4,895 research outputs found
Molecular motion of the main chain for a series of poly(alkyl L-glutamate)s as studied by H-2 NMR
H-2 NMR measurements were carried out for a series of poly(alkyl L-glutamate)s (PALG) in which the H-1 of the amide group in the main chain is replaced by H-2 in order to investigate the mobility and motional mode of the main chain. At low temperature, the H-2 spectra were typical powder patterns, which have three principal values. The temperature dependencies for the H-2 NMR spectra varied with the side chain length. For PALG with a short side chain length, Deltanu(1), Deltanu(2), and Deltanu(3) are almost constant in all temperature ranges. As the side chain length increases, the difference between the peaks and shoulders decreased with temperature. For PG-12-N-D, the peaks and shoulders are fused at high temperature in a liquid crystalline state. The mobility and molecular motion of the main chain is discussed based on the obtained H-2 NMR spectra
Structure and mobility of a series of poly(alkyl L-glutamate)s studied by VT C-13 CPMAS NMR spectroscopy
VT CPMAS NMR measurements were carried out for a series of poly(alkyl L-glutamate)s (PALG) which have n-alkyl side chains with carbon numbers ranging from 2 to 12 in order to investigate the structure and mobility of the main and the side chains. From the temperature dependencies of the peak intensities for the PALGs, the relative mobilities of the main and side chains are discussed. For PG-2 and PG-4, the molecular motions of both the main and side chains are not very fast. From the amount ratio between the main and side chains, the main chain dominates the entire mobility of the polymer. As the side chain length increases, the side chain motion is drastically activated by a temperature change. In addition, the main chain motion is induced by the side chain motion. For PALGs with long alkyl side chains, the mobilities of the polymers are governed by the structure and mobility of the side chain
Energy expenditure, recovery oxygen consumption, and substrate oxidation during and after body weight resistance exercise with slow movement compared to treadmill walking
The benefit of body weight resistance exercise with slow movement (BWRE-slow) for muscle function is well-documented, but not for energy metabolism. We aimed to examine physiological responses [e.g., energy expenditure (EE), respiratory exchange ratio (RER), and blood lactate (La)] during and after BWRE-slow compared to EE-matched treadmill walking (TW). Eight healthy young men (23.4 ± 1.8 years old, 171.2 ± 6.2 cm, 63.0 ± 4.8 kg) performed squat, push-up, lunge, heel-raise, hip-lift, and crunch exercises with BWRE-slow modality. Both the concentric and eccentric phases were set to 3 s. A total of three sets (10 repetitions) with 30 s rest between sets were performed for each exercise (26.5 min). On another day, subjects walked on a treadmill for 26.5 min during which EE during exercise was matched to that of BWRE-slow with the researcher controlling the treadmill speed manually. The time course changes of EE and RER were measured. The EE during exercise for BWRE-slow (92.6 ± 16.0 kcal for 26.5 min) was not significantly different from the EE during exercise for TW (95.5 ± 14.1 kcal, p = 0.36). BWRE-slow elicited greater recovery EE (40.55 ± 3.88 kcal for 30 min) than TW (37.61 ± 3.19 kcal, p = 0.029). RER was significantly higher in BWRE-slow during and 0–5 min after exercise, but became significantly lower during 25–30 min after exercise, suggesting greater lipid oxidation was induced about 30 min after exercise in BWRE-slow compared to TW. We also indicated that BWRE-slow has 3.1 metabolic equivalents in average, which is categorized as moderate-intensity physical activity
Development of a low-mass and high-efficiency charged particle detector
We developed a low-mass and high-efficiency charged particle detector for an
experimental study of the rare decay . The
detector is important to suppress the background with charged particles to the
level below the signal branching ratio predicted by the Standard Model
(O(10)). The detector consists of two layers of 3-mm-thick plastic
scintillators with wavelength shifting fibers embedded and Multi Pixel Photon
Counters for readout. We manufactured the counter and evaluated the performance
such as light yield, timing resolution, and efficiency. With this design, we
achieved the inefficiency per layer against penetrating charged particles to be
less than , which satisfies the requirement of the KOTO
experiment determined from simulation studies.Comment: 20 pages, 18 figure
An aerogel Cherenkov detector for multi-GeV photon detection with low sensitivity to neutrons
We describe a novel photon detector which operates under an intense flux of
neutrons. It is composed of lead-aerogel sandwich counter modules. Its salient
features are high photon detection efficiency and blindness to neutrons. As a
result of Monte Carlo (MC) simulations, the efficiency for photons with the
energy larger than 1 GeV is expected to be higher than 99.5% and that for 2
GeV/ neutrons less than 1%. The performance on the photon detection under
such a large flux of neutrons was measured for a part of the detector. It was
confirmed that the efficiency to photons with the energy 1 GeV was
consistent with the MC expectation within 8.2% uncertainty.Comment: 16 pages, 16 figures, submitted to Prog. Theor. Exp. Phy
Instability and Periodic Deformation in Bilayer Membranes Induced by Freezing
The instability and periodic deformation of bilayer membranes during freezing
processes are studied as a function of the difference of the shape energy
between the high and the low temperature membrane states. It is shown that
there exists a threshold stability condition, bellow which a planar
configuration will be deformed. Among the deformed shapes, the periodic curved
square textures are shown being one kind of the solutions of the associated
shape equation. In consistency with recent expe rimental observations, the
optimal ratio of period and amplitude for such a texture is found to be
approximately equal to (2)^{1/2}\pi.Comment: 8 pages in Latex form, 1 Postscript figure. To be appear in Mod.
Phys. Lett. B. 199
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