Chirality-dependent growth of single-wall carbon nanotubes as revealed inside nano-test tubes

Growth dynamics of single-wall carbon nanotubes (SWCNTs) have been studied with nickelocene as a precursor encapsulated in the interior of template SWCNTs. By means of multi-laser Raman spectroscopy, growth curves of nine different SWCNTs, (8,8), (12,3), (13,1), (9,6), (10,4), (11,2), (11,1), (9,3) and (9,2), have been determined upon in situ annealing at various temperatures. The data reveal that the nanotubes grow through fast and slow reaction pathways with high and low activation energies, respectively. While the activation energy of the slow growth is independent of the nanotube's chiral vector, that of the fast growth exhibits a monotonic increase as the tube diameter reduces from ∼1.1 down to 0.8 nm and no dependency on the chiral angle, which can be attributed to the size-dependent properties of catalyst clusters. The chirality dependent catalytic growth properties exploited in this study provide the basis for a large-scale synthesis of single-chiral vector SWCNTs

Robotic system for no-scar gastrointestinal surgery

10.1002/rcs.179International Journal of Medical Robotics and Computer Assisted Surgery4115-2

電総研 単語音声データベース（ETL-WD）

音韻バランスを考慮した単語リスト1542語の読み上げ音声Read speech data of phonetically-balanced 1542 words