Characterization of Structural Defects in (Cd,Zn)Te Crystals Grown by the Travelling Heater Method

Structural defects and compositional uniformity remain the major problems affecting the performance of (Cd, Zn)Te (CZT) based detector devices. Understanding the mechanism of growth and defect formation is therefore fundamental to improving the crystal quality. In this frame, space experiments for the growth of CZT by the Travelling Heater Method (THM) under microgravity are scheduled. A detailed ground-based program was performed to determine experimental parameters and three CZT crystals were grown by the THM. The structural defects, compositional homogeneity and resistivity of these ground-based crystals were investigated. A ZnTe content variation was observed at the growth interface and a high degree of stress associated with extensive dislocation networks was induced, which propagated into the grown crystal region according to the birefringence and X-ray White Beam Topography (XWBT) results. By adjusting the growth parameters, the ZnTe variations and the resulting stress were efficiently reduced. In addition, it was revealed that large inclusions and grain boundaries can generate a high degree of stress, leading to the formation of dislocation slip bands and subgrain boundaries. The dominant defects, including grain boundaries, dislocation networks and cracks in the interior of crystals, led to the resistivity variation in the crystals. The bulk resistivity of the as-grown crystals ranged from 109 Ωcm to 1010 Ωcm

Results of Theoretical Studies to Substantiate the Parameters of Multi-blade Rotary-type Working Bodies

The article presents the results of theoretical studies of the technological process of operation of multi-blade working bodies of rotary type, intended for the distribution of solid organic fertilizers. To determine the length of the blades of the last row of rotors, and accordingly the overall dimensions of the spreader, theoretical dependences of the range of fertilizer particles on the radius of the blades are obtained, which made it possible to determine the size of the blades that provide the required performance of the rotary spreader. Considering the uniform distribution of fertilizer particles over the sieving width, the dependences of the “limiting” zone of loading of the blades (the maximum thickness of the layer of fertilizers captured by one blade) on the angle of their inclination at different lengths of the blades were obtained, which showed that when applying fertilizers with medium and large doses, several rows of blades. Computational experiments were carried out, during which, the number of rows of blades and the ratio of the lengths of the blades of different rows were determined to obtain the smallest unevenness depending on different doses of fertilizer application. As a result of mathematical modeling, the dependences of the working insertion width on the angle of inclination of the blades of the rotor rows relative to the radial position are obtained for various second-time supply of material, using which rational values of the angle of inclination of the blades are found

Interface Superconductivity in a Dirac Semimetal NiTe2

We experimentally investigated charge transport through a single planar junction between a NiTe2 Dirac semimetal and a normal gold lead. At milli-Kelvin temperatures, we observe non-Ohmic dV/dI(V) behavior resembling Andreev reflection at a superconductor–normal metal interface, while NiTe2 bulk remains non-superconducting. The conclusion on superconductivity is also supported by the suppression of the effect by temperature and magnetic field. In analogy with the known results for Cd3As2 Dirac semimetal, we connect this behavior with interfacial superconductivity due to the flat-band formation at the Au-NiTe2 interface. Since the flat-band and topological surface states are closely connected, the claim on the flat-band-induced superconductivity is also supported by the Josephson current through the topological surface states on the pristine NiTe2 surface. We demonstrate the pronounced Josephson diode effect, which results from the momentum shift of the topological surface states of NiTe2 under an in-plane magnetic field

Variation of Surface Nanostructures on (100) PbS Single Crystals during Argon Plasma Treatment

The nanostructuring of the (100) PbS single crystal surface was studied under varying argon plasma treatment conditions. The initial PbS single crystals were grown by high-pressure vertical zone melting, cut into wafer samples, and polished. Subsequently, the PbS single crystals were treated with inductively coupled argon plasma under varying treatment parameters such as ion energy and sputtering time. Plasma treatment with ions at a minimum energy of 25 eV resulted in the formation of nanotips with heights of 30–50 nm. When the ion energy was increased to 75–200 eV, two types of structures formed on the surface: high submicron cones and arrays of nanostructures with various shapes. In particular, the 120 s plasma treatment formed specific cruciform nanostructures with lateral orthogonal elements oriented in four <100> directions. In contrast, plasma treatment with an ion energy of 75 eV for 180 s led to the formation of submicron quasi-spherical lead structures with diameters of 250–600 nm. The nanostructuring mechanisms included a surface micromasking mechanism with lead formation and the vapor–liquid–solid mechanism, with liquid lead droplets acting as self-forming micromasks and growth catalysts depending on the plasma treatment conditions (sputtering time and rate)

Variation of Surface Nanostructures on (100) PbS Single Crystals during Argon Plasma Treatment

The nanostructuring of the (100) PbS single crystal surface was studied under varying argon plasma treatment conditions. The initial PbS single crystals were grown by high-pressure vertical zone melting, cut into wafer samples, and polished. Subsequently, the PbS single crystals were treated with inductively coupled argon plasma under varying treatment parameters such as ion energy and sputtering time. Plasma treatment with ions at a minimum energy of 25 eV resulted in the formation of nanotips with heights of 30–50 nm. When the ion energy was increased to 75–200 eV, two types of structures formed on the surface: high submicron cones and arrays of nanostructures with various shapes. In particular, the 120 s plasma treatment formed specific cruciform nanostructures with lateral orthogonal elements oriented in four directions. In contrast, plasma treatment with an ion energy of 75 eV for 180 s led to the formation of submicron quasi-spherical lead structures with diameters of 250–600 nm. The nanostructuring mechanisms included a surface micromasking mechanism with lead formation and the vapor–liquid–solid mechanism, with liquid lead droplets acting as self-forming micromasks and growth catalysts depending on the plasma treatment conditions (sputtering time and rate)