2,114 research outputs found
Excitons in boron nitride nanotubes: dimensionality effects
We show that the optical absorption spectra of boron nitride (BN) nanotubes
are dominated by strongly bound excitons. Our first-principles calculations
indicate that the binding energy for the first and dominant excitonic peak
depends sensitively on the dimensionality of the system, varying from 0.7 eV in
bulk hexagonal BN via 2.1 eV in the single sheet of BN to more than 3 eV in the
hypothetical (2,2) tube. The strongly localized nature of this exciton dictates
the fast convergence of its binding energy with increasing tube diameter
towards the sheet value. The absolute position of the first excitonic peak is
almost independent of the tube radius and system dimensionality. This provides
an explanation for the observed "optical gap" constancy for different tubes and
bulk hBN [R. Arenal et al., to appear in Phys. Rev. Lett. (2005)].Comment: 5 pages, 2 figure
Excitons and Many-Electron Effects in the Optical Response of Single-Walled Boron Nitride Nanotubes
We report first-principles calculations of the effects of quasiparticle
self-energy and electron-hole interaction on the optical properties of
single-walled BN nanotubes. Excitonic effects are shown to be even more
important in BN nanotubes than in carbon nanotubes. Electron-hole interactions
give rise to complexes of bright (and dark) excitons, which qualitatively alter
the optical response. Excitons with binding energy larger than 2 eV are found
in the (8,0) BN nanotubes. Moreover, unlike the carbon nanotubes, theory
predicts that these exciton states are comprised of coherent supposition of
transitions from several different subband pairs, giving rise to novel
behaviors.Comment: 4 pages, 4 figure
A Particle-based Multiscale Solver for Compressible Liquid-Vapor Flow
To describe complex flow systems accurately, it is in many cases important to
account for the properties of fluid flows on a microscopic scale. In this work,
we focus on the description of liquid-vapor flow with a sharp interface between
the phases. The local phase dynamics at the interface can be interpreted as a
Riemann problem for which we develop a multiscale solver in the spirit of the
heterogeneous multiscale method, using a particle-based microscale model to
augment the macroscopic two-phase flow system. The application of a microscale
model makes it possible to use the intrinsic properties of the fluid at the
microscale, instead of formulating (ad-hoc) constitutive relations
GP attitudes and self-reported behaviour in primary care consultations for low back pain
Background. The implementation of guideline recommendations in primary care has become widespread. The treatment of low back pain (LBP) has followed suite. Research shows that the use of LBP guidelines is influenced by the believability of the underlying evidence, the GPs consultation style and uncertainties surrounding diagnosis and treatment
The role of social relationships and culture in the cognitive representation of emotions
Ministry of Education, Singapore under its Academic Research Funding Tier
Whispering gallery modes in open quantum billiards
The poles of the S-matrix and the wave functions of open 2D quantum billiards
with convex boundary of different shape are calculated by the method of complex
scaling. Two leads are attached to the cavities. The conductance of the
cavities is calculated at energies with one, two and three open channels in
each lead. Bands of overlapping resonance states appear which are localized
along the convex boundary of the cavities and contribute coherently to the
conductance. These bands correspond to the whispering gallery modes appearing
in the classical calculations.Comment: 9 pages, 3 figures in jpg and gif forma
Palladium-Catalyzed Allylic Substitution at Four-Membered-Ring Systems: Formation of η<sup>1</sup>-Allyl Complexes and Electrocyclic Ring Opening
Caught in the act: A series of unique η1-allyl palladium complexes of four-membered cyclic systems bearing ÎČ-hydrogens were prepared (see structure). Their unusual structure, reactivity, and unprecedented propensity for undergoing pericyclic reactions were uncovered
Increased Sensitivity to Possible Muonium to Antimuonium Conversion
A new experimental search for muonium-antimuonium conversion was conducted at
the Paul Scherrer Institute, Villigen, Switzerland. The preliminary analysis
yielded one event fulfilling all required criteria at an expected background of
1.7(2) events due to accidental coincidences. An upper limit for the conversion
probability in 0.1 T magnetic field is extracted as (90%
CL).Comment: 2 figure
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