The effects of nonlocality on the evolution of higher order fluxes in non-equilibrium thermodynamics

The role of gradient dependent constitutive spaces is investigated on the example of Extended Thermodynamics of rigid heat conductors. Different levels of nonlocality are developed and the different versions of extended thermodynamics are classified. The local form of the entropy density plays a crucial role in the investigations. The entropy inequality is solved under suitable constitutive assumptions. Balance form of evolution equations is obtained in special cases. Closure relations are derived on a phenomenological level.Comment: 16 pages, 1 figur

HDX and Native Mass Spectrometry Reveals the Different Structural Basis for Interaction of the Staphylococcal Pathogenicity Island Repressor Stl with Dimeric and Trimeric Phage dUTPases

The dUTPase enzyme family plays an essential role in maintaining the genome integrity and are represented by two distinct classes of proteins; the β-pleated homotrimeric and the all-α homodimeric dUTPases. Representatives of both trimeric and dimeric dUTPases are encoded by Staphylococcus aureus phage genomes and have been shown to interact with the Stl repressor protein of S. aureus pathogenicity island SaPIbov1. In the present work we set out to characterize the interactions between these proteins based on a range of biochemical and biophysical methods and shed light on the binding mechanism of the dimeric φNM1 phage dUTPase and Stl. Using hydrogen deuterium exchange mass spectrometry, we also characterize the protein regions involved in the dUTPase:Stl interactions. Based on these results we provide reasonable explanation for the enzyme inhibitory effect of Stl observed in both types of complexes. Our experiments reveal that Stl employs different peptide segments and stoichiometry for the two different phage dUTPases which allows us to propose a functional plasticity of Stl. The malleable character of Stl serves as a basis for the inhibition of both dimeric and trimeric dUTPases

Ecological Civilisation Discourse in Xinhua’s African Newswires: Towards a Greener Agency?

How does Chinese central media represent Africa through its environmental news? This article argues that the way in which Chinese central media organisations have reported environmental issues across the African continent has altered from a reactive “charm defensive” towards the promotion of a developmental model: “Ecological Civilisation”. Based on a critical discourse analysis of headline African news published by the Xinhua News Agency, this research illustrates the emergence of this new, unexpected turn in Chinese representations of Africa, as well as highlighting the coherencies and tensions within this discourse. Questioning why this change in the emphasis of content has occurred, it investigates explanations at the macro-, mezzo-, and micro-levels of analysis, concluding that the evidence indicates that Xinhua’s content remains closely linked to the soft power goals of the Chinese Communist Party. However, the presence of risk discourses in some reports indicates that the hegemonic discourse is altering. This could potentially be the result of Xinhua’s own commercial objectives in Africa, or of the subjectivities of individual Xinhua journalists seeping into reports. This research provides significant contributions to an understanding of Chinese soft power in Africa, the ecology of Chinese media in Africa, and the development of environmental discourses

Evolutionary and socio-cultural influences on feelings and attitudes towards nature: a cross-cultural study

Mounting environmental issues have prompted reconsideration of the human–nature relationship. Accordingly, attitudes to nature, as an important dimension of human–nature interactions, have become a research focus. How feelings and attitudes towards nature are influenced by evolutionary and social-cultural constructions, and whether there is variation between different cultural groups, demands more attention. Using a survey of visitors to two very different National Parks, the New Forest National Park, England and Jiuzhaigou Scenic Area, China, this paper shows that of nationality and living environment, differences between the two nationalities were significant in respect of both attitudes and feelings. Specifically, it demonstrates that the biophilia thesis, which purports that people have an innate and a genetically inherited need for affiliation with nature, is influenced by their socio-cultural environment, in particular their national culture, but also by their current living place. The study contributes to our understanding of sustainable tourism in natural areas