11 research outputs found
ELECTROCHEMICAL AND SPECTROSCOPIC PROPERTIES OF DIMERIC COFACIAL PORPHYRINS WITH NONELECTROACTIVE METAL CENTERS - DELOCALIZATION PROCESSES IN THE PORPHYRIN PI-CATION-RADICAL SYSTEMS
- Publication venue
- 'American Chemical Society (ACS)'
- Publication date
- 01/02/2019
- Field of study
The proximity of two or more porphyrins has been shown to be crucial in numerous biological processes such as electron transfer or oxygen activation. We report the electrochemical and spectroscopic (UV-vis, EPR) behavior of two families of dimeric cofacial diporphyrins, either covalently linked by two amide bridges (FTFn family) or monolinked by a polyaromatic bridge ("Pacman" DPX family). The derivatives with nonelectroactive centers (H2, Zn, Cu) are investigated; thus the redox systems are centered on the pi-ring systems only. When the two rings are sufficiently far apart, the dimer nearly behaves as the juxtaposition of two monomers. A two-electron oxidation process formally gives rise to a pi-cation diradical, and in one case a triplet-state spectrum can be observed. When the two rings are very close, strong pi-pi interactions generate mixed-valence behavior: the first oxidation process is split into two one-electron steps. The first oxidation product is a totally delocalized pi-radical, while in the second the two delocalized electrons of the rings become spin-paired, giving rise to a kind of nonclassical pi-pi bond. Analysis of the results and rationalization with the literature demonstrate that from a redox standpoint these molecules have to be considered as a single redox entity. A qualitative molecular orbital diagram is proposed which accounts for the enhanced electronic properties of these dimers.X1166sci
Effects of repeated exposure to an estrus synchronization protocol on reproductive parameters in dairy goats
- Author
- Publication venue
- 'Canadian Science Publishing'
- Publication date
- Field of study
A RADIOIMMUNOASSAY FOR GROWTH HORMONE RELEASE-INHIBITING HORMONE: METHOD AND QUANTITATIVE TISSUE DISTRIBUTION
- Author
- Publication venue
- 'Wiley'
- Publication date
- Field of study
Low dielectric constant materials
- Author
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- Field of study
Synthesis of Cu3.21Bi4.79S9 bismuth chalcogenide by mechanical alloying
- Author
- B.D. Long
- Barma
- Bashir
- Bell
- Calka
- Cantarero
- Chen
- Edelstein
- Elsheikh
- Ge
- Ge
- Hendricks
- Hsu
- Ioannou
- Ji
- K. Kimura
- Kadel
- Kanatzidis
- Kanatzidis
- Kanatzidis
- Loginov
- M.C. Barma
- M.F.M. Sabri
- McCarthy
- McCarthy
- Mrotzek
- N.H. Hai
- Ohmasa
- R. Saidur
- Rong
- Rowe
- S. Ramesh
- S.M. Said
- Shaw
- Skoug
- Snyder
- Sugaki
- Suryanarayana
- Suñol
- T.B. Trung
- T.D. Huy
- Varin
- Wood
- Yu
- Zhao
- Zhou
- Publication venue
- 'Elsevier BV'
- Publication date
- Field of study
Prediction of digging performance in mining
- Author
- Atkinson T.
- Atkinson T.
- Barton N
- Deere D.U.
- Evans I.
- Franklin J.A.
- Franklin J.A.
- Hendricks C.
- Hill R.
- Howarth D.F.
- Ismail A.M.
- J. Hadjigeorgiou
- Kazi A.
- Kirsten H.A.D.
- Kirsten H.A.D.
- Ladanyi B.
- Leps T.M.
- M. J. Scoble
- Milner D.
- Mol O.
- O'Regan G.
- Oook N.G.W.
- Osman M.S.
- Paul B.
- Read J.R.L.
- Reece A.R.
- Reichmuth D.R.
- Scoble M.J.
- Shand A.N.
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- Singh R.N.
- Smart B.G.D.
- Smith H.J.
- Stacy T.R.
- Wade N.H.
- Weaver J.M.
- West G.
- Williamson S.
- Publication venue
- 'Informa UK Limited'
- Publication date
- Field of study
Low dielectric constant materials for advanced interconnects
- Author
- A. Griffin
- A. Hurd
- C. Graas
- C. Hu
- C. Jin
- C. Jin
- C.-K. Hu
- C.J. Brinker
- C.T. Rosenmayer
- C.V. Nguyen
- Chuan Hu
- D. Burdeaux
- D. Edelstein
- D. Krevelen
- D.C. Edelstein
- E. Todd
- G. Hougham
- G.W. Ray
- J. Fricke
- J. Gross
- J. Gross
- J. Leu
- J.-H. Zhao
- J.G. Ryan
- J.N. Bremmer
- Jie-Hua Zhao
- K.E. Goodson
- K.J. Miller
- L.C. Klein
- M.T. Bohr
- Michael Morgen
- N. Hacker
- N.H. Hendricks
- O.W. Kading
- P.-H. Wang
- P.-H. Wang
- P.H. Townsend
- P.S. Ho
- Paul S. Ho
- R.A. Kirchhoff
- S. Jeng
- S. Jeng
- S. Venkatesan
- S.-P. Jeng
- S.H. Pine
- S.M. Kim
- S.S. Prakash
- Taiheui Cho
- W. Shih
- W.-L. Wu
- W.-Y. Shih
- W.W. Lee
- Y. Lu
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- Field of study
The role of micro-organisms in the ecological connectivity of running waters
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- Aiken G.R.
- Aiken G.R.
- Aller R.C.
- Amann R.I.
- Amon R.M.W.
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- Baerlocher F.
- Baerlocher F.
- Bajkiewicz-Grabowska E.
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- Becker G.
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- Biggs B.J.F.
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- Boon P.I.
- Borchardt M.A.
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- Bott T.L.
- Bott T.L.
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- Bou C.
- Boulton A.J.
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- Bretschko G.
- Brettar I.
- Brettar I.
- Bridge J.S.
- Bruesch W.
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- Fiebig D.M.
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- Fisher S.G.
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- Publication venue
- 'Wiley'
- Publication date
- 01/01/1998
- Field of study
Pusch M, Fiebig D, Brettar I, et al. The role of micro-organisms in the ecological connectivity of running waters. Freshwater Biology. 1998;40(3):453-495
Understanding the Monoclonal Antibody Involvement in Targeting the Activation of Tumor Suppressor Genes
- Author
- Abreu Velez.
- Ahamadi M.
- Ahmad A.
- Ajay Kumar
- Akinleye A.
- Akshay Vyawahare
- Aktas Y.
- Anas Ahmad
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- Choudhury H.
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- Coulson A.
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- Cruz E.
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- Dagogo-Jack I.
- Damodaran S.
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- Daugherty A.L.
- De Palma,M.
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- Dienstmann R.
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- Publication date
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Smectites and related silicates
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- G.L. Parfitt
- G.L. Taylor
- G.N. White
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- G.W. Brindley
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- H. Kodama
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- H. Kristmannsdottir
- H. Levanon
- H. Nishihara
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- H. Pollak
- H. Sato
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- H. Suquet
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- H. Van Olphen
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- H.C. Gupta
- H.D. Morris
- H.E. Roberson
- H.E. Robertson
- H.H. Murray
- H.J. Behrens
- H.J. Bray
- H.J. Jakobsen
- H.J. Jakobsen
- H.K. Chang
- H.N. Khoury
- H.P. He
- H.Z. Friedlander
- I. Barshad
- I. Bérend
- I. Hannus
- I. Ravina
- I. Rozenson
- I. Rozenson
- I. Rozenson
- I. Rozenson
- I. Rozenson
- I. Rozenson
- I. Shainberg
- I. Shainberg
- I. Shainberg
- I. Shainberg
- I. Tkac
- I. Waclawska
- I. Yusuke
- I.A. Rukavishnikova
- I.S. Suzuki
- J. Ben Brahim
- J. Ben Brahim
- J. Beyer
- J. Conrad
- J. Cuadros
- J. Cuevas
- J. Garcia-Miragaya
- J. Garcia-Miragaya
- J. Graham
- J. Grandjean
- J. Grandjean
- J. Gruner
- J. Hougardy
- J. Hougardy
- J. Howard
- J. Hower
- J. Ikhsan
- J. Komusinki
- J. Lee
- J. Lee
- J. Madejova
- J. Madejova
- J. Madejova
- J. Madejova
- J. Madejova
- J. Madejova
- J. Maes
- J. Mering
- J. Mering
- J. Méring
- J. Poyato
- J. Quakernaat
- J. Sanz
- J. Sanz
- J. Sanz
- J. Sanz
- J. Sanz
- J. Van Wonterghem
- J. Wu
- J.A. Helsen
- J.A. Raussel-Colom
- J.A. Whelan
- J.B. Hemwall
- J.C. Bart
- J.C. Dyre
- J.C. Dyre
- J.C.Q. Fletcher
- J.D. Grice
- J.D. Hamilton
- J.D. Morton
- J.D. Rhoades
- J.D. Russel
- J.D. Russell
- J.D. Russell
- J.D. Russell
- J.D. Russell
- J.E. Alcover
- J.E. Campbell
- J.F. Alcover
- J.F. Burst
- J.F. Burst
- J.F. Lambert
- J.F. Relyea
- J.G. Thompson
- J.H. Johnston
- J.H. Johnston
- J.H. Wu
- J.J. Fripiat
- J.J. Tuck
- J.J.H. Ackerman
- J.L. Bischoff
- J.L. Bishop
- J.L. Perez-Rodriguez
- J.L. Post
- J.L. Post
- J.M. Cases
- J.M. Corker
- J.M. Serratosa
- J.M. Trillo
- J.M. Zachara
- J.M.D. Coey
- J.M.D. Coey
- J.M.D. Coey
- J.M.D. Coey
- J.P. Quirk
- J.P.E. Jones
- J.T. Iiyama
- J.T. Iiyama
- J.T. Kendall
- J.T. Kloprogge
- J.T. Kloprogge
- J.T. Kloprogge
- J.T. Kloprogge
- J.T. Kloprogge
- J.T. Kloprogge
- J.T. Kloprogge
- J.V. Smith
- J.W. Gilman
- J.W. Stucki
- J.W. Stucki
- J.W. Stucki
- J.W. Stucki
- J.X. Zhu
- J.Y. Carriat
- K. Abraham
- K. Emmerich
- K. Emmerich
- K. Funke
- K. Koga
- K. Koga
- K. Magara
- K. Miyahara
- K. Norrish
- K. Ohtsuka
- K. Urabe
- K. Wada
- K.A. Carrado
- K.A. Carrado
- K.A. Smith
- K.B. Krauskopf
- K.G. Scheckel
- K.J.D. Mac Kenzie
- K.J.D. Mac Kenzie
- K.J.D. Mac Kenzie
- K.J.D. Mac Kenzie
- K.J.D. MacKenzie
- K.M. Kemner
- K.W. Lemons
- K.W. Lemons
- L. Bergaoui
- L. Daza
- L. Delevoye
- L. Gruner
- L. Heller-Kallai
- L. Heller-Kallai
- L. Heller-Kallai
- L. Lerot
- L. Li
- L. Pauling
- L. Storaro
- L. Storaro
- L. Zhang
- L.A. Bettison
- L.C.A. Oliveira
- L.G. Dainyak
- L.G. Daynyak
- L.G. Daynyak
- L.G. Daynyak
- L.G. Schultz
- L.J. Johnson
- L.J. Michot
- L.L. Huve
- L.L. Huve
- L.M. Coyne
- L.M. Coyne
- L.M. Coyne
- L.M. Coyne
- L.P. Manias
- L.P. Meier
- L.Q. Wang
- M. Alexandre
- M. Auboiroux
- M. Foster
- M. Ishii
- M. Kaneyoshi
- M. Kawasumi
- M. Kojima
- M. Lenarda
- M. Lipsicas
- M. Mc Bride
- M. Mc Bride
- M. Mägi
- M. Nakahira
- M. Nakano
- M. Ogawa
- M. Ogawa
- M. Pelletier
- M. Persson
- M. Plötze
- M. Schlegel
- M. Slonimskaya
- M. Suzuki
- M. Suzuki
- M. Suzuki
- M. Takahashi
- M. Takeda
- M.A. Karakassides
- M.A. Karakassides
- M.A. Vicente
- M.A. Vicente Rodriguez
- M.A. Wilson
- M.A. Wolfe
- M.B. Mc Bride
- M.B. Mc Bride
- M.B. Mc Bride
- M.B. Mc Bride
- M.B. Mc Bride
- M.C. Ball
- M.C. Powers
- M.D. Alba
- M.D. Alba
- M.D. Alba
- M.D. Alba
- M.E. Harward
- M.F Brigatti
- M.F. Brigatti
- M.F. Brigatti
- M.F. Brigatti
- M.F. Brigatti
- M.F. Thorpe
- M.G. Townsend
- M.G. Townsend
- M.H. Bradbury
- M.H. Stone
- M.I. Scullane
- M.K. Anis
- M.L. Farquhar
- M.L. Schlegel
- M.M. Mortland
- M.N. Pafamov
- M.S. Stul
- M.V. Eirish
- M.V. Eyrish
- M.W. Molloy
- N. Frini
- N. Güven
- N. Güven
- N. Janes
- N. Kohyama
- N. Lahav
- N. Lahav
- N. Lahav
- N. Malathi
- N. Petersen
- N. Sahai
- N. Wada
- N. Wada
- N.C.M. Alma
- N.H. Gangas
- N.H.J. Gangas
- N.M. Johnson
- N.T. Skipper
- N.T. Skipper
- N.T. Skipper
- N.T. Skipper
- N.V. Venkataraman
- O. Abollino
- O. Ballet
- O. Ballet
- O. Grauby
- O. Grauby
- O. Talibudeen
- P. Bayliss
- P. Di Leo
- P. Di Leo
- P. Di Leo
- P. Komadel
- P. Olivera-Pastor
- P. O’Day
- P. Salerno
- P. Wong
- P. Zhou
- P.A. Oberlin
- P.A. Schroeder
- P.C. Le Baron
- P.C. Zhang
- P.D.G. Cradwick
- P.F. Barron
- P.F. Barron
- P.F. Barron
- P.F. Low
- P.F. Low
- P.F. Low
- P.F. Low
- P.F. Low
- P.G. Slade
- P.G. Slade
- P.G. Slade
- P.G. Slade
- P.G. Slade
- P.G. Slade
- P.G. Slade
- P.L. Hall
- P.L. Hall
- P.L. Hall
- P.L. Ildefonse
- P.L. Tien
- P.M. Bell
- P.N. Sen
- P.R. Lear
- P.R. Lear
- P.R. Lear
- P.V. Brady
- R. Aasa
- R. Alvero
- R. Calvet
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- R. Glaeser
- R. Glaeser
- R. Glasier
- R. Green-Kelly
- R. Green-Kelly
- R. Molina
- R. Pampuch
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- R. Pushkareva
- R. Schuette
- R. Tettenhorst
- R. Tettenhorst
- R. Tettenhorst
- R. Van Bladel
- R. Wardle
- R.A. Kinsey
- R.A. Leonard
- R.A. Schoonheydt
- R.A. Schoonheydt
- R.A. Vaia
- R.B. Singer
- R.C. Mackenzie
- R.C. Reynolds
- R.C. Reynolds
- R.D. Wauchope
- R.E. Ferrell
- R.E. Grim
- R.E. Meads
- R.G. Ford
- R.J. Kirkpatrick
- R.J. Kirkpatrick
- R.J. Kirkpatrick
- R.J. Kirkpatrick
- R.J. Parfitt
- R.J.M.J. Vogels
- R.J.M.J. Vogels
- R.J.M.J. Vogels
- R.K. Hawkins
- R.L. Freed
- R.L. Frost
- R.L. Frost
- R.L. Frost
- R.L. Frost
- R.L. Frost
- R.L. Parfitt
- R.L. Parfitt
- R.M. Almeida
- R.M. Hazen
- R.M. Mineeva
- R.M. Pashley
- R.M. Pashley
- R.M. Pashley
- R.M. Rolf
- R.N. Clark
- R.W. Mooney
- R.W.T. Wilkins
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- S. Bank
- S. Barman
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- S. Ganapathy
- S. Guggenheim
- S. Jun
- S. Karaborni
- S. Komameni
- S. Komareni
- S. Lee
- S. Letaief
- S. Moreno
- S. Petit
- S. Petit
- S. Petit
- S. Shen
- S. Shoval
- S. Sorieul
- S. Yamanaka
- S. Yamanaka
- S. Yamanaka
- S. Yamanaka
- S. Yamanaka
- S.A. Bagshaw
- S.A. Chen
- S.A. Solin
- S.B. Hendricks
- S.B. Hendricks
- S.D. Burnside
- S.D. Logsdon
- S.D. Logsdon
- S.D. Logsdon
- S.E. Bailey
- S.E. Miller
- S.I. Tsipursky
- S.I. Tsipursky
- S.I. Tsipursky
- S.I. Wada
- S.J. Larson
- S.J. Van der Gaast
- S.P. Altaner
- S.P. Bond
- S.P. Hyun
- S.R. Drachman
- S.S. Gupta
- S.S. Hou
- S.W. Bailey
- S.W. Bailey
- S.W. Bailey
- S.W. Karickoff
- S.Y. Lee
- T. Allard
- T. Allard
- T. Allard
- T. Cole
- T. Delineau
- T. Ebina
- T. Endo
- T. Ericsson
- T. Ericsson
- T. Henmi
- T. Henmi
- T. Ishida
- T. Iwasaki
- T. Lan
- T. Matsuda
- T. Nishiyama
- T. Ohkubo
- T. Saarenketo
- T. Vengris
- T. Yui
- T.C. Wu
- T.D. Tsai
- T.J. Pinnavaia
- T.J. Pinnavaia
- T.J. Pinnavaia
- T.J. Pinnavaia
- T.W. Lee
- V. Berkheiser
- V. Cicel
- V. Hofmann
- V. Hofmann
- V. Luca
- V. Luca
- V. Luca
- V. Luca
- V. Marry
- V. Stubican
- V.A. Drits
- V.A. Drits
- V.A. Drits
- V.A. Drits
- V.A. Drits
- V.C. Farmer
- V.C. Farmer
- V.C. Farmer
- V.C. Farmer
- V.C. Farmer
- V.C. Farmer
- V.C. Farmer
- V.C. Farmer
- V.S. Komarov
- W. Gao
- W. Keune
- W. Loewenstein
- W. Noll
- W. Schreyer
- W.C. Hood
- W.D. Johns
- W.D. Keller
- W.F. Bleam
- W.F. Bleam
- W.F. Bradley
- W.F. Bradley
- W.F. Jaynes
- W.F. Jaynes
- W.H. Yang
- W.H. Yu
- W.J. Plumley
- W.L. Earl
- W.L. Huang
- W.P. Gates
- W.P. Gates
- W.P. Gates
- W.P. Gates
- W.S. Callaway
- W.T. Granquist
- Y. Chun
- Y. Kim
- Y. Kim
- Y. Kitagawa
- Y. Kitagawa
- Y. Kojima
- Y. Nakashima
- Y. Qi
- Y.B. Ma
- Y.B. Osipov
- Y.H. Shau
- Y.H. Shau
- Y.Q. Li
- Y.S. Han
- Y.S. Han
- Y.S. Han
- Y.S. Zhang
- Yu.M. Korolev
- Yu.M. Korolev
- Z. Egozy
- Z. Klapyta
- Z. Wang
- Z. Weiss
- Publication venue
- 'Springer Science and Business Media LLC'
- Publication date
- 01/01/2007
- Field of study