Structure and Magnetic Properties of a 1D Alternating Cu(II) Monomer―Paddlewheel Chain

One-dimensional metal–organic coordination polymers make up a class of compounds with potential towards the development of practical, new magnetic materials. Herein, a rare example of an ABBABB coupled linear chain comprised of alternating dicopper(II) tetraacetate units bridged to copper(II) acetate monomer units via axial η2:η1:µ2 coordinated acetate is reported. Examination of the structure, determined by small molecule X-ray crystallography, shows that each Cu(II) ion is in a dx2–y2 magnetic ground state. Magnetic susceptibility and magnetization data were collected and, consistent with the structural interpretation, demonstrate that the Cu(II) dimer (paddlewheel) exhibits classic antiferromagnetic exchange, while the S = 1/2 Cu(II) monomer is uncompensated in the ground state (low temperature regime.) Data were therefore fitted to a modified Bleaney-Bowers model, and results were consistent with the only other reported chain in this class for which magnetic data are available

Modern technology within the Western theological imaginary

In this paper, I claim that modern technology possesses certain general ‘onto-formative’ characteristics that indicate that our contemporary technological condition now defies orthodox theoretical forms of comprehension. In the light of this claim, I will propose that any adequate conceptual understanding of modern technics requires a decisive shift of disciplinary register: specifically, towards theology and to the formation of new philosophical paradigms founded upon metaphysically-inspired interpretations of the ‘total significance’ of modern technics. Such theological conceptions, I will argue, emerge from a startling recognition of modern technics’ incipient association with the infinite, the transcendent as well as with its capacity to “bring new worlds into existence”. I attempt this, in the first instance, by drawing upon the work of two major thinkers who I believe paved the way towards just such a theological conception: Martin Heidegger and Ernst Jünger. In a non-standard interpretation of their respective philosophies of technology, I will go on to claim that these two thinkers should be viewed as attempting to find a way towards a “radically conservative” revalorisation of ancient theological truths that they believed could provide 20th century modernity with the philosophical groundwork for a new techno-political order that they posited in contrast to a dying Platonic Christian civilisation. For both of these thinkers a theological understanding of modern technics created the possibility of a new spiritual condition/zeitgeist where the very idea of modern technology is rearticulated as the focal point of a post-Platonic-Christian social imaginary that they believed to be revolutionary in its necessarily destructive relationship to extant historical worlds and their corresponding traditions. By these lights, I suggest, that modern social imaginary can only be con conceived within a new theological synthesis that transcends the Platonic/Christian dichotomy of techne and theoria - of the worker and the philosopher/ priest - in a way that allows for the poetic root of both to be revealed in its primal, world-constituting, form. I will conclude with a brief comparison between these ‘pagan’ conceptions of technology and contemporary Christian theological conceptions which have been acutely aware of the highly ambiguous position of modern technics within Christian metaphysical schemes and the need to reform these in the light the manifestly destructive potential of modern forms of technological innovation

Achievement Trends in Schools With School Administration Managers (SAMs)

Compares student achievement trends over two years in schools with school administration managers helping principals increase the time they spend on instruction and schools without SAMs. Explores links between principals' time and student performance

Development of a Consensus Statement for the Definition, Diagnosis, and Treatment of Acute Exacerbations of Idiopathic Pulmonary Fibrosis Using the Delphi Technique.

© 2015, The Author(s).Introduction: There is a lack of agreed and established guidelines for the treatment of acute exacerbations of idiopathic pulmonary fibrosis (AE-IPF). This reflects, in part, the limited evidence-base underpinning the management of AE-IPF. In the absence of high-quality evidence, the aim of this research was to develop a clinician-led consensus statement for the definition, diagnosis and treatment of AE-IPF. Methods: A literature review was conducted to obtain published material on the definition and treatment of AE-IPF. The results of this review were circulated to an online panel of clinicians for review. Statements were then shared with ten expert respiratory clinicians who regularly treat patients with IPF. A Delphi technique was then used to develop a consensus statement for the definition, diagnosis and treatment of AE-IPF. During the first round of review, clinicians rated the clarity of each statement, the extent to which the statement should be included and provided comments. In two subsequent rounds of review, clinicians were provided with the group median inclusion rating for each statement, and any revised wording of statements to aid clarity. Clinicians were asked to repeat the clarity and inclusion ratings for the revised statements. Results: The literature review, online panel discussion, and face-to-face meeting generated 65 statements covering the definition, diagnosis, and management of AE-IPF. Following three rounds of blind review, 90% of clinicians agreed 39 final statements. These final statements included a definition of AE-IPF, approach to diagnosis, and treatment options, specifically: supportive measures, use of anti-microbials, immunosuppressants, anti-coagulants, anti-fibrotic therapy, escalation, transplant management, and long-term management including discharge planning. Conclusion: This clinician-led consensus statement establishes the ‘best practice’ for the management and treatment of AE-IPF based on current knowledge, evidence, and available treatments. Funding: Boehringer Ingelheim Ltd., Bracknell, West Berkshire, UK

Effect of organic, low-input and conventional production systems on yield and diseases in winter barley

The effect of organic, low-input and conventional management practices on barley yield and disease incidence was assessed in field trials over two years. Conventional fertility management (based on mineral fertiliser applications) and conventional crop protection (based on chemosynthetic pesticides) significantly increased the yield of winter barley as compared to organic fertility and crop protection regimes. Severity of leaf blotch (Rhynchosporium secalis) was highest under organic fertility and crop protection management and was correlated inversely with yield. For mildew (Erysiphe graminis), an interaction between fertility management and crop protection was detected. Conventional crop protection reduced severity of the disease, only under conventional fertility management. Under organic fertility management, incidence of mildew was low and application of synthetic pesticides in “low input” production systems had no significant effect on disease severity

WFIRST Coronagraph Technology Requirements: Status Update and Systems Engineering Approach

The coronagraphic instrument (CGI) on the Wide-Field Infrared Survey Telescope (WFIRST) will demonstrate technologies and methods for high-contrast direct imaging and spectroscopy of exoplanet systems in reflected light, including polarimetry of circumstellar disks. The WFIRST management and CGI engineering and science investigation teams have developed requirements for the instrument, motivated by the objectives and technology development needs of potential future flagship exoplanet characterization missions such as the NASA Habitable Exoplanet Imaging Mission (HabEx) and the Large UV/Optical/IR Surveyor (LUVOIR). The requirements have been refined to support recommendations from the WFIRST Independent External Technical/Management/Cost Review (WIETR) that the WFIRST CGI be classified as a technology demonstration instrument instead of a science instrument. This paper provides a description of how the CGI requirements flow from the top of the overall WFIRST mission structure through the Level 2 requirements, where the focus here is on capturing the detailed context and rationales for the CGI Level 2 requirements. The WFIRST requirements flow starts with the top Program Level Requirements Appendix (PLRA), which contains both high-level mission objectives as well as the CGI-specific baseline technical and data requirements (BTR and BDR, respectively)... We also present the process and collaborative tools used in the L2 requirements development and management, including the collection and organization of science inputs, an open-source approach to managing the requirements database, and automating documentation. The tools created for the CGI L2 requirements have the potential to improve the design and planning of other projects, streamlining requirement management and maintenance. [Abstract Abbreviated]Comment: 16 pages, 4 figure