574 research outputs found
Strong Optomechanical Coupling at Room Temperature by Coherent Scattering
Quantum control of a system requires the manipulation of quantum states
faster than any decoherence rate. For mesoscopic systems, this has so far only
been reached by few cryogenic systems. An important milestone towards quantum
control is the so-called strong coupling regime, which in cavity optomechanics
corresponds to an optomechanical coupling strength larger than cavity decay
rate and mechanical damping. Here, we demonstrate the strong coupling regime at
room temperature between a levitated silica particle and a high finesse optical
cavity. Normal mode splitting is achieved by employing coherent scattering,
instead of directly driving the cavity. The coupling strength achieved here
approaches three times the cavity linewidth, crossing deep into the strong
coupling regime. Entering the strong coupling regime is an essential step
towards quantum control with mesoscopic objects at room temperature
Conditions de convergence pratiques pour les problèmes d'optimisation d'une fonction sans contrainte
Microdroplet Approach for Measuring Aqueous Solubility and Nucleation Kinetics of a Metastable Polymorph: The case of KDP Phase IV
Solubility and interfacial energy are two fundamental parameters underlying
the competitive nucleation of polymorphs. However, solubility measurement of
metastable phases comes with a risk of solventmediated transformations which
can render the results unreliable. In this work, we present a rapid
microfluidic technique for measuring aqueous solubility of the metastable form
using KDP Phase IV as a model system. This bracketing approach involves
analyzing the dissolution behavior of crystals in contact with supersaturated
microdroplets generated via evaporation. Then, with the help of our recently
developed nucleation time measurement technique, together with Mersmann
calculation of interfacial energies from solubilities, we were able to access
the interfacial energies of both metastable and stable phases. To gain further
insights into the observed nucleation behavior, we employed the Classical
Nucleation Theory (CNT) to model the competition of polymorphs using our
measured solubility and calculated interfacial energies. The results show that
the stable form is favored at lower supersaturation while the metastable form
is favored at higher supersaturation, in good agreement with our observations
and experimental reports in the literature. Overall, our microfluidic approach
allows access to unprecedentedly deep levels of supersaturation and reveals an
interesting interplay between thermodynamics and kinetics in polymorphic
nucleation. The experimental methods and insights presented herein can be of
great interest, notably in the mineral processing and pharmaceutical industry
Structure des couronnes et variation de l’épaisseur et de la surface d’aubier chez l’Angélique deGuyane (Dicorynia guianensis Amsh., Caesalpinioideae, Fabaceae)
International audienceL'Angélique (Dicorynia guianensis Amsh.) représente environ 35% de laproduction de bois d'oeuvre en Guyane. Cependant, la stratégie de duraminisationdite ‘tardive’ chez cette essence entraîne une grande variabilité de l'épaisseurd'aubier (Fig. 1A) et par conséquent, influence la proportion exploitable de lagrume. La relation entre quantité de bois de coeur et diamètre à 1m30 (DBH) (e.g.Carrodus (1972), Wilkes (1991), Pinto et al. (2004), Wang et al. (2010)), ne permetpas une estimation suffisamment précise de la quantité de duramen et/ou d’aubier.A ce jour, très peu d’études mettent en lien la structure de la couronne et/ou lestatut social de l’individu avec la quantité de duramen (e.g. Pazdrowski et al.(2009), Nawrot et al. (2008)). Or, une grande diversité de structures des couronnesest observable au sein d’une même classe de diamètre (Fig. 1B).Ici, nous proposons une méthode visuelle et rapide de diagnostic architectural desarbres permettant d’améliorer l’estimation de la quantité de duramen dans letronc
The EGIM, modular though generic addresses the requirements of the EMSO platforms
The EGIM
(EMSO Generic Instrument Module
) is designed to consistently and continuously measure
parameters of interest for most major science areas covered by EMSO. This research infrastructure
provides accurate records on marine environmental changes from distributed regional nodes around
Europe. The system can deliver data that can support the Global Ocean Observing System
–Essential
Ocean Variables concept, as well as the Marine Strategy Framework Directive towards evaluating
environmentalstatus.
The EGIM is flexible for adaptation according to site and disciplinespecific requirements. Inter
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operability and capacity of future evolution of the system are key aspects of the modularity.
The EGIM is able to operate on any EMSO node type: mooring line, sea bed station, cabled or non
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cabled and surface buoy to monitor environmental parameters over a wide depth range. Operating
modes, power requirements, mechanical design can adapt to the various EMSO node configurations. In addition to sensors already included in the EGIM prototype (temperature, conductivity, pressure,
dissolved Oxygen, Turbidity, currents and passive acoustics)
the
EGIMcan host up to five additional
sensors such as chl
-a, pCO
2, pH, seismic and photographic/video images ornew sensors. The EGIM
provides all the sensor hosting services required
,for instance power distribution, positioning
, and
protection against bio
-fouling
.
Within EMSO
, the EGIM aimsto have a number of ocean locations where the same set of core
variables are measured homogeneously: using the same hardware, same sensor references, same
qualification methods, same calibration methods, same data format and access and the same
maintenance procedures. It’s compact and modular nature allows for flexible deploymentscenarios
that include being able to accommodate new instruments such for Essential Ocean Variables and
other needs as theirtechnology readiness levels improve.Peer ReviewedPostprint (published version
CNT effective interfacial energy and pre-exponential kinetic factor from measured NaCl crystal nucleation time distributions in contracting microdroplets
Nucleation, the birth of a stable cluster from disorder, is inherently
stochastic. Yet up to date, there are no quantitative studies on NaCl
nucleation that accounts for its stochastic nature. Here, we report the first
stochastic treatment of NaCl-water nucleation kinetics. Using a recently
developed microfluidic system and evaporation model, our measured interfacial
energies extracted from a modified Poisson distribution of nucleation time show
an excellent agreement with theoretical predictions. Furthermore, analysis of
nucleation parameters in 0.5 pL, 1.5pL and 5.5 pL microdroplets reveals an
interesting interplay between kinetic confinement and shifting of nucleation
mechanisms. Overall, our findings highlight the need to treat nucleation
stochastically rather deterministically to bridge the gap between theory and
experiment
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