Diplomasi Indonesia terhadap Unesco dalam Meresmikan Subak sebagai Warisan Budaya Dunia

This research is about Indonesia diplomacy effort to UNESCO to inaugurate Subak in Bali as a world cultural heritage from Indonesia in 2012. Subak Bali is a cultural heritage, it is an irrigation system that regulates the division of water management based on the mindset of harmony and togetherness, it based on formal rules and religious values. Many claims by other countries that take Indonesian culture, such as batik claiming by Malaysia, its make Indonesian government ask to UNESCO to recognize Subak as Indonesian culture. Many participants help the government to get the legally, its come from local community and also the government. Subak get legally as a Indonesia heritage culture after 10 years by some process like selection, filtration and fit and proper test. This research applies realist perspective, where it focuses on state as the main actor in international politics. Indonesia wants show to the world that Indonesia also has a heritage culture. To explain this research, the author used theory of diplomacy. This research is a qualitative descriptive research. It uses the library method by taking the data from books, journals, articles, internet and other source. The author visit Department Cultural of Bali to direct research. This research applies realist perspective, where it focuses on state as the main actor in international politics. Indonesia wants show to the world that Indonesia also has a heritage culture. To explain this research, the author used theory of diplomacy. This research is a qualitative descriptive research. It uses the library method by taking the data from books, journals, articles, internet and other source. The author visit Department Cultural of Bali to direct research. The result of this research indicate that Indonesian government did multi-track diplomacy effort to get legally Subak as a world cultural heritage of Indonesia from UNESCO on 2012. The effort get a feedback from UNESCO on Mei 2012, when the Bali Heritage culture The Cultural Landscape of Bali : Subak System as a Manifestation of The Tri Hita Karana was approved to be a World Cultural heritage. It assigned in the 36th session of UNESCO in St. Petersbug, Russia on 29 June 2012. The result of this research indicate that Indonesian government did multi-track diplomacy effort to get legally Subak as a world cultural heritage of Indonesia from UNESCO on 2012. The effort get a feedback from UNESCO on Mei 2012, when the Bali Heritage culture The Cultural Landscape of Bali : Subak System as a Manifestation of The Tri Hita Karana was approved to be a World Cultural heritage. It assigned in the 36th session of UNESCO in St. Petersbug, Russia on 29 June 2012. Keywords: subak, UNESCO, cultural heritage of Bali, multy-track diplomacy Keywords: subak, UNESCO, cultural heritage of Bali, multy-track diplomac

An Angular Bis-Oxamate Tecton for the Construction of Heterobimetallic Coordination Polymers

Two novel heterobimetallic three-dimensional coordination polymers, [Cu₂Na₄L₂(CH₃OH)_2.3(H₂O)_5.2]·1.7H₂O (<b>1</b>) and [CuNa₂L­(H₂O)_3.88]·H₂O (<b>2</b>), have been obtained by assembling a bis-oxamate copper­(II) complex with sodium ions (<i>L</i> = 4,4′-sulfonylbis­(phenylene)­bis­(oxamate). Both coordination frameworks are constructed by connecting {Cu₄L₄} crosslike anionic units by sodium ions forming polymers with different topologies. The magnetic susceptibility data shows weak antiferromagnetic interaction for both compounds

New Synthetic Route toward Heterometallic 3d–3d′ and 3d–4f Single-Molecule Magnets. The First Co^II–Mn^III Heterometallic Complex

Four tetranuclear heterometallic complexes, [Co^II₂Mn₂^III(dpm)₄(MeO)₆] (<b>1</b>) and [Ln^III₂­Mn^III₂­(dpm)₆­(MeO)₆(MeOH)_<i>n</i>], where Ln = Gd (<b>2</b>, <i>n</i> = 2), Tb (<b>3</b>, <i>n</i> = 2), and Dy (<b>4</b>, <i>n</i> = 0), have been obtained following the same general synthetic route, namely, the one-pot reaction between 2,2,6,6-tetrametil-3,5-heptanodione (Hdpm), MnCl₂ and CoCl₂ or Ln­(NO₃)₃ in the presence of sodium methoxide. Within the four compounds, the metal ions bridged by methoxide ligands display a defect-diheterocubane core. Compounds <b>1</b>, <b>3</b>, and <b>4</b> show slow relaxation of the magnetization below 4 K

New Synthetic Route toward Heterometallic 3d–3d′ and 3d–4f Single-Molecule Magnets. The First Co^II–Mn^III Heterometallic Complex

Four tetranuclear heterometallic complexes, [Co^II₂Mn₂^III(dpm)₄(MeO)₆] (<b>1</b>) and [Ln^III₂­Mn^III₂­(dpm)₆­(MeO)₆(MeOH)_<i>n</i>], where Ln = Gd (<b>2</b>, <i>n</i> = 2), Tb (<b>3</b>, <i>n</i> = 2), and Dy (<b>4</b>, <i>n</i> = 0), have been obtained following the same general synthetic route, namely, the one-pot reaction between 2,2,6,6-tetrametil-3,5-heptanodione (Hdpm), MnCl₂ and CoCl₂ or Ln­(NO₃)₃ in the presence of sodium methoxide. Within the four compounds, the metal ions bridged by methoxide ligands display a defect-diheterocubane core. Compounds <b>1</b>, <b>3</b>, and <b>4</b> show slow relaxation of the magnetization below 4 K

An Angular Bis-Oxamate Tecton for the Construction of Heterobimetallic Coordination Polymers

Two novel heterobimetallic three-dimensional coordination polymers, [Cu₂Na₄L₂(CH₃OH)_2.3(H₂O)_5.2]·1.7H₂O (<b>1</b>) and [CuNa₂L­(H₂O)_3.88]·H₂O (<b>2</b>), have been obtained by assembling a bis-oxamate copper­(II) complex with sodium ions (<i>L</i> = 4,4′-sulfonylbis­(phenylene)­bis­(oxamate). Both coordination frameworks are constructed by connecting {Cu₄L₄} crosslike anionic units by sodium ions forming polymers with different topologies. The magnetic susceptibility data shows weak antiferromagnetic interaction for both compounds

An Angular Bis-Oxamate Tecton for the Construction of Heterobimetallic Coordination Polymers

Two novel heterobimetallic three-dimensional coordination polymers, [Cu₂Na₄L₂(CH₃OH)_2.3(H₂O)_5.2]·1.7H₂O (<b>1</b>) and [CuNa₂L­(H₂O)_3.88]·H₂O (<b>2</b>), have been obtained by assembling a bis-oxamate copper­(II) complex with sodium ions (<i>L</i> = 4,4′-sulfonylbis­(phenylene)­bis­(oxamate). Both coordination frameworks are constructed by connecting {Cu₄L₄} crosslike anionic units by sodium ions forming polymers with different topologies. The magnetic susceptibility data shows weak antiferromagnetic interaction for both compounds

A New Quartz-like Metal–Organic Framework Constructed from a Versatile Pyrazole-Based Spacer

Two new coordination polymers, ¹_∞[Cu₂(L)₄­(MeOH)]­·MeOH (<b>1</b>) and ³_∞[Cu­(L)₂]­·5H₂O (<b>2</b>), have been obtained exploring the potential of 5-amino-1-phenyl-1<i>H</i>-pyrazole-4-carboxylate (L^–) to act as a spacer. The different architectures of these compounds arise from the versatility of this organic ligand. In compound <b>1</b>, the carboxylato groups (syn-syn bridging mode) and the copper ions generate a binuclear paddle-wheel motif. Each binuclear entity coordinates to another one, through one out of the four pyrazole rings, resulting in double chains. In crystal <b>2</b>, the organic ligand is coordinated to a copper ion through the carboxylato group (asymmetric chelating) and to another copper ion through the pyrazole nitrogen atom. Compound <b>2</b> crystallizes in the hexagonal system with the chiral space group <i>P</i>6₁22, featuring a quartz-like topology. The magnetic properties of both compounds have been investigated

A New Quartz-like Metal–Organic Framework Constructed from a Versatile Pyrazole-Based Spacer

Two new coordination polymers, ¹_∞[Cu₂(L)₄­(MeOH)]­·MeOH (<b>1</b>) and ³_∞[Cu­(L)₂]­·5H₂O (<b>2</b>), have been obtained exploring the potential of 5-amino-1-phenyl-1<i>H</i>-pyrazole-4-carboxylate (L^–) to act as a spacer. The different architectures of these compounds arise from the versatility of this organic ligand. In compound <b>1</b>, the carboxylato groups (syn-syn bridging mode) and the copper ions generate a binuclear paddle-wheel motif. Each binuclear entity coordinates to another one, through one out of the four pyrazole rings, resulting in double chains. In crystal <b>2</b>, the organic ligand is coordinated to a copper ion through the carboxylato group (asymmetric chelating) and to another copper ion through the pyrazole nitrogen atom. Compound <b>2</b> crystallizes in the hexagonal system with the chiral space group <i>P</i>6₁22, featuring a quartz-like topology. The magnetic properties of both compounds have been investigated

New Families of Hetero-tri-spin 2p−3d−4f Complexes: Synthesis, Crystal Structures, and Magnetic Properties

In this work we report the synthesis, crystal structures, and magnetic behavior of 2p–3d–4f heterospin systems containing the nitroxide radical 4-azido-2,2,6,6-tetramethylpiperidine-1-oxyl radical (N₃tempo). These compounds were synthesized through a one-pot reaction by using [Cu­(hfac)₂], [Ln­(hfac)₃] (hfac = hexafluoroacetylacetonate, Ln = Dy^III, Tb^III or Gd^III), and the N₃tempo radical. Depending on the stoichiometric ratio used, the synthesis leads to penta- or trimetallic compounds, with molecular formulas [Cu₃Ln₂(hfac)₈­(OH)₄(N₃tempo)] (Ln = Gd, Tb, Dy) and [CuLn₂(hfac)₈­(N₃tempo)₂(H₂O)₂] (Ln = Gd, Dy). The magnetic properties of all compounds were investigated by direct current (dc) and alternating current (ac) measurements. The ac magnetic susceptibility measurements of Tb^III- and Dy^III-containing compounds of both families revealed slow relaxation of the magnetization, with magnetic quantum tunneling in zero field