Remote atmospheric pressure plasma for improving acid-base surface properties of PEEK polymer: relevance to coating adhesion

Our study focuses on a remote atmospheric pressure plasma for the improvement of polymer surface reactivity. From the perspective of linking surface modifications to adhesives performances, wettability measurements are made using two models (Owens-Wendt-Rabel-Kaelble and Van Oss-Good-Chaudhury). This study is a contribution to correlate wettability with adhesion results obtained with three-point bending test. Acid-base properties of the treated polymeric surfaces are discussed according to the Lewis’s theory

Alimentation électrique des dispositifs à décharge à barrière diélectrique (DBD)

L’utilisation d’une Décharge contrôlée par Barrière Diélectrique (DBD) permet d’obtenir un plasma froid à pression atmosphérique dont une des utilisations est le traitement de surface. Actuellement, de tels dispositifs sont alimentés par des sources de tension variable (amplitude, fréquence) : la décharge obtenue est le plus souvent filamentaire (défavorable à la qualité du traitement de surface), notamment lorsque l’on souhaite transmettre une puissance élevée. Des études récentes menées pour l’alimentation de lampes à excimères [1] ont montré l’intérêt de remplacer la source de tension par une source de courant, afin d’obtenir la décharge sur une plus grande plage de puissance et de fréquence, de disposer de degrés de liberté permettant le contrôle de la puissance transmise. Cet article est dédié à l’étude théorique et expérimentale d’une structure d’alimentation électrique de ce type

Characterization of argon dielectric barrier discharges applied to ethyl lactate plasma polymerization

The influence of the input voltage frequency (35 and 150 kHz), interelectrode gap (1 and 2mm) and precursor concentration (250, 350, and 450 ppm) on the electron temperature (Te), number density of metastable Ar atoms (n(Arm)), and discharge current density (proportional to the electron density ne) is studied in an argon-ethyl lactate dielectric barrier discharge (DBD). An argon-ammonia Penning mixture is also considered as reference. These results are correlated to the chemistry (XPS, IR) and topography (AFM) of the ethyl-lactate-based plasma polymer coatings. Low Te values from 0.3 to 0.5 eV were obtained for all discharges. This observation, in addition to resemblances with the Ar–NH3 mixture, suggested that the ionization kinetics of ethyl lactate-based discharges is driven by Penning reactions. Among the investigated parameters, the dissipated power obtained through changes of the excitation frequency had the largest impact on both the coatings properties and the discharge behavior

Role of substrate outgassing on the formation dynamics of either hydrophilic or hydrophobic wood surfaces in atmospheric-pressure, organosilicon plasmas

This work examines the influence of substrate outgassing on the deposition dynamics of either hydrophilic or hydrophobic coatings on wood surfaces in organosilicon, dielectric barrier discharges. Sugar maple and black spruce wood samples were placed on the bottom electrode and the discharge was sustained in N2–HMDSO (hexamethyldisiloxane) gas mixtures by applying a 24 kV peak-to-peak voltage at 2 kHz. Current–voltage characteristics revealed a transition from a filamentary to a homogeneous discharge with increasing plasma treatment time, t. Based on opticalemission spectroscopy, the filamentary behaviorwas ascribed to the release of air and humidity from the wood substrate following discharge exposure which produced significant quenching of N2 metastables. This effect vanished at longer treatment times due to the nearly complete “pumping” of products from the wood substrate and the progressive deposition of a “barrier” layer. Analysis of the surface wettability through static, water contact angles (WCAs) and of the surface composition through Fourier-Transform-Infra-Red-Spectroscopy and X-ray-Photoelectron-Spectroscopy indicated that for t b 10 min, the wood surface was more hydrophilic due to the formation of a SiOx layer, a typical behavior for HMDSO deposition in presence of oxygen. On the other hand, for t > 10 min, the static WCA increased up to ~140° due to the deposition of hydrophobic Si(CH3)3-O-Si(CH3)2, Si(CH3)3, and Si(CH3)2 functional groups

The snow avalanches risk on Alpine roads network

Road accessibility is highly strategic for the maintenance of economic activities but also for the emergency services. In mountains, snow avalanches are a particularly strong threat because, in addition to the victims and direct damage, they cause a loss of accessibility more or less prolonged when the networks are already strongly altered by seasonal closures. Specifically, risk to traffic roads caused by snow avalanches has been very rarely assessed at a regional scale. To assess the physical, human and functional vulnerabilities of road networks in three Alpine departments (Alpes-de-Haute-Provence, Hautes-Alpes, Alpes-Maritimes), the first step of this research was to geo-locate and harmonize within a GIS all information sources about the consequences of avalanches on roads. This allowed identifying the road impacts of avalanches since 1937, to characterize the intensity and typology of damages and to evaluate the functional vulnerability of networks. The second step was to produce simple risk indexes of dysfunction and isolation at this regional scale. These indicators were modeled using the graph theory in a GIS framework, integrating avalanche activity indicators derived from the past activity with the road network. The obtained output maps should facilitate the decision support for crisis management and a comparative spatial analysis at the regional scale

The surface protein HvgA mediates group B streptococcus hypervirulence and meningeal tropism in neonates

Lethal meningitis triggered by the hypervirulent group B streptococcus clone ST-17 is mediated by a novel surface protein called HvgA

Transition from diffuse to self-organized discharge in a high frequency dielectric barrier discharge

Depending on the operating conditions, different regimes can be obtained in a dielectric barrier discharge (DBD): filamentary, diffuse (also called homogeneous) or self-organized. For a plane-to-plane DBD operated at high frequency (160 kHz) and at atmospheric pressure in helium gas, we show that the addition of a small amount of nitrogen induces a transition from the diffuse regime to a self-organized regime characterized by the appearance of filaments at the exit of the discharge. In this paper, we detail mechanisms that could be responsible of the transition from diffuse mode to this self-organized mode. We point out the critical role of the power supply and the importance of the gas memory effect from one discharge to the following one on the transition to the self-organised mode. The self-organized mode is usually attributed to a surface memory effect. In this work, we show an additional involvement of the gas memory effect on the self-organized mode

PHYSICO-CHIMIE ET REGIMES DES DECHARGES CONTROLEES PAR BARRIERE DIELECTRIQUE EN MELANGES AZOTE - GAZ OXYDANT - SILANE. APPLICATION A L'ACTIVATION DE SURFACES POLYMERES ET AUX DEPOTS

TOULOUSE3-BU Sciences (315552104) / SudocSudocFranceF

Experimental investigations of a remote atmospheric pressure plasma by electrical diagnostics and related effects on polymer composite surfaces

Surface activation of Carbon Fiber Reinforced Polymers (CFRP) using (Poly-EtherEtherKetone) (PEEK) matrices is required to achieve strong and long-term adherent painting on the composite. Among the different techniques, an industrial atmospheric pressure remote plasma has been used in this work to treat PEEK CFRP surfaces. The characterization of this device by means of electrical diagnostics related to the effect of such post-discharge on the surface modifications is discussed. Firstly, electrical characteristics of the discharge show fairly high currents associated to high voltages which suggest a nonestablished and cold arc. Power consumed by the electrical supply associated to post-discharge length and surface temperatures allowed a better understanding of the industrial device. Secondly, the effects of plasma on surface chemistry and topography are analyzed by water contact angle measurements, X-ray Photoelectron Spectroscopy (XPS) and Atomic Force Microscopy (AFM). Investigations showed that treated surfaces exhibited better hydrophilicity mainly due to an incorporation of oxygen containing groups (up to 8.4% more) under air plasma whereas an increase of the nanoroughness and specific surface is preponderant under nitrogen plasma. Different hydrophilic capabilities of the surface obtained in air and nitrogen gas plasmas highlight a potential optimization of activation performances according to industrial specification