Cleaning up Eta Carinae: Detection of Ammonia in the Homunculus

We report the first detection of ammonia in the Homunculus nebula around eta Carinae, which is also the first detection of emission from a polyatomic molecule in this or any other luminous blue variable (LBV) nebula. Observations of the NH3 (J,K)=(3,3) inversion transition made with the Australia Telescope Compact Array reveal emission at locations where infrared H2 emission had been detected previously, near the strongest dust emission in the core of the Homunculus. We also detect ammonia emission from the so-called ``strontium filament'' in the equatorial disk. The presence of NH3 around eta Car hints that molecular shells around some Wolf-Rayet stars could have originated in prior LBV eruptions, rather than in cool red supergiant winds or the ambient interstellar medium. Combined with the lack of any CO detection, NH3 seems to suggest that the Homunculus is nitrogen rich like the ionized ejecta around eta Car. It also indicates that the Homunculus is a unique laboratory in which to study unusual molecule and dust chemistry, as well as their rapid formation in a nitrogen-rich environment around a hot star. We encourage future observations of other transitions like NH3 (1,1) and (2,2), related molecules like N2H+, and renewed attempts to detect CO.Comment: 4 pages, accepted to ApJ letter

Light with a self-torque: extreme-ultraviolet beams with time-varying orbital angular momentum

Twisted light fields carrying orbital angular momentum (OAM) provide powerful capabilities for applications in optical communications, microscopy, quantum optics and microparticle rotation. Here we introduce and experimentally validate a new class of light beams, whose unique property is associated with a temporal OAM variation along a pulse: the self-torque of light. Self-torque is a phenomenon that can arise from matter-field interactions in electrodynamics and general relativity, but to date, there has been no optical analog. In particular, the self-torque of light is an inherent property, which is distinguished from the mechanical torque exerted by OAM beams when interacting with physical systems. We demonstrate that self-torqued beams in the extreme-ultraviolet (EUV) naturally arise as a necessary consequence of angular momentum conservation in non-perturbative high-order harmonic generation when driven by time-delayed pulses with different OAM. In addition, the time-dependent OAM naturally induces an azimuthal frequency chirp, which provides a signature for monitoring the self-torque of high-harmonic EUV beams. Such self-torqued EUV beams can serve as unique tools for imaging magnetic and topological excitations, for launching selective excitation of quantum matter, and for manipulating molecules and nanostructures on unprecedented time and length scales.Comment: 24 pages, 4 figure

Multiplexed droplet Interface bilayer formation

We present a simple method for the multiplexed formation of droplet interface bilayers (DIBs) using a mechanically operated linear acrylic chamber array. To demonstrate the functionality of the chip design, a lipid membrane permeability assay is performed. We show that multiple, symmetric DIBs can be created and separated using this robust low-cost approach

Rheological droplet interface bilayers (rheo-DIBs): Probing the unstirred water layer effect on membrane permeability via spinning disk induced shear stress

A new rheological droplet interface bilayer (rheo-DIB) device is presented as a tool to apply shear stress on biological lipid membranes. Despite their exciting potential for affecting high-throughput membrane translocation studies, permeability assays conducted using DIBs have neglected the effect of the unstirred water layer (UWL). However as demonstrated in this study, neglecting this phenomenon can cause significant underestimates in membrane permeability measurements which in turn limits their ability to predict key processes such as drug translocation rates across lipid membranes. With the use of the rheo-DIB chip, the effective bilayer permeability can be modulated by applying shear stress to the droplet interfaces, inducing flow parallel to the DIB membranes. By analysing the relation between the effective membrane permeability and the applied stress, both the intrinsic membrane permeability and UWL thickness can be determined for the first time using this model membrane approach, thereby unlocking the potential of DIBs for undertaking diffusion assays. The results are also validated with numerical simulations

Prospects for local co-governance

British local authorities and their partners are increasingly developing new ways of working together with local communities. The nature of this co-working, however, is complex, multi-faceted and little understood. This article argues for greater clarity of thinking on the topic, by analysing this co-working as a form of political co-governance, and drawing attention in particular to issues of scale and democracy. Using evidence from a study of 43 local authority areas, 16 authorities are identified where co-governance is practised, following three main types of approach: service-influencing, service-delivering and parish council developing. It is concluded that strengthening political co-governance is essential for a healthy democracy

Ptychographic amplitude and phase reconstruction of bichromatic vortex beams

We experimentally demonstrate that ptychographic coherent diffractive imaging can be used to simultaneously characterize the amplitude and phase of bichromatic orbital angular momenta-shaped vortex beams, which consist of a fundamental field, together with its copropagating second-harmonic field. In contrast to most other orbital angular momentum characterization methods, this approach solves for the complex field of a hyperspectral beam. This technique can also be used to characterize other phase-structured illumination beams, and, in the future, will be able to be extended to other complex fields in the extreme ultraviolet or X-ray spectral regions, as well as to matter waves.The NSF STROBE STC (DMR-1548924); DOE BES AMOS grant (DE-FG02-99ER14982); the NSF GRFP (DGE 1650115); 2017 Leonardo Grant for Researchers and Cultural Creators, BBVA Foundation; Junta de Castilla y León (SA046U16); Ministerio de Economía y Competitividad (FIS2016-75652-P)

Sculpting and fusing biomimetic vesicle networks using optical tweezers

Constructing higher-order vesicle assemblies has discipline-spanning potential from responsive soft-matter materials to artificial cell networks in synthetic biology. This potential is ultimately derived from the ability to compartmentalise and order chemical species in space. To unlock such applications, spatial organisation of vesicles in relation to one another must be controlled, and techniques to deliver cargo to compartments developed. Herein, we use optical tweezers to assemble, reconfigure and dismantle networks of cell-sized vesicles that, in different experimental scenarios, we engineer to exhibit several interesting properties. Vesicles are connected through double-bilayer junctions formed via electrostatically controlled adhesion. Chemically distinct vesicles are linked across length scales, from several nanometres to hundreds of micrometres, by axon-like tethers. In the former regime, patterning membranes with proteins and nanoparticles facilitates material exchange between compartments and enables laser-Triggered vesicle merging. This allows us to mix and dilute content, and to initiate protein expression by delivering biomolecular reaction components

Necklace-structured high-harmonic generation for low-divergence, soft x-ray harmonic combs with tunable line spacing

The extreme nonlinear optical process of high-harmonic generation (HHG) makes it possible to map the properties of a laser beam onto a radiating electron wave function and, in turn, onto the emitted x-ray light. Bright HHG beams typically emerge from a longitudinal phased distribution of atomic-scale quantum antennae. Here, we form a transverse necklace-shaped phased array of linearly polarized HHG emitters, where orbital angular momentum conservation allows us to tune the line spacing and divergence properties of extreme ultraviolet and soft x-ray high-harmonic combs. The on-axis HHG emission has extremely low divergence, well below that obtained when using Gaussian driving beams, which further decreases with harmonic order. This work provides a new degree of freedom for the design of harmonic combs—particularly in the soft x-ray regime, where very limited options are available. Such harmonic beams can enable more sensitive probes of the fastest correlated charge and spin dynamics in molecules, nanoparticles, and materials.The JILA team graciously acknowledges support from the Department of Energy BES Award No. DE-FG02-99ER14982 for the experimental implementation, a MURI grant from the Air Force Office of Scientific Research under Award No. FA9550-16-1-0121 for the mid-infrared laser soft x-ray research, and a National Science Foundation Physics Frontier Center grant PHY-1734006 for theory. N.J.B. acknowledges support from National Science FoundationGraduate Research Fellowships (grant no. DGE-1650115). Q.L.D.N. acknowledges support from National Science Foundation Graduate Research Fellowships (grant no. DGE-1144083). J.S.R., L.P., and C.H.-G. acknowledge support from Ministerio de Ciencia e Innovación (FIS2016-75652-Pand PID2019-106910GB-I00). This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program (grant agreement no. 851201). J.S.R., L.P., and C.H.-G. also acknowledge support from Junta de Castilla y León FEDER funds (project no. SA287P18). L.R. acknowledges support from Ministerio de Educación, Cultura y Deporte (FPU16/02591). C.H.-G. acknowledges Ministerio de Ciencia, Innovación, y Universidades for Ramón y Cajal contract (RYC-2017-22745), cofunded by the European Social Fund. L.R., J.S.R., L.P., and C.H.-G. thankfully acknowledge the computer resources at MareNostrum and the technical support provided by Barcelona Supercomputing Center (FI-2020-3-0013)