Magnetically controlled plasma accelerator Patent

Magnetically controlled plasma accelerator capable of ignition in low density gaseous environmen

Phosphorus Bearing Substrates in Ring Expansion Reactions

A variety of substituted phosphonium salts, phosphorus ylides and phosphonates were studied to assess their utility in ring expansion reactions. The strategy involved formation of fused ring systems whose ring strain could be exploited to accomplish ring expansion to medium sized rings. β-Alkoxy vinylphosphonium salts were found to be unreactive with species such as the dimethylsulfoxonium methylide anion, Simmons-Smith type reagents. and carbenes in attempts to produce cyclopropyl phosphonium salts. C-Alkylation of β-keto phosphorus ylides using haloalkanes bearing terminal groups that could be converted and reacted with the B-carbonyl, was also examined as a method for accessing strained rings bearing electron donating alkoxy groups and electron withdrawing phosphorus substituents. The presence of C-alkylated phosphonium salt products was detected by NMR analysis of crude reaction mixtures for diiodomethane and dibromoethane, but synthetically useful yields were not obtained except for the reaction with methyl iodide. Alkynyl phosphonates, however, were found to be adequate substrates for cycloaddition with enamines to yield ring expanded products. This represents the first ring expansion via cycloaddition of alkynyl phosphonates. The reactivities of enamines derived from pyrrolidine or morpholine were compared in the cycloaddition‘ Efficiency in formation of seven and eight member rings from the enamines of cyclopentanone and cyclohexanone were thus examined. The unsaturated medium sized rings thus obtained were probed for their utility in Michael addition. This method may provide access to the basic framework of a number of natural products found to have biological activity

Do Economic Restrictions Improve Forecasts?

A previous study showed that imposing economic restrictions improves the forecasting ability of food demand systems, thus warranting their use even when rejected in-sample. This study attempts to determine whether this is due solely to the fact that restrictions improve degrees of freedom. Results indicate that restrictions improve forecasting ability even when not derived from economic theory, but theoretical restrictions forecast best.Demand and Price Analysis,

Do Economic Restrictions Improve Forecasts?

A previous study showed that imposing economic restrictions improves the forecasting ability of food demand systems, thus warranting their use even when rejected in-sample. This study attempts to determine whether this is due solely to the fact that restrictions improve degrees of freedom. Results indicate that restrictions improve forecasting ability even when not derived from economic theory, but theoretical restrictions forecast best.Demand and Price Analysis,

Fiscal year 1981 US corn and soybeans pilot preliminary experiment plan, phase 1

A draft of the preliminary experiment plan for the foreign commodity production forecasting project fiscal year 1981 is presented. This draft plan includes: definition of the phase 1 and 2 U.S. pilot objectives; the proposed experiment design to evaluate crop calendar, area estimation, and area aggregation components for corn and soybean technologies using 1978/1979 crop-year data; a description of individual sensitivity evaluations of the baseline corn and soybean segment classification procedure; and technology and data assessment in support of the corn and soybean estimation technology for use in the U.S. central corn belt

Atomic oxygen effects on LDEF experiment AO171

The Solar Array Materials Passive Long Duration Exposure Facility (LDEF) Experiment (SAMPLE), AO171, contained in total approximately 100 materials and materials processes with a 300 specimen complement. With the exception of experiment solar cell and solar cell modules, all test specimens were weighed before flight, thus allowing an accurate determination of mass loss as a result of space exposure. Since almost all of the test specimens were thermal vacuum baked before flight, the mass loss sustained can be attributed principally to atomic oxygen attack. The atomic oxygen effects observed and measured in five classes of materials is documented. The atomic oxygen reactivity values generated for these materials are compared to those values derived for the same materials from exposures on short term shuttle flights. An assessment of the utility of predicting long term atomic oxygen effects from short term exposures is given. This experiment was located on Row 8 position A which allowed all experiment materials to be exposed to an atomic oxygen fluence of 6.93 x 10(exp 21) atoms/cm(sup 2) as a result of being positioned 38 degrees off the RAM direction

Imaging Studies of photodamage and self-healing in disperse orange 11 dye-doped PMMA

We report on optical imaging studies of self-healing after laser-induced photodamage in disperse orange 11 dye doped into poly(methyl methacrylate) (PMMA) polymer. In particular, the high spatial-contrast image of the damage track made by a line focus pump laser allows the recovery rates to be measured as a function of burn dose using the relationship between transverse distance and pump intensity profile. The time evolution of the damaged population results in an intensity-independent time constant of {\tau} = 490\pm23 min, in agreement with independent measurements of the time evolution of amplified spontaneous emission. Also observed is a damage threshold above which the material does not fully recover.Comment: 5 pages, 8 figure

Neutron Imaging for Selective Laser Melting Inconel Hardware with Internal Passages

Additive Manufacturing is showing great promise for the development of new innovative designs and large potential life cycle cost reduction for the Aerospace Industry. However, more development work is required to move this technology into space flight hardware production. With selective laser melting (SLM), hardware that once consisted of multiple, carefully machined and inspected pieces, joined together can be made in one part. However standard inspection techniques cannot be used to verify that the internal passages are within dimensional tolerances or surface finish requirements. NASA/MSFC traveled to Oak Ridge National Lab's (ORNL) Spallation Neutron Source to perform some non-destructive, proof of concept imaging measurements to assess the capabilities to understand internal dimensional tolerances and internal passages surface roughness. This presentation will describe 1) the goals of this proof of concept testing, 2) the lessons learned when designing and building these Inconel 718 test specimens to minimize beam time, 3) the neutron imaging test setup and test procedure to get the images, 4) the initial results in images, volume and a video, 4) the assessment of using this imaging technique to gather real data for designing internal flow passages in SLM manufacturing aerospace hardware, and lastly 5) how proper cleaning of the internal passages is critically important. In summary, the initial results are very promising and continued development of a technique to assist in SLM development for aerospace components is desired by both NASA and ORNL. A plan forward that benefits both ORNL and NASA will also be presented, based on the promising initial results. The initial images and volume reconstruction showed that clean, clear images of the internal passages geometry are obtainable. These clear images of the internal passages of simple geometries will be compared to the build model to determine any differences. One surprising result was that a new cleaning process was used on these simply geometric specimens that resulted in what appears to be very smooth internal surfaces, when compared to other aerospace hardware cleaning methods

Neutron Imaging for Laser Selective Melting Inconel Hardware with Internal Passages

No abstract availabl