67 research outputs found
Room temperature triggered single-photon source in the near infrared
We report the realization of a solid-state triggered single-photon source
with narrow emission in the near infrared at room temperature. It is based on
the photoluminescence of a single nickel-nitrogen NE8 colour centre in a
chemical vapour deposited diamond nanocrystal. Stable single-photon emission
has been observed in the photoluminescence under both continuous-wave and
pulsed excitations. The realization of this source represents a step forward in
the application of diamond-based single-photon sources to Quantum Key
Distribution (QKD) under practical operating conditions.Comment: 10 page
Coherence properties of a single dipole emitter in diamond
On-demand, high repetition rate sources of indistinguishable, polarised
single photons are the key component for future photonic quantum technologies.
Colour centres in diamond offer a promising solution, and the narrow line-width
of the recently identified nickel-based NE8 centre makes it particularly
appealing for realising the transform-limited sources necessary for quantum
interference. Here we report the characterisation of dipole orientation and
coherence properties of a single NE8 colour centre in a diamond nanocrystal at
room-temperature. We observe a single photon coherence time of 0.21 ps and an
emission lifetime of 1.5 ns. Combined with an emission wavelength that is
ideally suited for applications in existing quantum optical systems, these
results show that the NE8 is a far more promising source than the more commonly
studied nitrogen-vacancy centre and point the way to the realisation of a
practical diamond colour centre-based single photon source.Comment: 10 pages, 4 colour figure
Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene
© 2017 Elsevier Ltd Reactions of VCl 3 with chiral derivatives of dihydrophenanthroline (2R,4R,9R,11R)-3,3,10,10-tetramethyl-1,2,3,4,6,7,9,10,11,12-decahydro-2,4:9,11-dimethanodibenzo[b,j][1,10] phenanthroline (L1) and diazafluorene (1R,3R,8R,10R)-2,2,9,9-tetramethyl-2,3,4,7,8,9,10,12-octahydro-1H-1,3:8,10-dimethanocyclopenta[1,2-b:5,4-b′]diquinoline (L2) in acetonitrile in air yield mixtures of [V III (L1/L2)(CH 3 CN)Cl 3 ] and [V IV O(L1/L2)(CH 3 CN)Cl 2 ] (I, II) which were characterized by elemental analysis, IR spectroscopy and magnetic susceptibility data. The behavior of these mixtures in different solvents was investigated by 51 V NMR and EPR spectroscopies as well as optical rotation. Recrystallization of a [V III (L1)(CH 3 CN)Cl 3 ]/[V IV O(L1)(CH 3 CN)Cl 2 ] mixture from CH 2 Cl 2 /Et 2 O affords a V(IV) complex, [V IV O(L1)(H 2 O)Cl 2 ]·nCH 2 Cl 2 (III). Recrystallization from MeOH/Et 2 O leads to complete oxidation to V(V) complex [V V O(L1)(OMe)Cl 2 ] (IV), which was characterized by X-ray crystallography, IR, 51 V and 1 H NMR spectroscopies
Single photon emitters based on Ni/Si related defects in single crystalline diamond
We present investigations on single Ni/Si related color centers produced via
ion implantation into single crystalline type IIa CVD diamond. Testing
different ion dose combinations we show that there is an upper limit for both
the Ni and the Si dose 10^12/cm^2 and 10^10/cm^2 resp.) due to creation of
excess fluorescent background. We demonstrate creation of Ni/Si related centers
showing emission in the spectral range between 767nm and 775nm and narrow
line-widths of 2nm FWHM at room temperature. Measurements of the intensity
auto-correlation functions prove single-photon emission. The investigated color
centers can be coarsely divided into two groups: Drawing from photon statistics
and the degree of polarization in excitation and emission we find that some
color centers behave as two-level, single-dipole systems whereas other centers
exhibit three levels and contributions from two orthogonal dipoles. In
addition, some color centers feature stable and bright emission with saturation
count rates up to 78kcounts/s whereas others show fluctuating count rates and
three-level blinking.Comment: 7 pages, submitted to Applied Physics B, revised versio
Infrared Absorption Investigations Confirm the Extraterrestrial Origin of Carbonado-Diamonds
The first complete infrared FTIR absorption spectra for carbonado-diamond
confirm the interstellar origin for the most enigmatic diamonds known as
carbonado. All previous attempts failed to measure the absorption of
carbonado-diamond in the most important IR-range of 1000-1300 cm-1 (10.00-7.69
micro-m.) because of silica inclusions. In our investigation, KBr pellets were
made from crushed silica-free carbonado-diamond and thin sections were also
prepared. The 100 to 1000 times brighter synchrotron infrared radiation permits
a greater spatial resolution. Inclusions and pore spaces were avoided and/or
sources of chemical contamination were removed. The FTIR spectra of
carbonado-diamond mostly depict the presence of single nitrogen impurities, and
hydrogen. The lack of identifiable nitrogen aggregates in the infrared spectra,
the presence of features related to hydrocarbon stretch bonds, and the
resemblance of the spectra to CVD and presolar diamonds indicate that
carbonado-diamonds formed in a hydrogen-rich interstellar environment. This is
consistent with carbonado-diamond being sintered and porous, with extremely
reduced metals, metal alloys, carbides and nitrides, light carbon isotopes,
surfaces with glassy melt-like patinas, deformation lamellae, and a complete
absence of primary, terrestrial mineral inclusions. The 2.6-3.8 billion year
old fragmented body was of asteroidal proportions
Volatile Heterobimetallic Complexes from PdIIand CuIIβ-Diketonates: Structure, Magnetic Anisotropy, and Thermal Properties Related to the Chemical Vapor Deposition of Cu-Pd Thin Films
A novel approach for preparing volatile heterometallic complexes for use as precursors for the chemical vapor deposition of various materials is reported. New Cu¢Pd complexes based on b-diketonate units were prepared, and their structures and compositions were determined. [PdL2*CuL2] (1) and [PdL2*Cu(tmhd)2] (2) (L=2-methoxy-2,6,6-trimethylheptane-3,5-dionate; tmhd=2,2,6,6- tetramethylheptane-3,5-dionate) are 1D coordination polymers with alternating metal complexes, which are connected through weak interactions between the Cu atoms and the OCH3 groups from the ligand of the Pd complexes. The volatility and thermal stability were studied using thermogravimetric and differential thermal analyses and mass spectrometry. Compound 1 vaporizes without decomposition into monometallic complexes. It exhibits magnetic anisotropy, which was revealed from the angular variations in the EPR spectrum of a single crystal. The vapor thermolysis process for 1 was investigated using mass spectrometry, allowing the process to be framed within the temperature range of 200–3508C. The experimental data, supported by QTAIM calculations of the allowed intermolecular interactions, suggest that 1 likely exists in the gas phase as bimetallic molecules. Compound 1 proved to be suitable as a single-source precursor for the efficient preparation of Cu¢Pd alloy films with tunable Cu/Pd ratio. A possible mechanism for the film growth is proposed based on the reported data
23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –
Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described
- …