TiO2-WO3 composite nanotubes from co-sputtered thin films on si substrate for enhanced photoelectrochemical water splitting

pre-printElectrochemical anodization of a Ti-W nano-composite thin films deposited on a Si substrate by simultaneous magnetron sputtering of Ti and W resulted in the formation of TiO2-WO3 nanotubular arrays. A change in the morphology of TiO2-WO3 composite nanotubes with varying percentage of W in Ti-W composite thin films was observed. With a W density of less than or equal to 1.75 × 1019 W atoms per cm3 (after anodization), the morphology of the composite nanotubes were similar to that of plain TiO2 nanotubes. Whereas with further increase in W density resulted in a nanoporous morphology. Ti-W composite films were also deposited on Si substrates with a 100 nm thick layer of tin doped indium oxide (ITO) to examine the PEC activity of the formed oxide composites. The TiO2-WO3 composite nanotubes with 1.05 × 1019 W atoms per cm3 (3.15 × 1018 W atoms per cm3 before anodization) demonstrated to be an optimal W density for this system, giving rise to 40% increase in photocurrent at 0.5 V (vs. Ag/AgCl) compared to plain TiO2 nanotubes

Growth and characterization of TiO2 nanotubes from sputtered Ti film on Si substrate

In this paper, we present the synthesis of self-organized TiO(2) nanotube arrays formed by anodization of thin Ti film deposited on Si wafers by direct current (D.C.) sputtering. Organic electrolyte was used to demonstrate the growth of stable nanotubes at room temperature with voltages varying from 10 to 60 V (D.C.). The tubes were about 1.4 times longer than the thickness of the sputtered Ti film, showing little undesired dissolution of the metal in the electrolyte during anodization. By varying the thickness of the deposited Ti film, the length of the nanotubes could be controlled precisely irrespective of longer anodization time and/or anodization voltage. Scanning electron microscopy, atomic force microscopy, diffuse-reflectance UV–vis spectroscopy, and X-ray diffraction were used to characterize the thin film nanotubes. The tubes exhibited good adhesion to the wafer and did not peel off after annealing in air at 350 °C to form anatase TiO(2). With TiO(2) nanotubes on planar/stable Si substrates, one can envision their integration with the current micro-fabrication technique large-scale fabrication of TiO(2) nanotube-based devices

Exact Eigenstates of Tight-Binding Hamiltonians on the Penrose Tiling

We investigate exact eigenstates of tight-binding models on the planar rhombic Penrose tiling. We consider a vertex model with hopping along the edges and the diagonals of the rhombi. For the wave functions, we employ an ansatz, first introduced by Sutherland, which is based on the arrow decoration that encodes the matching rules of the tiling. Exact eigenstates are constructed for particular values of the hopping parameters and the eigenenergy. By a generalized ansatz that exploits the inflation symmetry of the tiling, we show that the corresponding eigenenergies are infinitely degenerate. Generalizations and applications to other systems are outlined.Comment: 24 pages, REVTeX, 13 PostScript figures include

Spin effects in gravitational radiation backreaction II. Finite mass effects

A convenient formalism for averaging the losses produced by gravitational radiation backreaction over one orbital period was developed in an earlier paper. In the present paper we generalize this formalism to include the case of a closed system composed from two bodies of comparable masses, one of them having the spin S. We employ the equations of motion given by Barker and O'Connell, where terms up to linear order in the spin (the spin-orbit interaction terms) are kept. To obtain the radiative losses up to terms linear in the spin, the equations of motion are taken to the same order. Then the magnitude L of the angular momentum L, the angle kappa subtended by S and L and the energy E are conserved. The analysis of the radial motion leads to a new parametrization of the orbit. From the instantaneous gravitational radiation losses computed by Kidder the leading terms and the spin-orbit terms are taken. Following Apostolatos, Cutler, Sussman and Thorne, the evolution of the vectors S and L in the momentary plane spanned by these vectors is separated from the evolution of the plane in space. The radiation-induced change in the spin is smaller than the leading-order spin terms in the momentary angular momentum loss. This enables us to compute the averaged losses in the constants of motion E, L and L_S=L cos kappa. In the latter, the radiative spin loss terms average to zero. An alternative description using the orbital elements a,e and kappa is given. The finite mass effects contribute terms, comparable in magnitude, to the basic, test-particle spin terms in the averaged losses.Comment: 12 pages, 1 figure, Phys.Rev.D15, March, 199

Generalized quasiperiodic Rauzy tilings

We present a geometrical description of new canonical $d$-dimensional codimension one quasiperiodic tilings based on generalized Fibonacci sequences. These tilings are made up of rhombi in 2d and rhombohedra in 3d as the usual Penrose and icosahedral tilings. Thanks to a natural indexing of the sites according to their local environment, we easily write down, for any approximant, the sites coordinates, the connectivity matrix and we compute the structure factor.Comment: 11 pages, 3 EPS figures, final version with minor change

Energy spectra, wavefunctions and quantum diffusion for quasiperiodic systems

We study energy spectra, eigenstates and quantum diffusion for one- and two-dimensional quasiperiodic tight-binding models. As our one-dimensional model system we choose the silver mean or `octonacci' chain. The two-dimensional labyrinth tiling, which is related to the octagonal tiling, is derived from a product of two octonacci chains. This makes it possible to treat rather large systems numerically. For the octonacci chain, one finds singular continuous energy spectra and critical eigenstates which is the typical behaviour for one-dimensional Schr"odinger operators based on substitution sequences. The energy spectra for the labyrinth tiling can, depending on the strength of the quasiperiodic modulation, be either band-like or fractal-like. However, the eigenstates are multifractal. The temporal spreading of a wavepacket is described in terms of the autocorrelation function C(t) and the mean square displacement d(t). In all cases, we observe power laws for C(t) and d(t) with exponents -delta and beta, respectively. For the octonacci chain, 0<delta<1, whereas for the labyrinth tiling a crossover is observed from delta=1 to 0<delta<1 with increasing modulation strength. Corresponding to the multifractal eigenstates, we obtain anomalous diffusion with 0<beta<1 for both systems. Moreover, we find that the behaviour of C(t) and d(t) is independent of the shape and the location of the initial wavepacket. We use our results to check several relations between the diffusion exponent beta and the fractal dimensions of energy spectra and eigenstates that were proposed in the literature.Comment: 24 pages, REVTeX, 10 PostScript figures included, major revision, new results adde

Tissue inhibitor of metalloproteinase-1 (TIMP-1) regulates mesenchymal stem cells through let-7f microRNA and Wnt/β-catenin signaling

Tissue inhibitor of metalloproteinases 1 (TIMP-1) is a matrix metalloproteinase (MMP)-independent regulator of growth and apoptosis in various cell types. The receptors and signaling pathways that are involved in the growth factor activities of TIMP-1, however, remain controversial. RNA interference of TIMP-1 has revealed that endogenous TIMP-1 suppresses the proliferation, metabolic activity, and osteogenic differentiation capacity of human mesenchymal stem cells (hMSCs). The knockdown of TIMP-1 in hMSCs activated the Wnt/β-catenin signaling pathway as indicated by the increased stability and nuclear localization of β-catenin in TIMP-1–deficient hMSCs. Moreover, TIMP-1 knockdown cells exhibited enhanced β-catenin transcriptional activity, determined by Wnt/β-catenin target gene expression analysis and a luciferase-based β-catenin– activated reporter assay. An analysis of a mutant form of TIMP-1 that cannot inhibit MMP indicated that the effect of TIMP-1 on β-catenin signaling is MMP independent. Furthermore, the binding of CD63 to TIMP-1 on the surface of hMSCs is essential for the TIMP-1–mediated effects on Wnt/β-catenin signaling. An array analysis of microRNAs (miRNAs) and transfection studies with specific miRNA inhibitors and mimics showed that let-7f miRNA is crucial for the regulation of β-catenin activity and osteogenic differentiation by TIMP-1. Let-7f was up-regulated in TIMP-1–depleted hMSCs and demonstrably reduced axin 2, an antagonist of β-catenin stability. Our results demonstrate that TIMP-1 is a direct regulator of hMSC functions and reveal a regulatory network in which let-7f modulates Wnt/β-catenin activity