66 research outputs found
Covalency effects on the magnetism of EuRh2P2
In experiments, the ternary Eu pnictide EuRh2P2 shows an unusual coexistence
of a non-integral Eu valence of about 2.2 and a rather high Neel temperature of
50 K. In this paper, we present a model which explains the non-integral Eu
valence via covalent bonding of the Eu 4f-orbitals to P2 molecular orbitals. In
contrast to intermediate valence models where the hybridization with
delocalized conduction band electrons is known to suppress magnetic ordering
temperatures to at most a few Kelvin, covalent hybridization to the localized
P2 orbitals avoids this suppression. Using perturbation theory we calculate the
valence, the high temperature susceptibility, the Eu single-ion anisotropy and
the superexchange couplings of nearest and next-nearest neighbouring Eu ions.
The model predicts a tetragonal anisotropy of the Curie constants. We suggest
an experimental investigation of this anisotropy using single crystals. From
experimental values of the valence and the two Curie constants, the three free
parameters of our model can be determined.Comment: 9 pages, 5 figures, submitted to J. Phys.: Condens. Matte
Anisotropic effect of field on the orthorhombic-to-tetragonal transition in the striped cuprate (La,Nd)_{2-x}Sr_xCuO_4
The Nd-doped cuprate La_{2-y-x}Nd_ySr_xCuO_4 displays a first-order phase
transition at T_d (= 74 K for x=0.10, y = 0.60) to a low-temperature tetragonal
(LTT) phase. A magnetic field H applied || the a-axis leads to an increase in
T_d, whereas T_d is decreased when H || c. These effects show that magnetic
ordering involving both Nd and Cu spins plays a key role in driving the LTO-LTT
transition. Related anisotropic effects are observed in the uniform
susceptibility and the in-plane magnetoresistance.Comment: 5 pages, 5 figure
Local Magnetic Order vs. Superconductivity in a Layered Cuprate
We report on the phase diagram for charge-stripe order in
La(1.6-x)Nd(0.4)Sr(x)CuO(4), determined by neutron and x-ray scattering studies
and resistivity measurements. From an analysis of the in-plane resistivity
motivated by recent nuclear-quadrupole-resonance studies, we conclude that the
transition temperature for local charge ordering decreases monotonically with
x, and hence that local antiferromagnetic order is uniquely correlated with the
anomalous depression of superconductivity at x = 1/8. This result is consistent
with theories in which superconductivity depends on the existence of
charge-stripe correlations.Comment: 4 pages, 4 figures; introduction revised, Fig. 3 removed, last figure
replace
Phase Separation Models for Cuprate Stripe Arrays
An electronic phase separation model provides a natural explanation for a
large variety of experimental results in the cuprates, including evidence for
both stripes and larger domains, and a termination of the phase separation in
the slightly overdoped regime, when the average hole density equals that on the
charged stripes. Several models are presented for charged stripes, showing how
density waves, superconductivity, and strong correlations compete with quantum
size effects (QSEs) in narrow stripes. The energy bands associated with the
charged stripes develop in the middle of the Mott gap, and the splitting of
these bands can be understood by considering the QSE on a single ladder.Comment: significant revisions: includes island phase, 16 eps figures, revte
How to detect fluctuating order in the high-temperature superconductors
We discuss fluctuating order in a quantum disordered phase proximate to a
quantum critical point, with particular emphasis on fluctuating stripe order.
Optimal strategies for extracting information concerning such local order from
experiments are derived with emphasis on neutron scattering and scanning
tunneling microscopy. These ideas are tested by application to two model
systems - the exactly solvable one dimensional electron gas with an impurity,
and a weakly-interacting 2D electron gas. We extensively review experiments on
the cuprate high-temperature superconductors which can be analyzed using these
strategies. We adduce evidence that stripe correlations are widespread in the
cuprates. Finally, we compare and contrast the advantages of two limiting
perspectives on the high-temperature superconductor: weak coupling, in which
correlation effects are treated as a perturbation on an underlying metallic
(although renormalized) Fermi liquid state, and strong coupling, in which the
magnetism is associated with well defined localized spins, and stripes are
viewed as a form of micro-phase separation. We present quantitative indicators
that the latter view better accounts for the observed stripe phenomena in the
cuprates.Comment: 43 pages, 11 figures, submitted to RMP; extensively revised and
greatly improved text; one new figure, one new section, two new appendices
and more reference
Violations of local stochastic independence exaggerate scalability in Mokken scaling analysis of the Chinese Mandarin SF-36
To be objective in Experimental Phenomenology: a Psychophysics application
Background Several scientific psychologists consider the approach for the study of perceptive problems of the Experimental Phenomenology is problematic, namely that the phenomenological demonstrations are subjectively based and they do not produce quantifiable results. Aim The aim of this study is to show that Experimental Phenomenology can lead to conclusions objective and quantifiable and propose a procedure allowing to obtain objective measuring using the Rasch mathematical model able to describe the experimental data gathered in Experimental Phenomenology procedures. Method In order to demonstrate this, a Psychophysics simulated study is proposed. Results/conclusions It is possible to carry out a fundamental measurement starting from Experimental Phenomenology by way of the Theory of Conjoint Measurement
3D printed sample holder for high temperature polymer electrolyte fuel cells (HT-PEFC) in-operando EPR and NMR
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