Hydroxyapatite-TiO2-SiO2-Coated 316L Stainless Steel for Biomedical Application

This study investigated the effectiveness of titania (TiO2) as a reinforcing phase in the hydroxyapatite (HAP) coating and silica (SiO2) single-layer as a bond coat between the TiO2-reinforced hydroxyapatite (TiO2/HAP) top layer and 316L stainless steel (316L SS) substrate on the corrosion resistance and mechanical properties of the underlying 316L SS metallic implant. Single-layer of SiO2 film was first deposited on 316L SS substrate and studied separately. Water contact angle measurements, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) spectrophotometer analysis were used to evaluate the hydroxyl group reactivity at the SiO2 outer surface. The microstructural and morphological results showed that the reinforcement of HAP coating with TiO2 and SiO2 reduced the crystallite size and the roughness surface. Indeed, the deposition of 50 vol. % TiO2-reinforced hydroxyapatite layer enhanced the hardness and the elastic modulus of the HAP coating, the introduction of SiO2 inner-layer on the surface of the 316L SS allowed the improvement of the bonding strength and the corrosion resistance as confirmed by scratch studies, nanoindentation and cyclic voltammetry tests

Application of cold thermal energy storage (CTES) for building demand management in hot climates

This paper investigates the feasibility of Cold Thermal Energy Storage (CTES) for building demand management applications in hot climate characterized by a cooling season lasting all year long. An existing office building, located in Singapore, serves as case study. The CTES is coupled to the existing cooling systems in order to address the opportunity of improving overall energy efficiency and to perform price arbitrage, exploiting the spread between peak and off-peak energy tariffs. Six different sizes for the CTES are analyzed, addressing different percentage of the daily cooling energy demand. A new index, Savings per energy unit, is defined to assess the effectiveness of CTES. Results indicate that it is possible to enhance the efficiency of the whole cooling system, achieving both energy and economic savings. The payback periods of the different solutions range from a minimum of 8.9 years to a maximum of 16 years. All these aspects make CTES applications a viable option. However, a large amount of space in direct proximity to the building is necessary and, especially in largely urban environment, this is not always available

Citrate Functionalized Zirconium-Based Metal Organic Framework for the Fluorescent Detection of Ciprofloxacin in Aqueous Media

Ciprofloxacin (CIP) is a commonly used antibiotic for the treatment of infectious diseases in humans and as a prophylactic agent in the livestock industry, leading to the environmental discharge of significant amounts of CIP. CIP is stable in aquatic systems leading to its pseudo-persistence. Constant exposure to these antibiotics results in the generation of antibiotic-resistant pathogens and potential toxicity/hypersensitivity in humans. Therefore, it is necessary to develop a convenient, rapid, and cost-effective method for the monitoring of ciprofloxacin in environmental samples. Rhodamine-based fluorescent receptors have the limitation of aqueous solubility. Therefore, in order to overcome this drawback, we designed a novel fluorescent receptor based on a zirconium-based metal organic framework (MOF-808). The precursor, MOF-808, was synthesized and functionalized by using sodium citrate to obtain a receptor called C-MOF-808. The C-MOF-808 was structurally characterized by XRD and spectroscopic analyses. Thus, this synthesized receptor can be used for the fluorescent detection of CIP in aqueous media with a detection limit of 9.4 µM. The detection phenomena of the receptor were studied by absorption as well as fluorescent spectra. The binding behavior of CIP with the receptor was studied by FT-IR and 1H-NMR analyses, and a binding mechanism is proposed

Storing energy for cooling demand management in tropical climates: A techno-economic comparison between different energy storage technologies

This paper addresses the role of energy storage in cooling applications. Cold energy storage technologies addressed are: Li-Ion batteries (Li-Ion EES), sensible heat thermal energy storage (SHTES); phase change material (PCM TES), compressed air energy storage (CAES) and liquid air energy storage (LAES). Batteries and CAES are electrical storage systems which run the cooling systems; SHTES and PCM TES are thermal storage systems which directly store cold energy; LAES is assessed as a hybrid storage system which provides both electricity (for cooling) and cold energy. A hybrid quantitative-qualitative comparison is presented. Quantitative comparison was investigated for different sizes of daily cooling energy demand and three different tariff scenarios. A techno-economic analysis was performed to show the suitability of the different storage systems at different scales. Three parameters were used (Pay-back period, Savings-per-energy-unit and levelized-cost-of-energy) to analyze and compare the different scenarios. The qualitative analysis was based on five comparison criteria (Complexity, Technology Readiness Level, Sustainability, Flexibility and Safety). Results showed the importance of weighing the pros and cons of each technology to select a suitable cold energy storage system. Techno-economic analysis highlighted the fundamental role of tariff scenario: a greater difference between peak and off-peak electricity tariff leads to a shorter payback period of each technology