7,297 research outputs found
A versatile modular plant for converting biogas into advanced biofuels
The patented technology is a novel, portable, non-invasive, and flexible technical solution for converting biogas into valuable chemical compounds, such as bio-methanol and bio-dimethyl ether (bio-DME). It consists of compact modules, connected through a flange-valve-flange system, to be installed downstream of an existing traditional biogas plant.
The two main sections of the module are those of reforming and synthesis: in the first, the biogas is converted into bio-syngas (H2/CO/CO2), while in the second the bio-syngas is transformed into advanced biofuels such as bio-methanol and bio-DME. Parts of the synthesis module can permanently be changed with small investments to switch the final products, according to local market needs and price volatilities. Downstream at the synthesis section, it is possible to add a module for separating and purifying the chemical products.
The technology has been validated at the 0.15 MWe industrial scale
Impact of Charge-Resonance Excitations on CT-Mediated J-Type Aggregation in Singlet and Triplet Exciton States of Perylene Di-Imide Aggregates: A TDDFT Investigation
The modulation of intermolecular interactions upon aggregation induces changes in excited state properties of organic molecules that can be detrimental for some optoelectronic applications but can be exploited for others. The time-dependent density functional theory (TDDFT) is a cost-effective approach to determining the exciton states of molecular aggregates, and it has been shown to provide reliable results when coupled with the appropriate choice of the functional. Here we apply a general procedure to analyze the aggregates’ exciton states derived from TDDFT calculations in terms of diabatic states chosen to coincide with local (LE) and charge-transfer (CT) excitations within a restricted orbital space. We apply the approach to study energy profiles, interstate couplings, and the charge-transfer character of singlet and triplet exciton states of perylene di-imide aggregates (PDI). We focus on the intermolecular displacement along the longitudinal translation coordinate, which mimics different amounts of slip-stacking observed in PDI crystals. The analysis, in terms of symmetry-adapted Frenkel excitations (FE) and charge-resonance (CR) states and their interactions, discloses how the interchange of the H/J character for small longitudinal shifts, previously reported for singlet exciton states, also occurs for triplet excitons
The LAUE project for broadband gamma-ray focusing lenses
We present the LAUE project devoted to develop an advanced technology for
building a high focal length Laue lens for soft gamma--ray astronomy (80-600
keV). The final goal is to develop a focusing optics that can improve the
current sensitivity in the above energy band by 2 orders of magnitude.Comment: 7 pages, 6 figures, presented at the SPIE conference on "Optics for
EUV, X-ray, and Gamma-ray Astronomy". To be published in the Proceedings of
SPIE, vol.8147, 201
Adaptive greedy algorithms based on parameter-domain decomposition and reconstruction for the reduced basis method
The reduced basis method (RBM) empowers repeated and rapid evaluation of
parametrized partial differential equations through an offline-online
decomposition, a.k.a. a learning-execution process. A key feature of the method
is a greedy algorithm repeatedly scanning the training set, a fine
discretization of the parameter domain, to identify the next dimension of the
parameter-induced solution manifold along which we expand the surrogate
solution space. Although successfully applied to problems with fairly high
parametric dimensions, the challenge is that this scanning cost dominates the
offline cost due to it being proportional to the cardinality of the training
set which is exponential with respect to the parameter dimension. In this work,
we review three recent attempts in effectively delaying this curse of
dimensionality, and propose two new hybrid strategies through successive
refinement and multilevel maximization of the error estimate over the training
set. All five offline-enhanced methods and the original greedy algorithm are
tested and compared on {two types of problems: the thermal block problem and
the geometrically parameterized Helmholtz problem
Cloning and characterization of the gene expression profiles of maize phosphorus-starvation tolerance 1 genes.
Risk factors for adenocarcinoma of the cervix: a case-control study.
To assess risk factors for cervical adenocarcinoma data were collected in a case-control study of 39 cases and 409 controls conducted in the greater Milan area. Questions were asked about personal characteristics and habits, gynaecologic and obstetric data, history of lifetime use of oral contraceptives and other female hormones, and general indicators of sexual habits (age at first intercourse and total number of sexual partners). The relative risk of cervical adenocarcinoma increased with number of births and abortions, early age at first birth and early age at first intercourse. These estimates did not materially change after adjustment for the potential reciprocal confounding effect. Further, there was a positive association with overweight, but an apparent association with lower education was not significant. No relationship emerged with oral contraceptive use. Thus, despite the similarities with the epidemiology of squamous cell cancer, reproductive patterns and other factors related to the risk of endometrial cancer (i.e., overweight) seem to play an important role in the risk of adenocarcinoma of cervix uteri
On Deriving Nested Calculi for Intuitionistic Logics from Semantic Systems
This paper shows how to derive nested calculi from labelled calculi for propositional intuitionistic logic and first-order intuitionistic logic with constant domains, thus connecting the general results for labelled calculi with the more refined formalism of nested sequents. The extraction of nested calculi from labelled calculi obtains via considerations pertaining to the elimination of structural rules in labelled derivations. Each aspect of the extraction process is motivated and detailed, showing that each nested calculus inherits favorable proof-theoretic properties from its associated labelled calculus
Frenkel and charge transfer excitons in C60
We have studied the low energy electronic excitations of C60 using momentum
dependent electron energy-loss spectroscopy in transmission. The momentum
dependent intensity of the gap excitation allows the first direct experimental
determination of the energy of the 1Hg excitation and thus also of the total
width of the multiplet resulting from the gap transition. In addition, we could
elucidate the nature of the following excitations - as either Frenkel or charge
transfer excitons.Comment: RevTEX, 3 Figures, to appear in Phys. Rev.
Avaliação das caracterĂsticas morfolĂłgicas do sistema radicular de linhagens recombinantes endogâmicas de sorgo em solução nutritiva sob estresse de fĂłsforo.
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