The evaluation of waste tyre pulverised fuel for NOx reduction by reburning

The combustion of coal for power generation will continue to play a major role in the future, however, this must be achieved using cleaner technologies than we use at present. Scrap tyre arisings in the UK are 400,000 tonnes per year amounting to 30 million tyres and in the EU as a whole, more than 2.5 million tonnes of tyres per year are scrapped. The recent EC Waste Landfill Directive (1999) sets a deadline for the banning of whole and shredded tyres from landfill sites by 2006. Consequently, there is an urgent need to find a mass disposal route for tyres. We describe, in this paper, a novel use for tyre rubber pulverised fuel in a NOx reburning process which may have an application in power station boilers. This method of disposal could represent a way of combining waste disposal, energy recovery and pollution control within one process. A preliminary study of micronised tyre combustion was undertaken to identify the suitable size ranges for application in NOx reduction by reburning. Tests were performed in a down-fired, pulverised fuel combustor (PFC) operating at about 80 kW. Superior combustion characteristics, i.e. burnout were achieved with particle sizes less than 250 μm. A South African coal was used as the primary fuel in the reburn tests and the tyre was fed pneumatically via a separate feed system. Parameters studied, were, reburn zone stoichiometry and reburn fuel fraction. Additionally, the carbon content of the ash was carefully monitored for any effect on burnout at the fuel rich reburn stoichiometries. The NOx reductions achieved with tyres are compared with reburning with coal. NOx reductions up to 80% were achieved with tyres at half of the reburn fuel feed rate required to achieve the same reductions by coal. The results have been evaluated within the context of other studies available in the literature on NOx reburning by bituminous coal, brown coal, gas and biomass

Gastric emptying and drug absorption

SIGLEAvailable from British Library Document Supply Centre- DSC:D43939/82 / BLDSC - British Library Document Supply CentreGBUnited Kingdo

Comparative Techno-economic assessment of biomass and coal with CCS technologies in a pulverized combustion power plant in the United Kingdom

The technical performance and cost effectiveness of white wood pellets (WWP) combustion in comparison to three types of coal namely U.S., Russian and Colombian coals are investigated in this study. Post-combustion capture and storage (CCS) namely with amine FG+, and oxy-fuel with carbon capture and storage (oxy-fuel) are applied to a 650 MW pulverized combustion (PC) plant. The impacts of the Renewable Obligation Certificate (ROC) and carbon price (CP) policy in accelerating the CCS deployment in the framework of GHG emissions mitigation, are also evaluated. The operational factors affecting CCS costs and emissions in the power generation plants are taken into consideration, hence, the Integrated Environmental Control Model (IECM 8.0.2) is employed for a systematic estimation of plant performance, costs and emissions of different scenarios of fuel and CCS technologies. This study showed that the utilization of white wood pellets (WWP) in electricity generation can annually avoid about 3 M tonnes CO2 emissions from a 650 MW power plant. However, this mitigation process had impact on the plant efficiency and the cost of electricity. Further, the BECCS using white wood pellets has showed a better efficiency and lower cost of electricity with the oxy-fuel technology than the post-combustion CCS technology. However, in order to boost biomass energy CCS (BECCS) deployment with the WWP, an increase of the ROC for biomass power plants, or, an increase of the carbon price for the coal power plants is recommended. It was found that, the sensitivity of COE towards the ROC was higher than towards the carbon price variation. This result can be interpreted as the ROC has more positive impact than the carbon price, on the COE from the point of customers view without adding more burdens on the power generation companies

Resolving the decades-long transient FIRST J141918.9+394036: an orphan long gamma-ray burst or a young magnetar nebula?

Ofek (2017) identified FIRST J141918.9+394036 (hereafter FIRST J1419+3940) as a radio source sharing similar properties and host galaxy type to the compact, persistent radio source associated with the first known repeating fast radio burst, FRB 121102. Law et al. (2018) showed that FIRST J1419+3940 is a transient source decaying in brightness over the last few decades. One possible interpretation is that FIRST J1419+3940 is a nearby analogue to FRB 121102 and that the radio emission represents a young magnetar nebula (as several scenarios assume for FRB 121102). Another interpretation is that FIRST J1419+3940 is the afterglow of an `orphan' long gamma-ray burst (GRB). The environment is similar to where most such events are produced. To distinguish between these hypotheses, we conducted radio observations using the European VLBI Network at 1.6 GHz to spatially resolve the emission and to search for millisecond-duration radio bursts. We detect FIRST J1419+3940 as a compact radio source with a flux density of $620 \pm 20\ \mathrm{\mu Jy}$ (on 2018 September 18) and a source size of $3.9 \pm 0.7\ \mathrm{mas}$ (i.e. $1.6 \pm 0.3\ \mathrm{pc}$ given the angular diameter distance of $83\ \mathrm{Mpc}$). These results confirm that the radio emission is non-thermal and imply an average expansion velocity of $(0.10 \pm 0.02)c$. Contemporaneous high-time-resolution observations using the 100-m Effelsberg telescope detected no millisecond-duration bursts of astrophysical origin. The source properties and lack of short-duration bursts are consistent with a GRB jet expansion, whereas they disfavor a magnetar birth nebula.Comment: 8 pages, 4 figures, accepted for publication in ApJ

Bubble-based EMMS mixture model applied to turbulent fluidization Powder Technology

Turbulent fluidization is now widely recognized as a distinct flow regime and is commonly utilized in industrial fluidized-bed reactors. However, relatively fewer attempts have been made to rigorously model these systems in comparison to bubbling and circulating fluidized beds. In this work, we have rewritten the original bubble based EMMS model in form of a mixture to apply it to turbulent fluidization. At microscale this mixture is composed of gas and particles whereas voids and gas-particle suspension make up this mixture at mesoscale level. Subsequently, all the system properties are then calculated in terms of mixture rather than individual phases. With the minimization of the objective function for the bubbling mixture, the set of equations is then solved numerically. The objective function, used to close the system of equations, is composed of the energy consumption rates required to suspend gas-particle suspension and the energy consumed due to interaction between suspension and voids. The model is then applied to simulate gas-solid turbulent fluidized beds. Simulation results are encouraging as the model is able to predict the dense bottom and dilute top zones along the height of the bed. Comparison of results with experimental data and homogeneous drag model has been made for validation purposes

On a direct approach to quasideterminant solutions of a noncommutative KP equation

A noncommutative version of the KP equation and two families of its solutions expressed as quasideterminants are discussed. The origin of these solutions is explained by means of Darboux and binary Darboux transformations. Additionally, it is shown that these solutions may also be verified directly. This approach is reminiscent of the wronskian technique used for the Hirota bilinear form of the regular, commutative KP equation but, in the noncommutative case, no bilinearising transformation is available.Comment: 11 page

Longitudinal analyses of immune responses to Plasmodium falciparum derived peptides corresponding to novel blood stage antigens in coastal Kenya.

We have recently described 95 predicted alpha-helical coiled-coil peptides derived from putative Plasmodium falciparum erythrocytic stage proteins. Seventy peptides recognized with the highest level of prevalence by sera from three endemic areas were selected for further studies. In this study, we sequentially examined antibody responses to these synthetic peptides in two cohorts of children at risk of clinical malaria in Kilifi district in coastal Kenya, in order to characterize the level of peptide recognition by age, and the role of anti-peptide antibodies in protection from clinical malaria. Antibody levels from 268 children in the first cohort (Chonyi) were assayed against 70 peptides. Thirty-nine peptides were selected for further study in a second cohort (Junju). The rationale for the second cohort was to confirm those peptides identified as protective in the first cohort. The Junju cohort comprised of children aged 1-6 years old (inclusive). Children were actively followed up to identify episodes of febrile malaria in both cohorts. Of the 70 peptides examined, 32 showed significantly (p<0.05) increased antibody recognition in older children and 40 showed significantly increased antibody recognition in parasitaemic children. Ten peptides were associated with a significantly reduced odds ratio (OR) for an episode of clinical malaria in the first cohort of children and two of these peptides (LR146 and AS202.11) were associated with a significantly reduced OR in both cohorts. LR146 is derived from hypothetical protein PFB0145c in PlasmoDB. Previous work has identified this protein as a target of antibodies effective in antibody dependent cellular inhibition (ADCI). The current study substantiates further the potential of protein PFB0145c and also identifies protein PF11_0424 as another likely target of protective antibodies against P. falciparum malaria

Characterization of a process for the in-furnace reduction of NOx, SO2, and HCl by carboxylic salts of calcium

Calcium magnesium acetate has been assessed as an agent for the reduction of NOx, SO2, and HCl, at the pilot scale, in a down-fired combustor operating at 80 kWth. In addition to this, the chemical and physical processes that occur during heating have been investigated. Benchmarking of calcium magnesium acetate with a suite of five other carboxylic salts (calcium magnesium acetate, calcium propionate, calcium acetate, calcium benzoate, magnesium acetate, and calcium formate) has been performed. NOx reduction involves the volatile organic content of the carboxylic salt being released at temperatures of >1000 °C, where the reaction of CHi radicals with NO under fuel-rich conditions can result in some of the NO forming N2 in a “reburning” process. Thermogravimetry-Fourier transform infrared (TG-FTIR) studies identified the nature of the decomposition products from the low- and high-temperature decompositions. In addition, the rate of weight losses were studied to investigate the influence of the organic decomposition on NOx reduction by reburning. In-furnace reductions of SO2 and HCl are aided by the highly porous, particulate residue, which results from the in situ drying, pyrolysis, and calcination processes. Simultaneous reduction of all three pollutants was obtained, and a synergy between SO2 and HCl capture was identified. A mechanism for this inter-relationship has been proposed. Sorbent particle characterization has been performed by collecting the calcined powder from a spray pyrolysis reactor and compared with those produced from a suite of pure carboxylic salts. Physical properties (including porosity, surface area, and decomposition behavior) have been discussed, relative to reductions in NOx and acid gas emissions

Effect of oxy-fuel combustion on ash deposition of pulverized wood pellets

Biomass is a clean alternative fuel to coal in terms of carbon, NOx, and SO2 emissions in the power generation sector. However, ash deposition problems have been a concern with biomass fuels due to the high alkali and residual sulphur contents in the ash forming particles. In this study, the influence of oxy-fuel firing conditions of wood pellets combustion on ash partitioning and deposit formation, were investigated experimentally on a 250-kW pilot scale pulverized furnace and theoretically through chemical equilibrium modelling using the FactSage program. Oxy-fuel combustion case was compared with air-fuel case in this assessment. The results of this study showed that wood pellets had a low tendency for radiation zone slagging, but, had a high fouling tendency in the convective passes. It is possible that oxy-fuel combustion inhibited the release of volatile elements to the gas phase in the initial stages of the combustion, thus reducing the alkali sulphates slagging, increasing however, the alkali sulphate fouling tendencies on the convective passes. Moreover, the effect of the oxy-fuel environment on the ash formation was significant. The chemical equilibrium modelling showed reasonable predictions of the ash behaviour of wood pellets in terms of alkali behaviour and explained to some extent the influence of the oxy environment on ash deposit formation

Experimental investigation of NO reburning during oxy-coal burner staging

This study presents an investigation into the impact of varied burner staging environments on an oxy-fuel flame and the rate of the NO formation and destruction processes. The experimental data was extracted from the use of a 250 kWth down-fired combustion test facility with a scaled-down model of an industrial low-NOx burner (LNB). Two oxy-coal combustion regimes were investigated by varying a fixed flow of oxidant between the secondary and tertiary registers, so as to impact the stoichiometry in the fuel-rich region and flame structure, and using various NO recycling regimes, to test the impact of these different burner configurations on NO reburning. The data was collected by monitoring key emissions in the flue gas and in the flame, as well as temperatures throughout the furnace and the unburned carbon content of the ash. A detailed investigation encompassing the impact of secondary oxidant proportion for different oxidants on NO emissions, together with the quantification of recycled NO destruction, is discussed. This investigation finds that 85 % to 95 % of the recycled NO is destroyed at a range of burner configurations using OF 27 and OF 30 at 170 kWth. In addition to this, NO formation and carbon burnout are found to be significantly affected with changing burner configurations. Further to this, OF 30 flames appear to be more sensitive to burner configuration than OF 27 flames with regards to both NO formation and destruction, possibly due to the decreased density of the OF 30 oxidant. Radial profiles of two burner configurations at OF 27 and OF 30, as well as an axial profile of two burner configurations at OF 30, are analysed. The profiles appear to show that burner staging aids in controlling the products of NO reburning, hence maximising the destruction of recycled NO