297 research outputs found

    The Biogeochemistry of iron, zinc and cobalt in the Atlantic Ocean: the Atlantic Meridional Transect and UK GEOTRACES sections

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    Between 40 % and 50 % of the Earthā€™s primary production occurs in marine environments, primarily by phytoplankton. The trace metal micronutrients iron, zinc and cobalt are known to exert a significant biological control on phytoplankton productivity by serving as essential active centres in enzymatic processes such as inorganic carbon, nitrogen and phosphorus acquisition. The distributions and biogeochemistries of iron, zinc and cobalt therefore, have the potential to impact upon the global carbon cycle and hence climate. This research involves investigations into the biogeochemical cycling of iron, zinc and cobalt in the Atlantic Ocean. Iron measurements were conducted during October and November 2009 to determine the distribution and biogeochemistry of iron in the upper water column of the Atlantic Ocean along an Atlantic Meridional Transect (AMT-19). In addition, deck board incubation experiments were performed to establish the role of iron in controlling rates of di-nitrogen (N2) fixation in the North Atlantic. The distribution patterns and biogeochemistries of iron, zinc and cobalt in the South Atlantic at 40Ā° S were determined during the UK GEOTRACES Section GA10 cruises of October 2010 and December 2011 to January 2012. Iron distributions in North Atlantic surface waters were primarily controlled by the transport and deposition of atmospheric dust particles. In the North Atlantic, elevated surface dissolved iron concentrations (0.50 - 1.65 nM) were associated with wet and dry deposition of Saharan dust between 4 and 29Ā° N. To the south of 4Ā° N, surface dissolved iron concentrations were markedly reduced (0.14 nM) indicating that high precipitation rates in the Inter-Tropical Convergence Zone (4 - 10Ā° N) formed a barrier to the large-scale transport of Saharan dust particles, thus iron, to the South Atlantic. Here, the low surface dissolved iron concentrations were balanced by a total dissolvable iron flux out of the surface mixed layer (3.2 Āµmol m-2 y-1) that was comparable to atmospheric input estimates. Nitrogen fixation rates in the North Atlantic were highest (0.3 ā€“ 1.1 nmol L-1 d-1) where surface dissolved iron concentrations were elevated (1.02 nM) and decreased with increasing latitude as iron decreased. Hence, iron variability in the North Atlantic was sufficient to influence nitrogen fixation over a large spatial scale. In the South Atlantic Ocean at 40Ā° S, the vertical and horizontal distributions of dissolved zinc and cobalt showed distinct gradients associated with the water masses present. Zinc concentrations ranged from 15 pM in open ocean surface waters to 8 nM in Antarctic Bottom Waters, whilst cobalt ranged from 2 pM to 80 pM in intermediate waters and was scavenged in deeper waters. Growth limiting mixed layer zinc concentrations resulted from the lack of a direct return path for zinc to the South Atlantic pycnocline with Sub-Antarctic Mode Water. Low zinc in this return path was identified by a linear correlation between zinc and soluble reactive phosphorus that showed a kink at ~ 500 m, much deeper than that observed in other oceanographic regimes. A seasonal study in the Southeast Atlantic revealed that the depletion of zinc over spring-summer periods resulted in an increase in the nutritional importance of cobalt and a shift towards phytoplankton with a cellular preference for cobalt over zinc and/or the ability to co-substitute these two trace metals at the molecular level. These key findings demonstrate the physico-chemical and biological influences that interact to control the distributions and biogeochemistries of iron, zinc and cobalt across diverse oceanographic regimes of the Atlantic Ocean, provide the first examination of zinc and cobalt biogeochemistries along the productive 40Ā° S parallel and highlight the need for additional research in this region.National Environmental Research Counci

    Fit for Planning? An Evaluation of the Application of Development Viability Appraisal Models in the UK Planning System

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    The aim of this paper is to critically examine the application of development appraisal to viability assessment in the planning system. This evaluation is of development appraisal models in general and also their use in particular applications associated with estimating planning obligation capacity. The paper is organised into four themes: Ā· The context and conceptual basis for development viability appraisal Ā· A review of development viability appraisal methods Ā· A discussion of selected key inputs into a development viability appraisal Ā· A discussion of the applications of development viability appraisals in the planning system. It is assumed that readers are familiar with the basic models and information needs of development viability appraisal rather than at the cutting edge of practice and/or academe.

    A multi-channel system for use in cardiac electrophysiologic studies

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    The location of accessory pathways in Wolff-Parkinson-White syndrome patients is performed manually during open heart surgery at Groote Schuur Hospital, using a hand-held roving electrode. This manual procedure is slow and tedious, prolonging the operation and the time for which the patient remains on cardiac bypass. A multichannel electrogram acquisition and display system with a storage facility would significantly reduce the time taken and improve the reliability of locating the accessory pathways. Having considered a number of currently available cardiac mapping systems it was decided that a new system be developed for specific application within Groote Schuur Hospital. The main design goals of this system are to improve accuracy, increase reliability and enhance the speed of the entire mapping procedure with direct benefit to staff and patients. The system is based on an IBM compatible computer and allows for the acquisition of a maximum of thirty-two electrogram inputs. A typical configuration would acquire twenty epicardial, two references (one each from atrium and ventricle), one roving electrode and two surface lead signals. The epicardial signals are obtained from a custom-built electrode belt which is placed around the heart over the atrioventricular groove. The project includes the development of front-end hardware and software for processing, display and storage of electrogram signals. The relative activation times of the signals are displayed under software control in order to facilitate the location of any accessory pathway(s)

    Prospectus, April 11, 2001

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    https://spark.parkland.edu/prospectus_2001/1012/thumbnail.jp

    Coffee and Caffeine Ingestion Have Little Effect on Repeated Sprint Cycling in Relatively Untrained Males

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    The present study investigated the effect of ingesting caffeine-dose-matched anhydrous caffeine or coffee on the performance of repeated sprints. Twelve recreationally active males (mean Ā± SD age: 22 Ā± 2 years, height: 1.78 Ā± 0.07 m, body mass: 81 Ā± 16 kg) completed eighteen 4 s sprints with 116 s recovery on a cycle ergometer on four separate occasions in a double-blind, randomised, counterbalanced crossover design. Participants ingested either 3 mgĀ·kgāˆ’1 of caffeine (CAF), 0.09 gĀ·kgāˆ’1 coffee, which provided 3 mgĀ·kgāˆ’1 of caffeine (COF), a taste-matched placebo beverage (PLA), or a control condition (CON) 45 min prior to commencing the exercise protocol. Peak and mean power output and rating of perceived exertion (RPE) were recorded for each sprint. There were no significant differences in peak power output (CAF: 949 Ā± 199 W, COF: 949 Ā± 174 W, PLA: 971 Ā± 149 W and CON: 975 Ā± 170 W; p = 0.872; Ī· P 2 = 0.02) or mean power output (CAF: 873 Ā± 172 W, COF: 862 Ā± 44 W, PLA: 887 Ā± 119 W and CON: 892 Ā± 143 W; p = 0.819; Ī· P 2 = 0.03) between experimental conditions. Mean RPE was similar for all trials (CAF: 11 Ā± 2, COF: 11 Ā± 2, PLA: 11 Ā± 2 and CON: 11 Ā± 2; p = 0.927; Ī· P 2 = 0.01). Neither the ingestion of COF or CAF improved repeated sprint cycling performance in relatively untrained males

    Low tropical diversity during the adaptive radiation of early land plants.

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    The latitudinal biodiversity gradient, with tropical regions acting as 'evolutionary cradles', is a cornerstone of current biogeographical and ecological theory1. In the modern world floral biodiversity and biomass are overwhelmingly concentrated in the tropics, and it is often assumed that the tropics were evolutionary cradles throughout land plant evolutionary history. For example, the origination and diversification of angiosperms is believed to have taken place in the Cretaceous tropics2 and modern gymnosperms in the Permian tropics3. Here, we show that during the first major diversification of land plants, in the Late Silurian-Early Devonian, land plant biodiversity was much lower at the equator compared to medium-high southern latitudes. Throughout this crucial interval of plant evolution, tropical vegetation remained depauperate and of very low taxonomic biodiversity, although with similar morphological disparity to the more diverse higher latitude floras. Possible explanations for this low tropical floral biodiversity include palaeocontinental configuration or adverse palaeotropical environmental conditions. We discount the possibility that it was simply a fortuitous feature of the biogeographical spread of the earliest vascular land plants.National Geographi
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