Kramers' formula for chemical reactions in the context of Wasserstein gradient flows

We derive Kramers' formula as singular limit of the Fokker-Planck equation with double-well potential. The convergence proof is based on the Rayleigh principle of the underlying Wasserstein gradient structure and complements a recent result by Peletier, Savar\'e and Veneroni.Comment: revised proofs, 12 pages, 1 figur

Non-self-similar behavior in the LSW theory of Ostwald ripening

The classical Lifshitz-Slyozov-Wagner theory of domain coarsening predicts asymptotically self-similar behavior for the size distribution of a dilute system of particles that evolve by diffusional mass transfer with a common mean field. Here we consider the long-time behavior of measure-valued solutions for systems in which particle size is uniformly bounded, i.e., for initial measures of compact support. We prove that the long-time behavior of the size distribution depends sensitively on the initial distribution of the largest particles in the system. Convergence to the classically predicted smooth similarity solution is impossible if the initial distribution function is comparable to any finite power of distance to the end of the support. We give a necessary criterion for convergence to other self-similar solutions, and conditional stability theorems for some such solutions. For a dense set of initial data, convergence to any self-similar solution is impossible.Comment: 31 pages, LaTeX2e; Revised version, to appear in J. Stat. Phy

Optimal bounds for self-similar solutions to coagulation equations with product kernel

We consider mass-conserving self-similar solutions of Smoluchowski's coagulation equation with multiplicative kernel of homogeneity $2l\lambda \in (0,1)$. We establish rigorously that such solutions exhibit a singular behavior of the form $x^{-(1+2\lambda)}$ as $x \to 0$. This property had been conjectured, but only weaker results had been available up to now

Self-similar gelling solutions for the coagulation equation with diagonal kernel

We consider Smoluchowski's coagulation equation in the case of the diagonal kernel with homogeneity $\gamma>1$. In this case the phenomenon of gelation occurs and solutions lose mass at some finite time. The problem of the existence of self-similar solutions involves a free parameter $b$, and one expects that a physically relevant solution (i.e. nonnegative and with sufficiently fast decay at infinity) exists for a single value of $b$, depending on the homogeneity $\gamma$. We prove this picture rigorously for large values of $\gamma$. In the general case, we discuss in detail the behaviour of solutions to the self-similar equation as the parameter $b$ changes

Weak solutions to lubrication equations in the presence of strong slippage

The existence of global weak solutions is proved for one-dimensional lubrication models that describe the dewetting process of nanoscopic thin polymer films on hydrophobyzed substrates and take account of large slippage at the polymer-substrate interface. The convergence of these solutions as either the Reynolds number or the capillarity goes to zero, as well as their limiting behaviour as the slip length goes to zero or infinity are investigated

Dynamics and self-similarity in min-driven clustering

We study a mean-field model for a clustering process that may be described informally as follows. At each step a random integer $k$ is chosen with probability $p_k$, and the smallest cluster merges with $k$ randomly chosen clusters. We prove that the model determines a continuous dynamical system on the space of probability measures supported in $(0,\infty)$, and we establish necessary and sufficient conditions for approach to self-similar form. We also characterize eternal solutions for this model via a Levy-Khintchine formula. The analysis is based on an explicit solution formula discovered by Gallay and Mielke, extended using a careful choice of time scale

Self-similar solutions with fat tails for a coagulation equation with diagonal kernel

We consider self-similar solutions of Smoluchowski's coagulation equation with a diagonal kernel of homogeneity $\gamma < 1$. We show that there exists a family of second-kind self-similar solutions with power-law behavior $x^{-(1+\rho)}$ as $x \to \infty$ with $\rho \in (\gamma,1)$. To our knowledge this is the first example of a non-solvable kernel for which the existence of such a family has been established