Disorder-Induced Order in Quantum XY Chains

We observe signatures of disorder-induced order in 1D XY spin chains with an external, site-dependent uni-axial random field within the XY plane. We numerically investigate signatures of a quantum phase transition at T=0, in particular an upsurge of the magnetization in the direction orthogonal to the external magnetic field, and the scaling of the block-entropy with the amplitude of this field. Also, we discuss possible realizations of this effect in ultra-cold atom experiments

CO2 sensing with chemoresistive Nd2O2CO3 sensors - Operando insights

AbstractIn this work the sensing of Nd2O2CO3-based chemoresistive CO2 sensor was investigated combining DRIFT and DC-resistance measurements. Besides the already reported effect of CO2 exposure, we found that exposure to CO determines comparable effects and that the presence of oxygen in the background is not important. The humidity significantly influences the response for both gases. The spectroscopic results reveal that the exposure to both CO and CO2 consumes the water-related surface species – the rooted-hydroxyls being the electrically active one – and increases the concentration of carbonates; the decrease of the rooted-hydroxyls is probably the cause of the resistance increase

Rare earth oxycarbonates as a material class for chemoresistive CO2 gas sensors

AbstractIn this work we compare the CO2 gas sensing properties of two new materials synthesized from rare earth hydroxide (La(OH)3,Pr(OH)3) precursors, with the already reported ones for neodymium oxycarbonate, which was synthesized from the corresponding Nd(OH)3 precursor. In-situ XRD measurements show that by following similar thermal treatment, praseodymium hydroxide is transforming to the metal oxide while lanthanum hydroxide forms an oxycarbonate, like in the case of neodymium. The chemoresistive effects we found for the lanthanum oxycarbonate were even higher than the ones recorded for the neodymium oxycarbonate; for the praseodymium metal oxide we could not find any CO2 sensitivity. Accordingly, we think that the condition for CO2 sensing is the formation of the rare earth oxycarbonate

The ground state of binary systems with a periodic modulation of the linear coupling

We consider a quasi-one-dimensional two-component systm, described by a pair of Nonlinear Schr\"{o}dinger/Gross-Pitaevskii Equations (NLSEs/GPEs), which are coupled by the linear mixing, with local strength $\Omega$, and by the nonlinear incoherent interaction. We assume the self-repulsive nonlinearity in both components, and include effects of a harmonic trapping potential. The model may be realized in terms of periodically modulated slab waveguides in nonlinear optics, and in Bose-Einstein condensates too. Depending on the strengths of the linear and nonlinear couplings between the components, the ground states (GSs) in such binary systems may be symmetric or asymmetric. In this work, we introduce a periodic spatial modulation of the linear coupling, making $\Omega$ an odd, or even function of the coordinate. The sign flips of $\Omega (x)$ strongly modify the structure of the GS in the binary system, as the relative sign of its components tends to lock to the local sign of $\Omega$. Using a systematic numerical analysis, and an analytical approximation, we demonstrate that the GS of the trapped system contains one or several kinks (dark solitons) in one component, while the other component does not change its sign. Final results are presented in the form of maps showing the number of kinks in the GS as a function of the system's parameters, with the odd/even modulation function giving rise to the odd/even number of the kinks. The modulation of $\Omega (x)$ also produces a strong effect on the transition between states with nearly equal and strongly unequal amplitudes of the two components.Comment: 8 pages, 3 figure

In-depth mesocrystal formation analysis of microwave-assisted synthesis of LiMnPO4nanostructures in organic solution

In the present work, we report on the preparation of LiMnPO4 (lithiophilite) nanorods and mesocrystals composed of self-assembled rod subunits employing microwave-assisted precipitation with processing times on the time scale of minutes. Starting from metal salt precursors and H3PO4 as phosphate source, single-phase LiMnPO4 powders with grain sizes of approx. 35 and 65 nm with varying morphologies were obtained by tailoring the synthesis conditions using rac-1-phenylethanol as solvent. The mesocrystal formation, microstructure and phase composition were determined by electron microscopy, nitrogen physisorption, X-ray diffraction (including Rietveld refinement), dynamic light scattering, X-ray absorption and X-ray photoelectron spectroscopy, and other techniques. In addition, we investigated the formed organic matter by gas chromatography coupled with mass spectrometry in order to gain a deeper understanding of the dissolution\u2013precipitation process. Also, we demonstrate that the obtained LiMnPO4 nanocrystals can be redispersed in polar solvents such as ethanol and dimethylformamide and are suitable as building blocks for the fabrication of nanofibers via electrospinning

Elastic behaviour of the carotid artery in intact spontaneously hypertensive rats

Intact spontaneously hypertensive rats (SHR) were studied to assess the effect of prolonged antihypertensive treatment on the elastic behaviour of the external carotid artery. Thirty-week-old SHR received the ACE inhibitor captopril, the ateriolar dilator hydralazine or their vehicle for 6 weeks. These rats were compared to normotensive, vehicle treated WKY rats. The internal diameter of the carotid artery was measured continuously in halothane-anaesthetized rats using an echo-tracking device, and intra-arterial pressure was also monitored continuously, on the controlateral side. Captopril- and hydralazinetreated SHR as well as normotensive controls had similar blood pressure values. No significant shift in the distensibility-pressure curves was observed among vehicle-treated SHR and WKY rats or the SHR which had received captopril or hydralazine. Histological examination of the carotid artery fixed ex vivo with paraformaldehyde showed a significant increase in cross-sectional area in vehicle-treated SHR as compared to their normotensive counterparts. These results therefore suggest that the elastic behaviour of elastic arteries is not necessarily altered by the structural changes developing in response to hypertensio

Disorder-induced phase control in superfluid fermi-bose mixtures

Abstract -We consider a mixture of a superfluid Fermi gas of ultracold atoms and a BoseEinstein condensate of molecules possessing a continuous U (1) (relative phase) symmetry. We study the effects of a spatially random photo-associative-dissociative symmetry-breaking coupling of the systems. Such coupling allows one to control the relative phase between a superfluid order parameter of the Fermi system and the condensate wave function of molecules for temperatures below the Bardeen-Cooper-Schriefer critical temperature. The presented mechanism of phase control belongs to the general class of phenomena in which disorder interacts with continuous symmetry. Our results show the robustness and wide range of applicability of disorder-induced order and are valid for both disordered and regular couplings. Here, the effect is studied in the case of interacting fermionic and bosonic gases in the superfluid phase