Ca-substitution and O-doping effects in superconducting Cu(Ba0.8Sr0.2)2(Yb1-xCax)Cu2O6+z obtained from neutron diffraction refinements

Distinct calcium and oxygen doping effects were studied in the Cu(Ba0.8Sr0.2)2(Yb1−xCax)Cu2O6+z (Cu−1212:P) system by means of neutron diffraction and superconducting quantum interference device experiments in the wide substitution ranges of 0<~x<~0.35 and 0<z<1. The effectiveness of the two different ways to introduce holes into the CuO2 planes was compared both in respect to the capability to increase Tc and in terms of the hole production as estimated from neutron-diffraction data via bond-valence-sum calculation. Oxygen doping was found to increase the hole concentration less efficiently, and further, at a certain hole concentration value higher Tc values were obtained with calcium substitution than with oxygen doping. The two different hole-doping methods exhibited also different Tc vs Cu-O bond length relations. As a conclusion, the possible roles of the hole distribution in the in-plane Cu-O bond and the flatness of the CuO2 planes in determining the superconducting properties were recognized.Peer reviewe

Impurity scattering in unconventional density waves

We have investigated the effect of nonmagnetic impurities on the quasi-one-dimensional unconventional density wave (UDW) ground state. The thermodynamics were found to be close to those of a d-wave superconductor in the Born limit. Four different optical conductivity curves were found depending on the direction of the applied electric field and on the wavevector dependence of the gap.Comment: 14 pages, 9 figure

Ground-based millimeter-wave observation of stratospheric ClO over Atacama, Chile in the mid-latitude Southern Hemisphere

We have performed ground-based measurements of stratospheric chlorine monoxide (ClO) during the summer in 2009 over the Atacama highland, Chile, a new observing site in the mid-latitude region in the Southern Hemisphere, by using a millimeter-wave spectroscopic radiometer. The radiometer, equipped with a superconducting receiver and a digital Fourier spectrometer, was developed by Nagoya University, and the new observing system provides us high sensitivity and stable performance to measure the very weak ClO lines. The receiver noise temperature of the superconducting receiver is 170 K in DSB. To reveal the diurnal variation of ClO, we retrieved the vertical mixing ratio profiles by the weighted-damped least-squares algorithm applied for the spectral data at 203 GHz obtained between 5 and 16 December 2009. The total error on the retrieval is estimated to be 20% to 30% in an altitude range from 40 km to 50 km. The amplitude of the diurnal variation is estimated as 33% of the daytime average at 40 km. The observed time variation shows a pattern similar to that of the previous works observed in the northern mid-latitude region

Lidar observation of ozone over Tsukuba (36 deg N, 140 deg E)

An ozone lidar system was installed at the National Institute for Environmental Studies (NIES) in Tsukuba, Japan in March 1988 and has been measuring vertical profiles of ozone (15 - 45 km) since September 1988. The lidar system consists of a XeCl (308 nm) excimer laser, its deuterium Raman shifter (339 nm), a XeF excimer laser (351 nm), a 2 m telescope, a receiving system and a data processing system. The precision of the derived ozone concentration is about 10 percent of an altitude of 40 km for a 4 hr observation. Temperature profiles (30 - 80 km) are also obtained from the Rayleigh scattering signals at 351 nm. Approximate 50 ozone measurements are carried out in a year and variations of vertical profiles of ozone such as seasonal variations and shorter-term variations are observed. Systematic errors due to aerosols had been negligible until the arrival of the stratospheric aerosols injected by the eruption of Mt. Pinatubo. Effects of the volcanic aerosols on ozone measurements depend on the differences between wavelengths used as the on- and off-resonance

Layer-specific hole concentrations in Bi2Sr2(Y1-xCax)Cu208+[delta] as probed by XANES spectroscopy and coulometric redox analysis

Induction of holes not only in the superconductive CuO2 plane but also in the Bi2O2+δ charge reservoir of the Bi2Sr2(Y1-xCax)Cu2O8+δ superconductor upon CaII-for-YIII substitution is evidenced by means of two independent techniques, i.e., high-resolution x-ray-absorption near-edge structure (XANES) spectroscopy measurements and coulometric redox titrations. The absolute values derived for the CuO2-plane hole concentration from the Cu L2,3-edge XANES spectra are in good agreement with those obtained from the coulometric redox analysis. The CuO2-plane hole concentration is found to increase from 0.03 to 0.14 concomitantly with the increase in the BiO1+δ/2-layer hole concentration from 0.00 to 0.13 as the Ca-substitution level, x, increases from 0 to 1. The threshold CuO2-plane hole concentration for the appearance of superconductivity is determined at 0.06, while the highest Tc is obtained at the hole concentration of 0.12. In the O K-edge XANES spectrum, the increases in the CuO2-plane and BiO1+δ/2-layer hole concentrations with increasing x are seen as enhancement in the relative intensities of the pre-edge peaks at ∼528.3 and ∼530.5 eV, respectively.Peer reviewe