7,669 research outputs found
^{59}Co NMR evidence for charge ordering below T_{CO}\sim 51 K in Na_{0.5}CoO_2
The CoO layers in sodium-cobaltates NaCoO may be viewed as
a spin triangular-lattice doped with charge carriers. The underlying
physics of the cobaltates is very similar to that of the high cuprates.
We will present unequivocal Co NMR evidence that below ,
the insulating ground state of the itinerant antiferromagnet
NaCoO () is induced by charge ordering.Comment: Phys. Rev. Lett. 100 (2008), in press. 4 figure
NMR Search for the Spin Nematic State in LaFeAsO Single Crystal
We report a 75-As single crystal NMR investigation of LaFeAsO, the parent
phase of a pnictide high Tc superconductor. We demonstrate that spin dynamics
develop a strong two-fold anisotropy within each orthorhombic domain below the
tetragonal-orthorhombic structural phase transition at T[TO]~156 K. This
intermediate state with a dynamical breaking of the rotational symmetry freezes
progressively into a spin density wave (SDW) below T[SDW]~142 K. Our findings
are consistent with the presence of a spin nematic state below T[TO] with an
incipient magnetic order.Comment: Revised manuscript accepted for publication in Phys. Rev. Let
The Magnetic Properties of 1111-type Diluted Magnetic Semiconductor (LaBa)(ZnMn)AsO in the Low Doping Regime
We investigated the magnetic properties of
(LaBa)(ZnMn)AsO with varying from 0.005 to 0.05
at an external magnetic field of 1000 Oe. For doping levels of 0.01,
the system remains paramagnetic down to the lowest measurable temperature of 2
K. Only when the doping level increases to = 0.02 does the ferromagnetic
ordering appear. Our analysis indicates that antiferromagnetic exchange
interactions dominate for 0.01, as shown by the negative Weiss
temperature fitted from the magnetization data. The Weiss temperature becomes
positive, i.e., ferromagnetic coupling starts to dominate, for 0.02.
The Mn-Mn spin interaction parameter is estimated to be in
the order of 10 K for both 0.01 (antiferromagnetic ordered state)
and 0.02 (ferromagnetic ordered state). Our results unequivocally
demonstrate the competition between ferromagnetic and antiferromagnetic
exchange interactions in carrier-mediated ferromagnetic systems.Comment: 9 pages, 3 figure
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Biocompatible Mesoporous Hollow Carbon Nanocapsules for High Performance Supercapacitors.
A facile and general method for the controllable synthesis of N-doped hollow mesoporous carbon nanocapsules (NHCNCs) with four different geometries has been developed. The spheres (NHCNC-1), low-concaves (NHCNC-2), semi-concaves (NHCNC-3) and wrinkles (NHCNC-4) shaped samples were prepared and systematically investigated to understand the structural effects of hollow particles on their supercapacitor performances. Compared with the other three different shaped samples (NHCNC-1, NHCNC-2, and NHCNC-4), the as-synthesized semi-concave structured NHCNC-3 demonstrated excellent performance with high gravimetric capacitance of 326 F g-1 (419 F cm-3) and ultra-stable cycling stability (96.6% after 5000 cycles). The outstanding performances achieved are attributed to the unique semi-concave structure, high specific surface area (1400 m2 g-1), hierarchical porosity, high packing density (1.41 g cm-3) and high nitrogen (N) content (up to 3.73%) of the new materials. These carbon nanocapsules with tailorable structures and properties enable them as outstanding carriers and platforms for various emerging applications, such as nanoscale chemical reactors, catalysis, batteries, solar energy harvest, gas storage and so on. In addition, these novel carbons have negligible cytotoxicity and high biocompatibility for human cells, promising a wide range of bio applications, such as biomaterials, drug delivery, biomedicine, biotherapy and bioelectronic devices
Anisotropic Behavior of Knight Shift in Superconducting State of Na_xCoO_2yH_2O
The Co Knight shift was measured in an aligned powder sample of
Na_xCoO_2yH_2O, which shows superconductivity at T_c \sim 4.6 K. The
Knight-shift components parallel (K_c) and perpendicular to the c-axis (along
the ab plane K_{ab}) were measured in both the normal and superconducting (SC)
states. The temperature dependences of K_{ab} and K_c are scaled with the bulk
susceptibility, which shows that the microscopic susceptibility deduced from
the Knight shift is related to Co-3d spins. In the SC state, the Knight shift
shows an anisotropic temperature dependence: K_{ab} decreases below 5 K,
whereas K_c does not decrease within experimental accuracy. This result raises
the possibility that spin-triplet superconductivity with the spin component of
the pairs directed along the c-axis is realized in Na_xCoO_2yH_2O.Comment: 5 pages, 5 figures, to be published in Journal of Physical Society of
Japan vol. 75, No.
(Sr3La2O5)(Zn1-xMnx)2As2: A Bulk Form Diluted Magnetic Semiconductor isostructural to the "32522" Fe-based Superconductors
A new diluted magnetic semiconductor system, (Sr3La2O5)(Zn1-xMnx)2As2, has
been synthesized and characterized. 10% Mn substitution for Zn in bulk form
(Sr3La2O5)Zn2As2 results in a ferromagnetic ordering below Curie temperature,
TC ~ 40 K. (Sr3La2O5)(Zn1-xMnx)2As2 has a layered crystal structure identical
to that of 32522-type Fe based superconductors, and represents the fifth DMS
family that has a direct counterpart among the FeAs high temperature
superconductor families.Comment: Accepted for publication in EP
Sodium vacancy ordering and the co-existence of localized spins and itinerant charges in NaxCoO2
The sodium cobaltate family (NaxCoO2) is unique among transition metal oxides
because the Co sits on a triangular lattice and its valence can be tuned over a
wide range by varying the Na concentration x. Up to now detailed modeling of
the rich phenomenology (which ranges from unconventional superconductivity to
enhanced thermopower) has been hampered by the difficulty of controlling pure
phases. We discovered that certain Na concentrations are specially stable and
are associated with superlattice ordering of the Na clusters. This leads
naturally to a picture of co-existence of localized spins and itinerant charge
carriers. For x = 0.84 we found a remarkably small Fermi energy of 87 K. Our
picture brings coherence to a variety of measurements ranging from NMR to
optical to thermal transport. Our results also allow us to take the first step
towards modeling the mysterious ``Curie-Weiss'' metal state at x = 0.71. We
suggest the local moments may form a quantum spin liquid state and we propose
experimental test of our hypothesis.Comment: 16 pages, 5 figure
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