrated experimentally that recently developed gaseous detectors combined with solid or gaseous photo-cathodes have exceptionally low noise and high quantum efficiency for UV photons while being solar blind. For this reason they can be used for the detection of weak UV sources in daylight conditions. These detectors are extremely robust, can operate in poor gas conditions and are cheap. We present the first results of their applications to hyper-spectroscopy and flame detection in daylight conditions
How can ski resorts get smart? Transdisciplinary approaches to sustainable winter tourism in the European Alps
Climate change and the call for reduction of greenhouse gas emissions, the efficient use of
(renewable) energy, and more resilient winter tourism regions, forces ski resorts across the European Alps to look for \u201csmart\u201d approaches to transition towards a sustainable, low-carbon economy. Drawing on the smart-city concept and considering the different historical developments of Alpine resorts, the Smart Altitude Decision-Making Toolkit was developed using a combination of an energy audit tool, a WebGIS, and collaborative and innovative living labs installed in Les Orres (France), Madonna di Campiglio (Italy), Krvavec (Slovenia), and Verbier (Switzerland). This step-by-step Decision-Making Toolkit enables ski resorts to get feedback on their energy demand, an overview of the locally available sources of renewable energy, and insights regarding their potential for improving their energy efficiency by low-carbon interventions. The Decision-Making Toolkit is suitable for knowledge transfer between stakeholders within living labs and moreover provides the flexibility for tailor-made low-carbon strategies adapting to the unique assets and situatedness of ski resorts
Electrode Polarization Effects in Broadband Dielectric Spectroscopy
In the present work, we provide broadband dielectric spectra showing strong
electrode polarization effects for various materials, belonging to very
different material classes. This includes both ionic and electronic conductors
as, e.g., salt solutions, ionic liquids, human blood, and
colossal-dielectric-constant materials. These data are intended to provide a
broad data base enabling a critical test of the validity of phenomenological
and microscopic models for electrode polarization. In the present work, the
results are analyzed using a simple phenomenological equivalent-circuit
description, involving a distributed parallel RC circuit element for the
modeling of the weakly conducting regions close to the electrodes. Excellent
fits of the experimental data are achieved in this way, demonstrating the
universal applicability of this approach. In the investigated ionically
conducting materials, we find the universal appearance of a second dispersion
region due to electrode polarization, which is only revealed if measuring down
to sufficiently low frequencies. This indicates the presence of a second
charge-transport process in ionic conductors with blocking electrodes.Comment: 9 pages, 6 figures, experimental data are provided in electronic form
(see "Data Conservancy"
Evolution of Linear Absorption and Nonlinear Optical Properties in V-Shaped Ruthenium(II)-Based Chromophores
In this article, we describe a series of complexes with electron-rich cis-{Ru^(II)(NH_3)_4}^(2+) centers coordinated to two pyridyl ligands bearing N-methyl/arylpyridinium electron-acceptor groups. These V-shaped dipolar species are new, extended members of a class of chromophores first reported by us (Coe, B. J. et al. J. Am. Chem. Soc. 2005, 127, 4845−4859). They have been isolated as their PF_6− salts and characterized by using various techniques including ^1H NMR and electronic absorption spectroscopies and cyclic voltammetry. Reversible Ru^(III/II) waves show that the new complexes are potentially redox-switchable chromophores. Single crystal X-ray structures have been obtained for four complex salts; three of these crystallize noncentrosymmetrically, but with the individual molecular dipoles aligned largely antiparallel. Very large molecular first hyperpolarizabilities β have been determined by using hyper-Rayleigh scattering (HRS) with an 800 nm laser and also via Stark (electroabsorption) spectroscopic studies on the intense, visible d → π^* metal-to-ligand charge-transfer (MLCT) and π → π^* intraligand charge-transfer (ILCT) bands. The latter measurements afford total nonresonant β_0 responses as high as ca. 600 × 10^(−30) esu. These pseudo-C_(2v) chromophores show two substantial components of the β tensor, β_(zzz) and β_(zyy), although the relative significance of these varies with the physical method applied. According to HRS, β_(zzz) dominates in all cases, whereas the Stark analyses indicate that β_(zyy) is dominant in the shorter chromophores, but β_(zzz) and β_(zyy) are similar for the extended species. In contrast, finite field calculations predict that β_(zyy) is always the major component. Time-dependent density functional theory calculations predict increasing ILCT character for the nominally MLCT transitions and accompanying blue-shifts of the visible absorptions, as the ligand π-systems are extended. Such unusual behavior has also been observed with related 1D complexes (Coe, B. J. et al. J. Am. Chem. Soc. 2004, 126, 3880−3891)
Colossal dielectric constants in transition-metal oxides
Many transition-metal oxides show very large ("colossal") magnitudes of the
dielectric constant and thus have immense potential for applications in modern
microelectronics and for the development of new capacitance-based
energy-storage devices. In the present work, we thoroughly discuss the
mechanisms that can lead to colossal values of the dielectric constant,
especially emphasising effects generated by external and internal interfaces,
including electronic phase separation. In addition, we provide a detailed
overview and discussion of the dielectric properties of CaCu3Ti4O12 and related
systems, which is today's most investigated material with colossal dielectric
constant. Also a variety of further transition-metal oxides with large
dielectric constants are treated in detail, among them the system La2-xSrxNiO4
where electronic phase separation may play a role in the generation of a
colossal dielectric constant.Comment: 31 pages, 18 figures, submitted to Eur. Phys. J. for publication in
the Special Topics volume "Cooperative Phenomena in Solids: Metal-Insulator
Transitions and Ordering of Microscopic Degrees of Freedom
Dielectric properties of PbBO₃ perovskites with mixed-valence substitution in the B position
Dielectric properties of PbBO₃ perovskites with mixed-valence substitution in the B position / V. G. Zalesskiĭ, V. V. LemanovThis paper reports on the synthesis of PbBO3 perovskites with mixed-valence substitution in the B position in which the number of ions n in different valence states occupying oxygen octahedra varies from 2 to 6. The dielectric properties of ceramic samples have been studied at frequencies in the range from 12 Hz to 100 kHz and in the temperature interval 77–450 K. The new compounds have been shown to possess relaxor properties. Original Russian Text © V.G. Zalesskiĭ, V.V. Lemanov, 2010, published in Fizika Tverdogo Tela, 2010, Vol. 52, No. 7, pp. 1365–1369
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