Spatial distribution of Chlorpyrifos and Endosulfan in USA coastal waters and the Great Lakes

Between 1994 and 1997, 258 tissue and 178 sediment samples were analyzed for chlorpyrifos throughout the coastal United States and the Great Lakes. Subsequently, 95 of the 1997 tissue samples were reanalyzed for endosulfan. Tissue chlorpyrifos concentrations, which exceeded the 90th percentile, were found in coastal regions known to have high agricultural use rates but also strongly correlated with sites near high population. The highest concentrations of endosulfans in contrast, were generally limited to agricultural regions of the country. Detections of chlorpyrifos at several Alaskan sites suggest an atmospheric transport mechanism. Many Great Lakes sites had chlorpyrifos tissue concentrations above the 90th percentile which decreased with increasing distance from the Corn Belt region (Iowa, Indiana, Illinois, and Wisconsin) where most agriculturally applied chlorpyrifos is used. Correlation analysis suggests that fluvial discharge is the primary transport pathway on the Atlantic and Gulf of Mexico coasts for chlorpyrifos but not necessarily for endosulfans. (PDF contains 28 pages

The Force Explosion Condition is Consistent with Spherically Symmetric CCSN Explosions

One of the major challenges in Core-collapse Supernova (CCSN) theory is to predict which stars explode and which collapse to black holes. Gogilashvili and Murphy (2022) derived an analytic force explosion condition (FEC) and showed that the FEC is consistent with CCSN simulations that use the light-bulb approximation for neutrino heating and cooling. In this follow-up manuscript, we show that the FEC is consistent with the explosion condition when using actual neutrino transport in GR1D simulations (O'CONNOR 2015). Since most 1D simulations do not explode, to facilitate this test, we enhance the heating efficiency within the gain region. To compare the analytic FEC and radiation-hydrodynamic simulations, this manuscript also presents a practical translation of the physical parameters. For example: we replace the neutrino power deposited in the gain region, $L_\nu\tau_g$, with the net neutrino heating in the gain region; rather than assuming that $\dot{M}$ is the same everywhere, we calculate $\dot{M}$ within the gain region; and we use the neutrino opacity at the gain radius. With small, yet practical modifications, we show that the FEC predicts the explosion conditions in spherically symmetric CCSN simulations that use neutrino transport.Comment: Figure 5 most clearly highlights the fidelity and the efficacy of the Force Explosion Conditio

The Specific Heat of a Ferromagnetic Film.

We analyze the specific heat for the $O(N)$ vector model on a $d$-dimensional film geometry of thickness $L$ using ``environmentally friendly'' renormalization. We consider periodic, Dirichlet and antiperiodic boundary conditions, deriving expressions for the specific heat and an effective specific heat exponent, \alpha\ef. In the case of $d=3$, for $N=1$, by matching to the exact exponent of the two dimensional Ising model we capture the crossover for \xi_L\ra\infty between power law behaviour in the limit {L\over\xi_L}\ra\infty and logarithmic behaviour in the limit {L\over\xi_L}\ra0 for fixed $L$, where $\xi_L$ is the correlation length in the transverse dimensions.Comment: 21 pages of Plain TeX. Postscript figures available upon request from [email protected]

Recommended Thermal Rate Coefficients for the C + H3+_3^+ Reaction and Some Astrochemical Implications

We have incorporated our experimentally derived thermal rate coefficients for C + H$_3^+$ forming CH$^+$ and CH$_2^+$ into a commonly used astrochemical model. We find that the Arrhenius-Kooij equation typically used in chemical models does not accurately fit our data and use instead a more versatile fitting formula. At a temperature of 10 K and a density of 10$^4$ cm$^{-3}$, we find no significant differences in the predicted chemical abundances, but at higher temperatures of 50, 100, and 300 K we find up to factor of 2 changes. Additionally, we find that the relatively small error on our thermal rate coefficients, $\sim15\%$, significantly reduces the uncertainties on the predicted abundances compared to those obtained using the currently implemented Langevin rate coefficient with its estimated factor of 2 uncertainty.Comment: 19 pages, 5 figures. Accepted for publication in Ap

Merged-beams Reaction Studies of O + H_3^+

We have measured the reaction of O + H3+ forming OH+ and H2O+. This is one of the key gas-phase astrochemical processes initiating the formation of water molecules in dense molecular clouds. For this work, we have used a novel merged fast-beams apparatus which overlaps a beam of H3+ onto a beam of ground-term neutral O. Here, we present cross section data for forming OH+ and H2O+ at relative energies from \approx 3.5 meV to \approx 15.5 and 0.13 eV, respectively. Measurements were performed for statistically populated O(3PJ) in the ground term reacting with hot H3+ (with an internal temperature of \approx 2500-3000 K). From these data, we have derived rate coefficients for translational temperatures from \approx 25 K to \approx 10^5 and 10^3 K, respectively. Using state-of-the-art theoretical methods as a guide, we have converted these results to a thermal rate coefficient for forming either OH+ or H2O+, thereby accounting for the temperature dependence of the O fine-structure levels. Our results are in good agreement with two independent flowing afterglow measurements at a temperature of \approx 300 K, and with a corresponding level of H3+ internal excitation. This good agreement strongly suggests that the internal excitation of the H3+ does not play a significant role in this reaction. The Langevin rate coefficient is in reasonable agreement with the experimental results at 10 K but a factor of \approx 2 larger at 300 K. The two published classical trajectory studies using quantum mechanical potential energy surfaces lie a factor of \approx 1.5 above our experimental results over this 10-300 K range.Comment: 43 pages, 11 figures. Submitted to the Astrophysical Journa

Multiparticle entanglement and its experimental detection

We discuss several aspects of multiparticle mixed state entanglement and its experimental detection. First we consider entanglement between two particles which is robust against disposals of other particles. To completely detect these kinds of entanglement, full knowledge of the multiparticle density matrix (or of all reduced density matrixes) is required. Then we review the relation of the separability properties of l-partite splittings of a state $\rho$ to its multipartite entanglement properties. We show that it suffices to determine the diagonal matrix elements of $\rho$ in a certain basis in order to detect multiparticle entanglement properties of $\rho$. We apply these observations to analyze two recent experiments, where multiparticle entangled states of 3 (4) particles were produced. Finally, we focus on bound entangled states (non-separable, non-distillable states) and show that they can be activated by joint actions of the parties. We also provide several examples which show the activation of bound entanglement with bound entanglement.Comment: 9 pages, no figures; submitted to The Journal of Physics A: Mathematical and General, special issue in Quantum Information and Computatio

Relaxation and Localization in Interacting Quantum Maps

We quantise and study several versions of finite multibaker maps. Classically these are exactly solvable K-systems with known exponential decay to global equilibrium. This is an attempt to construct simple models of relaxation in quantum systems. The effect of symmetries and localization on quantum transport is discussed.Comment: 32 pages. LaTex file. 9 figures, not included. For figures send mail to first author at '[email protected]

Generation of neutral atomic beams utilizing photodetachment by high power diode laser stacks

We demonstrate the use of high power diode laser stacks to photodetach fast hydrogen and carbon anions and produce ground term neutral atomic beams. We achieve photodetachment efficiencies of $\sim$7.4\% for H$^-$ at a beam energy of 10\,keV and $\sim$3.7\% for C$^-$ at 28\,keV. The diode laser systems used here operate at 975\,nm and 808\,nm, respectively, and provide high continuous power levels of up to 2\,kW, without the need of additional enhancements like optical cavities. The alignment of the beams is straightforward and operation at constant power levels is very stable, while maintenance is minimal. We present a dedicated photodetachment setup that is suitable to efficiently neutralize the majority of stable negative ions in the periodic table