Synthesis of CdS and CdSe nanocrystallites using a novel single-molecule precursors approach

The synthesis of CdS and CdSe nanocrystallites using the thermolysis of several dithioor diselenocarbamato complexes of cadmium in trioctylphosphine oxide (TOPO) is reported. The nanodispersed materials obtained show quantum size effects in their optical spectra and exhibit near band-edge luminescence. The influence of experimental parameters on the properties of the nanocrystallites is discussed. HRTEM images of these materials show well-defined, crystalline nanosized particles. Standard size fractionation procedures can be performed in order to narrow the size dispersion of the samples. The TOPO-capped CdS and CdSe nanocrystallites and simple organic bridging ligands, such as 2,2¢-bipyrimidine, are used as the starting materials for the preparation of novel nanocomposites. The optical properties shown by these new nanocomposites are compared with those of the starting nanodispersed materials

Evolution of an eruptive flare loop system

<p><b>Context:</b> Flares, eruptive prominences and coronal mass ejections are phenomena where magnetic reconnection plays an important role. However, the location and the rate of the reconnection, as well as the mechanisms of particle interaction with ambient and chromospheric plasma are still unclear.</p> <p><b>Aims:</b> In order to contribute to the comprehension of the above mentioned processes we studied the evolution of the eruptive flare loop system in an active region where a flare, a prominence eruption and a CME occurred on August 24, 2002.</p> <p><b>Methods:</b> We measured the rate of expansion of the flare loop arcade using TRACE 195 Å images and determined the rising velocity and the evolution of the low and high energy hard X-ray sources using RHESSI data. We also fitted HXR spectra and considered the radio emission at 17 and 34 GHZ.</p> <p><b>Results:</b> We observed that the top of the eruptive flare loop system initially rises with a linear behavior and then, after 120 mn from the start of the event registered by GOES at 1–8 Å, it slows down. We also observed that the heating source (low energy X-ray) rises faster than the top of the loops at 195 Å and that the high energy X-ray emission (30–40 keV) changes in time, changing from footpoint emission at the very onset of the flare to being coincident during the flare peak with the whole flare loop arcade.</p> <p><b>Conclusions:</b> The evolution of the loop system and of the X-ray sources allowed us to interpret this event in the framework of the Lin & Forbes model (2000), where the absolute rate of reconnection decreases when the current sheet is located at an altitude where the Alfvén speed decreases with height. We estimated that the lower limit for the altitude of the current sheet is km. Moreover, we interpreted the unusual variation of the high energy HXR emission as a manifestation of the non thermal coronal thick-target process which appears during the flare in a manner consistent with the inferred increase in coronal column density.</p&gt

HYTHEC:An EC funded search for a long term massive hydrogen production route using solar and nuclear technologies

The objective of HYTHEC—HYdrogen THErmo-chemical Cycles—is to investigate the effective potential for massive hydrogen production of the S–I thermo-chemical cycle, and to compare it with the hybrid S Westinghouse (WH) cycle. The project aims to conduct flow-sheeting, industrial scale-up, safety and costs modelling, to improve the fundamental knowledge and efficiency of the S–I cycle H2 production step, and to investigate a solar primary energy source for the H2SO4 decomposition step which is common to both the cycles. Initial reference flowsheets have been prepared and compared. First data and results are available now on the coupling of S–I cycle with a very high temperature nuclear reactor, scale-up to industrial level and cost estimation, improvement of the knowledge of the HIx mixture (S–I cycle) and membrane separation, splitting of sulphuric acid using a solar furnace, and plant concepts regarding the WH process