Effect of Hetrovalent substitution at Mn site on the Magnetic and Transport Properties of La0.67_{0.67}Sr0.33_{0.33}MnO3_3

Magnetic and transport properties of Ti substituted La$_{0.67}$Sr$_{0.33}$MnO$_3$ are drastically affected with a change in preparation conditions. Low temperature infra-red absorption measurements reveal that this is perhaps due to inhomogeniety in substitution of Ti$^{4+}$ on Mn sites. It is found that, in the high temperature annealed samples, the substitution of Ti supresses the double exchange interaction due to the formation of Mn$^{3+}$-O-Ti$^{4+}$ chains. While in the low temperature annealed case substitution of Ti causes formation of isolated ferromagnetic clusters linked to each other by a variable range hopping polaron.Comment: 11 pages, 8 figures, accepted in J. Magn. Magn. Magn. Mate