52,424 research outputs found
Influence of temperature and the role of chromium on the kinetics of sulfidation of 310 stainless steel
The sulfidation of 310 stainless steel was studied over the temperature range from 910 K to 1285 K. By adjusting the ratio of hydrogen sulfide, variations in sulfur potential were obtained. The effect of temperature on sulfidation was determined at three different sulfur potentials: 39/sqNm, 0.014/sqNm, and 0.00015/sqNm. All sulfide scales contained one or two surface layers in addition to a subscale. The second outer layer (OL-II), furthest from the alloy, contained primarily Fe-Ni-S. The first outer layer (OL-I), nearest the subscale, contained FE-Cr-S. The subscale consisted of sulfide inclusions in the metal matrix. At a given temperature and sulfur potential, the weight gain data obeyed the parabolic rate law after an initial transient period. The parabolic rate constants obtained at the sulfur potential of 39/sqNm did not show a break when the logarithm of the rate constant was plotted as a function of the inverse of absolute temperature. Sulfidation carried out at sulfur potentials below 0.02/sqNm, however, did show a break at 1145 K, which is termed as the transition temperature. This break was found to be associated with the changes which had occurred in the Fe:Cr ratio of OL-I. Below the transition temperature the activation energy was found to be approximately 125 kj/mole. Above the transition temperature the rate of sulfidation decreased with temperature but dependent on the Fe:Cr ratio in the iron-chromium-sulfide layers of the OL-I. A reaction mechanism consistent with the experimental results has been proposed
Sulfidation of 310 stainless steel at sulfur potentials encountered in coal conversion systems
The sulfidation of SAE 310 stainless steel was carried out in gas mixtures of hydrogen and hydrogen sulfide over a range of sulfur potentials anticipated in advanced coal gasification processes. The kinetics, composition, and morphology of sulfide scale formation were studied at a fixed temperature of 1,065 K over a range of sulfur potentials from .00015 Nm to the -2nd power to 900 Nm to the -2nd power. At all sulfur potentials investigated, the sulfide scales were found to be multilayered. The relative thickness of the individual layers as well as the composition was found to depend on the sulfur potential. The reaction was found to obey the parabolic rate law after an initial transient period. Considerably longer transient periods were found to be due to unsteady state conditions resulting from compositional variations in the spinel layer. The sulfur pressure dependence on the parabolic rate constant was found to best fit the equation K sub p equals const. (P sub S2) to the 1/nth power, where n equals 3.7. The growth of the outer layers was found to be primarily due to the diffusion of metal ions, iron being the predominant species. The inner layer growth was due to the dissociation of the primary product at the alloy scale interface and depended on the activity of chromium
Long range order in the classical kagome antiferromagnet: effective Hamiltonian approach
Following Huse and Rutenberg [Phys. Rev. B 45, 7536 (1992)], I argue the
classical Heisenberg antiferromagnet on the kagom\'e lattice has long-range
spin order of the type (modulo gradual orientation
fluctuations of the spins' plane). I start from the effective quartic
Hamiltonian for the soft (out of plane) spin fluctuation modes, and treat as a
perturbation those terms which depend on the discrete coplanar state. Soft mode
correlations, which become the coefficients of a discrete effective
Hamiltonian, are estimated analytically.Comment: 4pp, no figures. Converted to PRB format, extensive revisions/some
reorderings to improve clarity; some cut
Progress in Electroweak Baryogenesis
Recent work on generating the excess of matter over antimatter in the early
universe during the electroweak phase transition is reviewed.Comment: 50 pages (figures on request), uses harvmac (table of contents
correct for "l" format), UCSD-93-2,BU-HEP-93-
Localization transitions in non-Hermitian quantum mechanics
We study the localization transitions which arise in both one and two
dimensions when quantum mechanical particles described by a random
Schr\"odinger equation are subjected to a constant imaginary vector potential.
A path-integral formulation relates the transition to flux lines depinned from
columnar defects by a transverse magnetic field in superconductors. The theory
predicts that the transverse Meissner effect is accompanied by stretched
exponential relaxation of the field into the bulk and a diverging penetration
depth at the transition.Comment: 4 pages (latex) with 3 figures (epsf) embedded in the text using the
style file epsf.st
Free Energies of Isolated 5- and 7-fold Disclinations in Hexatic Membranes
We examine the shapes and energies of 5- and 7-fold disclinations in
low-temperature hexatic membranes. These defects buckle at different values of
the ratio of the bending rigidity, , to the hexatic stiffness constant,
, suggesting {\em two} distinct Kosterlitz-Thouless defect proliferation
temperatures. Seven-fold disclinations are studied in detail numerically for
arbitrary . We argue that thermal fluctuations always drive
into an ``unbuckled'' regime at long wavelengths, so that
disclinations should, in fact, proliferate at the {\em same} critical
temperature. We show analytically that both types of defects have power law
shapes with continuously variable exponents in the ``unbuckled'' regime.
Thermal fluctuations then lock in specific power laws at long wavelengths,
which we calculate for 5- and 7-fold defects at low temperatures.Comment: LaTeX format. 17 pages. To appear in Phys. Rev.
A high-Reynolds-number seal test facility: Facility description and preliminary test data
A facility has been developed for testing the leakage and rotordynamic characteristics of interstage-seal configurations for the HPFTP (High Pressure Fuel Turbopump) of the SSME (Space Shuttle Main Engine). Axial Reynolds numbers on the order of 400,000 are realized in the test facility by using a Dupont freon fluid called Halon (CBrF3). The kinematic viscosity of Halon is of the same order as the liquid hydrogen used in the HPFTP. Initial testing has focused on the current flight configurations (a three-segment, stepped unit) and a convergent-taper candidate
The generalized Fenyes-Nelson model for free scalar field theory
The generalized Fenyes--Nelson model of quantum mechanics is applied to the
free scalar field. The resulting Markov field is equivalent to the Euclidean
Markov field with the times scaled by a common factor which depends on the
diffusion parameter. This result is consistent between Guerra's earlier work on
stochastic quantization of scalar fields. It suggests a deep connection between
Euclidean field theory and the stochastic interpretation of quantum mechanics.
The question of Lorentz covariance is also discussed.Comment: 6 page
Some studies on a solid state sulfur probe for coal gasification systems
Measurements on the solid electrolyte cell (Ar + H(2) + H(2)S/CaS + CaF(2) + (Pt)//CaF(2)//(Pt) + CaF(2) + CaS/H(2) + H(2)+Ar) show that the emf of the cell is directly related to the difference in sulfur potentials established at the Ar + H(2) + H(2)S/electrode interfaces. The electrodes convert the sulfur potential gradient across the calcium fluoride electrolyte into an equivalent fluorine potential gradient. Response time of the probe varies from approximately 9 hr at 990 K to 2.5 hr at 1225 K. The conversion of calcium sulfide and/or calcium fluoride into calcium oxide is not a problem anticipated in commercial coal gasification systems. Suggestions are presented for improving the cell for such commercial applications
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