5,991 research outputs found

    Laser Raman and Infrared Spectra of Some Uracil Derivatives

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    Optical, Thermal and Topological Characterization of Quaternary Se65Ge15Te20-aSba Chalcogenide Glasses

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    Se-Te based chalcogenide glasses have been found suitable for optical memory devices due to their distinct amorphous-to-crystalline transformation. In the present work alloys of Se65Ge15Te20-aSba (a = 3, 6, 9, 12, 15, 18) glasses have been synthesized using melt quench technique. Author report investigations leading to optical, thermal and topological properties of these glasses by varying the concentrations of Te and Sb. Glass transition and crystallization kinetics of alloys have been investigated using differential thermal analysis at different heating rates (5, 10, 15, and 20 Kmin-1). The results so obtained verify the usefulness of above composition

    Transport properties of Layer-Antiferromagnet CuCrS2: A possible thermoelectric material

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    The electrical, thermal conductivity and Seebeck coefficient of the quenched, annealed and slowly cooled phases of the layer compound CuCrS2 have been reported between 15K to 300K. We also confirm the antiferromagnetic transition at 40K in them by our magnetic measurements between 2K and 300K. The crystal flakes show a minimum around 100K in their in-plane resistance behavior. For the polycrystalline pellets the resistivity depends on their flaky texture and it attains at most 10 to 20 times of the room temperature value at the lowest temperature of measurement. The temperature dependence is complex and no definite activation energy of electronic conduction can be discerned. We find that the Seebeck coefficient is between 200-450 microV/K and is unusually large for the observed resistivity values of between 5-100 mOhm-cm at room temperature. The figure of merit ZT for the thermoelectric application is 2.3 for our quenched phases, which is much larger than 1 for useful materials. The thermal conductivity K is mostly due to lattice conduction and is reduced by the disorder in Cu- occupancy in our quenched phase. A dramatic reduction of electrical and thermal conductivity is found as the antiferromagnetic transition is approached from the paramagnetic region, and K subsequently rises in the ordered phase. We discuss the transport properties as being similar to a doped Kondo-insulator

    Multi-band superconductivity and nanoscale inhomogeneity at oxide interfaces

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    The two-dimensional electron gas at the LaTiO3/SrTiO3 or LaAlO3/SrTiO3 oxide interfaces becomes superconducting when the carrier density is tuned by gating. The measured resistance and superfluid density reveal an inhomogeneous superconductivity resulting from percolation of filamentary structures of superconducting "puddles" with randomly distributed critical temperatures, embedded in a non-superconducting matrix. Following the evidence that superconductivity is related to the appearance of high-mobility carriers, we model intra-puddle superconductivity by a multi-band system within a weak coupling BCS scheme. The microscopic parameters, extracted by fitting the transport data with a percolative model, yield a consistent description of the dependence of the average intra-puddle critical temperature and superfluid density on the carrier density.Comment: 7 pages with 3 figures + supplemental material (4 pages and 5 figures

    Presence of glucose, xylose, and glycerol fermenting bacteria in the deep biosphere of the former Homestake gold mine, South Dakota

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    Eight fermentative bacterial strains were isolated from mixed enrichment cultures of a composite soil sample collected at 1.34 km depth from the former Homestake gold mine in Lead, SD, USA. Phylogenetic analysis of their 16S rRNA gene sequences revealed that these isolates were affiliated with the phylum Firmicutes belonging to genera Bacillus and Clostridium. Batch fermentation studies demonstrated that isolates had the ability to ferment glucose, xylose, or glycerol to industrially valuable products such as ethanol and 1,3-propanediol (PDO). Ethanol was detected as the major fermentation end product in glucose-fermenting cultures at pH 10 with yields of 0.205–0.304 g of ethanol/g of glucose. While a xylose-fermenting strain yielded 0.189 g of ethanol/g of xylose and 0.585 g of acetic acid/g of xylose at the end of fermentation. At pH 7, glycerol-fermenting isolates produced PDO (0.323–0.458 g of PDO/g of glycerol) and ethanol (0.284–0.350 g of ethanol/g of glycerol) as major end products while acetic acid and succinic acid were identified as minor by-products in fermentation broths. These results suggest that the deep biosphere of the former Homestake gold mine harbors bacterial strains which could be used in bio-based production of ethanol and PDO

    Transport and Magnetic Properties of FexVse2 (x = 0 - 0.33)

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    We present our results of the effect of Fe intercalation on the structural, transport and magnetic properties of 1T-VSe2. Intercalation of iron, suppresses the 110K charge density wave (CDW) transition of the 1T-VSe2. For the higher concentration of iron, formation of a new kind of first order transition at 160K takes place, which go on stronger for the 33% Fe intercalation. Thermopower of the FexVSe2 compounds (x = 0 - 0.33), however do not show any anomaly around the transition. The intercalation of Fe does not trigger any magnetism in the weak paramagnetic 1T-VSe2, and Fe is the low spin state of Fe3+.Comment: 7 pages, 8 figures, 2 table

    Agro-morphological and quality characterization of indigenous and exotic aromatic rice (Oryza sativa L.) germplasm

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    For establishment of the distinctness among 64 aromatic rice germplasm, 35 agro-morphological and quality traits were used. Most of the studied traits showed wide variation among the germplasm. Purple colour of auricles and ligule was found in only one genotype, while light purple colour of auricles was recorded in four genotypes. White colour of stigma was recorded in 57 accessions, whereas purple stigma was observed in six accessions. Awns present in 31 accessions. The weight of 1000 grains, which is one of the most important yield attributing traits showed wide variation among accessions, and ranges from very low to very high weight. Grain: length and decorticated grain: length showed high variation and ranges from very short to long type, while grain: width and decorticated grain: width showed somewhat little variation among the genotypes. Extra long slender type grain shape was observed in 27 accessions. White type of decorticated grain colour was found in 55 genotypes, while light red and red colour was observed in only three genotypes. The present study concluded that all sixty four accessions were found to be distinct on the basis of thirty one agro-morphological and quality traits. Accessions having short stem length, very long panicle length, more number of panicle per plant, and extra long slender grain may be used as potential donor in hybridization programmes. This study will be useful for breeders, researchers and farmers toidentify and choose the restoration and conservation of beneficial genes for crop improvement

    Spin-Glass Model for Inverse Freezing

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    We analyze the Blume-Emery-Griffiths model with disordered magnetic interaction displaying the inverse freezing phenomenon. The behaviour of this spin-1 model in crystal field is studied throughout the phase diagram and the transition and spinodal lines for the model are computed using the Full Replica Symmetry Breaking Ansatz that always yelds a thermodynamically stable phase. We compare the results both with the quenched disordered model with Ising spins on lattice gas - where no reentrance takes place - and with the model with generalized spin variables recently introduced by Schupper and Shnerb [Phys. Rev. Lett. 93, 037202 (2004)]. The simplest version of all these models, known as Ghatak-Sherrington model, turns out to hold all the general features characterizing an inverse transition to an amorphous phase, including the right thermodynamic behavior.Comment: 6 pages, 4 figures, to appear in the Proceeding for the X International Workshop on Disordered Systems (2006), Molveno, Ital

    Discrimination in the University in India

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    Despite changes to the status of women in India, the strong patriarchal traditions continue to shape the way that women take their place in Indian society. There are more opportunities for women in India today, inclusive of political, financial and working opportunities, but it is difficult not to notice that India is still a male dominated society
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