Preparation of homogeneous vitreous materials for electronic and optical devices

Vitreous material builds up as series of solidified layers on inside walls of sealed quartz ampoule containing molten constituents of material, and forms well defined shapes to close dimensional tolerances. Ampoules are made of material which does not react with melt and has lower thermal expansion coefficient than solidified layer

Chemical and spectroscopic evidence for the formation of a ferryl Fea3 intermediate during turnover of cytochrome c oxidase

Journal ArticleWhen partially reduced cytochrome c oxidase samples are reoxidized with dioxygen, an EPR-silent dioxygen intermediate, which is at the three-electron level of dioxygen reduction, is trapped at the dioxygen reduction site. The intermediate has novel spectral features at 580 and 537 nm. Combined optical and EPR results reveal that this intermediate reacts rapidly with CO at 277-298 K causing the abolition of the 5801 537 nm features and the appearance of a rhombic CuB EPR signal

A search for continuous fluorescence in reflection nebulae

Photometric and spectrophotometric observations were made of the reflection nebulae NGC1435, NGC2068, NGC7023, and IC1287 in an attempt to detect continuous fluorescence by dust grains. Several effects of importance for observations of such faint objects are discussed, including instrumental light scattering, a photographic effect, and a time delay effect which can occur if the illuminating star is a spectrum variable. It is found that continuous fluorescence by interstellar grains is not likely to exist and that it cannot account for more than 10 percent of the total surface brightness of these reflection nebulae. No evidence of diffuse interstellar features is found in the spectra of these nebulae

Double precision trajectory program /DPTRAJ 2.2C/

Four part program computes trajectory of space probe moving in solar system and subject to variety of forces

Quaestor: Query web caching for database-as-a-service providers

Today, web performance is primarily governed by round-trip latencies between end devices and cloud services. To improve performance, services need to minimize the delay of accessing data. In this paper, we propose a novel approach to low latency that relies on existing content delivery and web caching infrastructure. The main idea is to enable application-independent caching of query results and records with tunable consistency guarantees, in particular bounded staleness. Q uaestor (Query Store) employs two key concepts to incorporate both expiration-based and invalidation-based web caches: (1) an Expiring Bloom Filter data structure to indicate potentially stale data, and (2) statistically derived cache expiration times to maximize cache hit rates. Through a distributed query invalidation pipeline, changes to cached query results are detected in real-time. The proposed caching algorithms offer a new means for data-centric cloud services to trade latency against staleness bounds, e.g. in a database-as-a-service. Q uaestor is the core technology of the backend-as-a-service platform Baqend, a cloud service for low-latency websites. We provide empirical evidence for Q uaestor 's scalability and performance through both simulation and experiments. The results indicate that for read-heavy workloads, up to tenfold speed-ups can be achieved through Q uaestor 's caching. </jats:p

Quantum theory of massless (p,0)-forms

We describe the quantum theory of massless (p,0)-forms that satisfy a suitable holomorphic generalization of the free Maxwell equations on Kaehler spaces. These equations arise by first-quantizing a spinning particle with a U(1)-extended local supersymmetry on the worldline. Dirac quantization of the spinning particle produces a physical Hilbert space made up of (p,0)-forms that satisfy holomorphic Maxwell equations coupled to the background Kaehler geometry, containing in particular a charge that measures the amount of coupling to the U(1) part of the U(d) holonomy group of the d-dimensional Kaehler space. The relevant differential operators appearing in these equations are a twisted exterior holomorphic derivative and its hermitian conjugate (twisted Dolbeault operators with charge q). The particle model is used to obtain a worldline representation of the one-loop effective action of the (p,0)-forms. This representation allows to compute the first few heat kernel coefficients contained in the local expansion of the effective action and to derive duality relations between (p,0) and (d-p-2,0)-forms that include a topological mismatch appearing at one-loop.Comment: 32 pages, 3 figure

Natural history and evolution of an elevational generalist, the Cinereous Conebill (Conirostrum cinereum)

Elevational generalism is relatively rare in the tropical Andes Mountains, likely owing to the inherent requirements of enduring a high degree of climatic zonation and coping with hypoxic stress. The Cinereous Conebill (Conirostrum cinereum) appears to be an exception, and inhabits a continuous elevational distribution that spans over 4,500 m. Two subspecies, cinereum and fraseri, are restricted to high elevations and may be isolated, whereas the third and most widespread, littorale, occurs continuously along the western slope of the Andes from 0 to over 4,500 m. First, we aim to characterize the morphology, genetics, and climatic niche of the three subspecies using a comparative biogeographic approach to explore patterns and timing of differentiation and to consider possible mechanisms of diversification. Second, we study whether hemoglobin adaptation plays a role in this elevational generalist’s ability to thrive in high-elevation environments, and whether localized adaptation is possible despite altitudinal migration and gene flow. We used a comparative phylogeographic framework to examine whether lineage divergence within C. cinereum is associated with climatic, geographic, and/or physiological barriers leading to incipient speciation

X-ray Halos and Large Grains in the Diffuse Interstellar Medium

Recent observations with dust detectors on board the interplanetary spacecraft Ulysses and Galileo have recorded a substantial flux of large interstellar grains with radii between 0.25 and 2.0 mu entering the solar system from the local interstellar cloud. The most commonly used interstellar grain size distribution is characterized by a a^-3.5 power law in grain radii a, and extends to a maximum grain radius of 0.25 mu. The extension of the interstellar grain size distribution to such large radii will have a major effect on the median grain size, and on the amount of mass needed to be tied up in dust for a given visual optical depth. It is therefore important to investigate whether this population of larger dust particles prevails in the general interstellar medium, or if it is merely a local phenomenon. The presence of large interstellar grains can be mainly inferred from their effect on the intensity and radial profiles of scattering halos around X-ray sources. In this paper we examine the grain size distribution that gives rise to the X-ray halo around Nova Cygni 1992. The results of our study confirm the need to extend the interstellar grain size distribution in the direction of this source to and possibly beyond 2.0 mu. The model that gives the best fit to the halo data is characterized by: (1) a grain size distribution that follows an a^-3.5 power law up to 0.50 mu, followed by an a^-4.0 extension from 0.50 mu to 2.0 mu; and (2) silicate and graphite (carbon) dust-to-gas mass ratios of 0.0044 and 0.0022, respectively, consistent with solar abundances constraints. Additional observations of X-ray halos probing other spatial directions are badly needed to test the general validity of this result.Comment: 17 pages, incl. 1 figure, accepted for publ. by ApJ Letter

M-theory on eight-manifolds revisited: N=1 supersymmetry and generalized Spin(7) structures

The requirement of ${\cal N}=1$ supersymmetry for M-theory backgrounds of the form of a warped product ${\cal M}\times_{w}X$, where $X$ is an eight-manifold and ${\cal M}$ is three-dimensional Minkowski or AdS space, implies the existence of a nowhere-vanishing Majorana spinor $\xi$ on $X$. $\xi$ lifts to a nowhere-vanishing spinor on the auxiliary nine-manifold $Y:=X\times S^1$, where $S^1$ is a circle of constant radius, implying the reduction of the structure group of $Y$ to $Spin(7)$. In general, however, there is no reduction of the structure group of $X$ itself. This situation can be described in the language of generalized $Spin(7)$ structures, defined in terms of certain spinors of $Spin(TY\oplus T^*Y)$. We express the condition for ${\cal N}=1$ supersymmetry in terms of differential equations for these spinors. In an equivalent formulation, working locally in the vicinity of any point in $X$ in terms of a `preferred' $Spin(7)$ structure, we show that the requirement of ${\cal N}=1$ supersymmetry amounts to solving for the intrinsic torsion and all irreducible flux components, except for the one lying in the $\bf{27}$ of $Spin(7)$, in terms of the warp factor and a one-form $L$ on $X$ (not necessarily nowhere-vanishing) constructed as a $\xi$ bilinear; in addition, $L$ is constrained to satisfy a pair of differential equations. The formalism based on the group $Spin(7)$ is the most suitable language in which to describe supersymmetric compactifications on eight-manifolds of $Spin(7)$ structure, and/or small-flux perturbations around supersymmetric compactifications on manifolds of $Spin(7)$ holonomy.Comment: 24 pages. V2: introduction slightly extended, typos corrected in the text, references added. V3: the role of Spin(7) clarified, erroneous statements thereof corrected. New material on generalized Spin(7) structures in nine dimensions. To appear in JHE

The Influence of High Density Grazing and Conventional, Rotational Grazing on Soil And Vegetation Parameters in the Semi-Arid and Mesic Grasslands of South Africa

In South Africa, multi-camp rotational grazing using ‘conservative stocking rates’ have been the conventional approach to livestock grazing management systems. However, as of late, the high-desnity approach (used interchangeably – depending on the situation – with regenerative grazing, mob grazing, short duration, high pressure grazing, rapid rotation, time controlled, ultra-high density, holistic grazing and holistic resource management) has been adopted by numerous farmers. This approach is considered to be an adaptable one, incorporating the ‘herd effect’ concept, whereby large numbers of animals occupy an area for short periods of time, and allowed an extended rest period. It claims to improve rangeland productivity by improving both vegetation and soil condition, and, in turn, enhancing animal productivity. However, scientifically sound information regarding these claims, as well as the influences of this strategy opposed to the conventional rotational systems in South Africa is somewhat lacking. The aim of our research is to explore the different facets of regenerative grazing, practiced by various livestock farmers in natural veld in the semi-arid and mesic grasslands of South Africa. These facets include different soil (physical and chemical parameters), vegetation (composition, dry matter production, necromass, cover and quality (i.e. crude protein (CP), neutral detergent fibre (NDF), acid detergent fibre (ADF), acid detergent lignin (ADL) and organic matter (OM)), animal and human (decision-making and financials) interactions and dynamics, in comparison to conventional, rotational grazing. Due to preliminary trials, only the forage quality parameters will be discussed. These parameters have been shown to differ between the two different grazing management strategies on a farm scale, however, not on a spatial scale. This project has the potential to produce scientific and objective information on the functionality of different grazing systems in the grasslands of South Africa, and it can, too, assist livestock farmers in understanding the rationale behind high pressure grazing