Toward the total synthesis of spirastrellolide A. Part 3: Intelligence gathering and preparation of a ring-expanded analogue

Different methods for the formation of the C.25–C.26 bond of spirastrellolide A (1) are evaluated that might qualify for the end game of the projected total synthesis, with emphasis on metathetic ways to forge the macrocyclic frame

Response to Comment on `Undamped electrostatic plasma waves' [Phys. Plasmas 19, 092103 (2012)]

Numerical and experimental evidence is given for the occurrence of the plateau states and concomitant corner modes proposed in \cite{valentini12}. It is argued that these states provide a better description of reality for small amplitude off-dispersion disturbances than the conventional Bernstein-Greene-Kruskal or cnoidal states such as those proposed in \cite{comment

The Effects of Starburst Activity on Low Surface Brightness Disk Galaxies

Although numerous simulations have been done to understand the effects of intense bursts of star formation on high surface brightness galaxies, few attempts have been made to understand how localized starbursts would affect both the color and surface brightness of low surface brightness (LSB) galaxies. To remedy this, we have run 53 simulations involving bursts of star formation activity on LSB galaxies, varying both the underlying galaxy properties and the parameters describing the starbursts. We discovered that although changing the total color of a galaxy was fairly straightforward, it was virtually impossible to alter a galaxy's central surface brightness and thereby remove it from the LSB galaxy classification without placing a high (and fairly artificial) threshold for the underlying gas density. The primary effect of large amounts of induced star formation was to produce a centralized core (bulge) component which is generally not observed in LSB galaxies. The noisy morphological appearance of LSB galaxies as well as their noisy surface brightness profiles can be reproduced by considering small bursts of star formation that are localized within the disk. The trigger mechanism for such bursts is likely distant/weak tidal encounters. The stability of disk central surface brightness to these periods of star formation argues that the large space density of LSB galaxies at z = 0 should hold to substantially higher redshifts.Comment: 38 pages, 5 figures, 4 tables, tarred and compressed Also available on http://guernsey.uoregon.edu/~kare

Strangers in the night: Discovery of a dwarf spheroidal galaxy on its first Local Group infall

We present spectroscopic observations of the AndXII dwarf spheroidal galaxy using DEIMOS/Keck-II, showing it to be moving rapidly through the Local Group (-556 km/s heliocentric velocity, -281 km/s relative to Andromeda from the MW), falling into the Local Group from ~115 kpc beyond Andromeda's nucleus. AndXII therefore represents a dwarf galaxy plausibly falling into the Local Group for the first time, and never having experienced a dense galactic environment. From Green Bank Telescope observations, a limit on the H{I} gas mass of <3000 Msun suggests that AndXII's gas could have been removed prior to experiencing the tides of the Local Group galaxies. Orbit models suggest the dwarf is close to the escape velocity of M31 for published mass models. AndXII is our best direct evidence for the late infall of satellite galaxies, a prediction of cosmological simulations.Comment: 4 pages 5 figures 1 table, accepted in ApJ, july issu