Evaluation of fundamental frequency in individuals with normal voice and those with vocal nodules

Introduction: Vocal nodules are non-malignant lesions of vocal cords caused by vocal misuse and abuse. Nodules can be viewed as the reaction of vocal tissue to a constant stress induced by frequent and severe movements. Acoustic signs of people with vocal fold nodules somehow differ from those with normal voice. However, there is no universal agreement on the exact amount difference between acoustics of normal voice and pathologic voice heard at the presence of vocal nodule and this, in turn, has resulted in different reported acoustic measurements. In this study, we used the standardized Rangin Kaman passage for vocal assessment of normal people and patients with voice nodule. Materials and Methods: In a cross-sectional descriptive– analytical study, 20 people with normal voice (10 males and 10 females) and 20 patients with vocal nodules (10 males and 10 females) with an age range of 40 to 59 years were randomly assigned into two age groups of 40 to 59 and 50 to 59 years. Each of these age groups included 10 subjects with normal voice (5 males and 5 females) and 10 ones with bilateral vocal nodules (5 males and 5 females). Thus, 20 voice samples were obtained from each age group. These voice samples were acoustically compared to each other on the basis of fundamental frequency and fundamental frequency variation range. Results: Results showed that the differences in fundamental frequencies was significant when all samples were considered (P = 0.043). For detecting local differences, repeated analysis of variance was performed for men and women separately. In men, significant differences of fundamental frequency were neither observed between normal and pathological samples nor between two age groups as a whole (P = 0.59). In women, differences of mean in fundamental frequency between two age groups were significant (P = 0.007). Conclusion: Mean fundamental frequency analysis can discriminates between normal voice and voice with nodules only in 50 to 59-year age group. Although nodules were recognizable through stroboscope, acoustic signs varied depending on the amount of influence exerted by the nodule on the voice. Keywords: Speech fundamental frequency, Fundamental frequency variation range, Voice, Nodule

Persian Morphologically Segmented Lexicon 0.5

This dataset includes 45300 Persian word forms which are manually segmented into sequences of morphemes

Persian Morphologically Segmented Lexicon 0.5

This dataset includes 45300 Persian word forms which are manually segmented into sequences of morphemes

Highly Emissive Cycloplatinated(II) Complexes Obtained by the Chloride Abstraction from the Complex [Pt(ppy)(PPh3)(Cl)]:Employing Various Silver Salts

In the present investigation, the precursor complex [Pt(ppy)(PPh3)(Cl)], 3, ppy = 2-phenylpyridinyl, undergoes the chloride abstraction reaction using various AgX (X = PF6, BF4, NO3 and CH3COO) salts. Depending on the nature of anions in AgX salts (coordinating or noncoordinating), the products can be neutral or ionic. In the cases of NO3 and CH3COO, they can be coordinated to the Pt center so that the neutral complexes [Pt(ppy)(PPh3)(NO3)], 4a, and [Pt(ppy)(PPh3)(CH3COO)], 4b, are formed. In contrast, the ionic complexes [{Pt(ppy)(PPh3)(CH3CN)}PF6], 5a, and [{Pt(ppy)(PPh3)(CH3CN)}BF4], 5b, can be generated when the AgPF6 ([{Ag(CH3CN)4}PF6]) or AgBF4 ([{Ag(CH3CN)4}BF4]) salts are used in which the PF6 and BF4 stand as counteranions. In these two complexes, CH3CN fills the empty ligand position which can be present as solvent or ligand in the initial silver salts. The structures of the new complexes were accurately deduced from the multinuclear (1H, 31P{1H}, 195Pt{1H}) NMR spectroscopy and further authenticated by X-ray crystallography. Interestingly, the complexes are green emitters under various states and temperature conditions for which nonchelating L/X (PPh3/NO3 or PPh3/CH3COO) and L/L (PPh3/CH3CN) ancillary ligands exist in the structure of cycloplatinated(II) complexes. The photophysical properties of these new complexes, supported by density functional theory (DFT) and time-dependent DFT (TD-DFT) calculations, were investigated by photoluminescence and UV–vis spectroscopies

A C^N Cycloplatinated(II) Fluorido Complex: Photophysical Studies and Csp3‒F Bond Formation

This work reports the synthesis and characterization of a new C^N-based cycloplatinated(II) fluorido complex [Pt(ppy)PPh3)F] involving a Pt‒F bond. The new complex is highly luminescent in green area with a high quantum yield of 94.6% at 77K. A comparison study of the heavier of halogen derivatives reveals a descending emission quantum yield order of F > Cl > Br > I. Time-dependent density functional theory (TD-DFT) calculations ascribe the decreased emission efficiency to the decreasing trend of ILCT transition from F to I, which accounts for the major radiative pathway.</div

Universal Segmentations 1.0 (UniSegments 1.0)

Universal Segmentations (UniSegments) is a collection of lexical resources capturing morphological segmentations harmonised into a cross-linguistically consistent annotation scheme for many languages. The annotation scheme consists of simple tab-separated columns that stores a word and its morphological segmentations, including pieces of information about the word and the segmented units, e.g., part-of-speech categories, type of morphs/morphemes etc. The current public version of the collection contains 38 harmonised segmentation datasets covering 30 different languages