746 research outputs found
Size effect in the ionization energy of PAH clusters
We report the first experimental measurement of the near-threshold
photo-ionization spectra of polycyclic aromatic hydrocarbon clusters made of
pyrene C16H10 and coronene C24H12, obtained using imaging photoelectron
photoion coincidence spectrometry with a VUV synchrotron beamline. The
experimental results of the ionization energy are confronted to calculated ones
obtained from simulations using dedicated electronic structure treatment for
large ionized molecular clusters. Experiment and theory consistently find a
decrease of the ionization energy with cluster size. The inclusion of
temperature effects in the simulations leads to a lowering of this energy and
to a quantitative agreement with the experiment. In the case of pyrene, both
theory and experiment show a discontinuity in the IE trend for the hexamer
High-resolution Fourier-transform XUV photoabsorption spectroscopy of 14N15N
The first comprehensive high-resolution photoabsorption spectrum of 14N15N
has been recorded using the Fourier-transform spectrometer attached to the
Desirs beamline at the Soleil synchrotron. Observations are made in the extreme
ultraviolet (XUV) and span 100,000-109,000 cm-1 (100-91.7 nm). The observed
absorption lines have been assigned to 25 bands and reduced to a set of
transition energies, f values, and linewidths. This analysis has verified the
predictions of a theoretical model of N2 that simulates its photoabsorption and
photodissociation cross section by solution of an isotopomer independent
formulation of the coupled-channel Schroedinger equation. The mass dependence
of predissociation linewidths and oscillator strengths is clearly evident and
many local perturbations of transition energies, strengths, and widths within
individual rotational series have been observed.Comment: 14 pages, 8 figures, one data archiv
Equatorial rain forest lateritic mantles : a geomembrane filter
ABSTRACT The superimposed weathering layers in equatorial rain forest lateritic mantles from Gabon, AtXca, function as interactive compartments forming a dynamic semipermeable geomembrane filter. Selectivity of the filter is controlled by a progressive downward disappearance Of Connected macropore pathways created by bioturbation and dissolution. The natural balance of root activity, translocation, dissolution, deformation, and pore evolution leads to the development of porous and permeable, mature, open geochemical weathering systems at the expense of the lithosphere. These conclusions can be useful in modeling the fate of lateritic soils, which cover one-third of the emerged area of the world and which are economically important both as metal deposits and agricultural soils
Melanin-concentrating hormone receptors (version 2019.4) in the IUPHAR/BPS Guide to Pharmacology Database
Melanin-concentrating hormone (MCH) receptors (provisional nomenclature as recommended by NC-IUPHAR [31]) are activated by an endogenous nonadecameric cyclic peptide identical in humans and rats (DFDMLRCMLGRVYRPCWQV; mammalian MCH) generated from a precursor (PMCH, P20382), which also produces neuropeptide EI and neuropeptide GE
Melanin-concentrating hormone receptors in GtoPdb v.2023.1
Melanin-concentrating hormone (MCH) receptors (provisional nomenclature as recommended by NC-IUPHAR [32]) are activated by an endogenous nonadecameric cyclic peptide identical in humans and rats (DFDMLRCMLGRVYRPCWQV; mammalian MCH) generated from a precursor (PMCH, P20382), which also produces neuropeptide EI and neuropeptide GE
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