13 research outputs found
Quantum-dot thermometry
We present a method for the measurement of a temperature differential across
a single quantum dot that has transmission resonances that are separated in
energy by much more than the thermal energy. We determine numerically that the
method is accurate to within a few percent across a wide range of parameters.
The proposed method measures the temperature of the electrons that enter the
quantum dot and will be useful in experiments that aim to test theory which
predicts quantum dots are highly-efficient thermoelectrics.Comment: 3 pages, 4 Figure
Lineshape of the thermopower of quantum dots
Quantum dots are an important model system for thermoelectric phenomena, and
may be used to enhance the thermal-to-electric energy conversion efficiency in
functional materials. It is therefore important to obtain a detailed
understanding of a quantum-dot's thermopower as a function of the Fermi energy.
However, so far it has proven difficult to take effects of co-tunnelling into
account in the interpretation of experimental data. Here we show that a
single-electron tunnelling model, using knowledge of the dot's electrical
conductance which in fact includes all-order co-tunneling effects, predicts the
thermopower of quantum dots as a function of the relevant energy scales, in
very good agreement with experiment.Comment: 10 pages, 5 figure
A linear nonequilibrium thermodynamics approach to optimization of thermoelectric devices
Improvement of thermoelectric systems in terms of performance and range of
applications relies on progress in materials science and optimization of device
operation. In this chapter, we focuse on optimization by taking into account
the interaction of the system with its environment. For this purpose, we
consider the illustrative case of a thermoelectric generator coupled to two
temperature baths via heat exchangers characterized by a thermal resistance,
and we analyze its working conditions. Our main message is that both electrical
and thermal impedance matching conditions must be met for optimal device
performance. Our analysis is fundamentally based on linear nonequilibrium
thermodynamics using the force-flux formalism. An outlook on mesoscopic systems
is also given.Comment: Chapter 14 in "Thermoelectric Nanomaterials", Editors Kunihito
Koumoto and Takao Mori, Springer Series in Materials Science Volume 182
(2013
Determining a temperature differential across a quantum dot
We present a method for determining a temperature differential across a quantum dot. If the device has a transmission function with sufficiently spaced resonant energies, then one can distinguish electrons which have tunneled from the hot lead, and those which have tunneled from the cold lead. By measuring the thermocurrent as the electrochemical potential is swept through a resonant energy level, information about the transmission function obtained from conductance measurements can be used to deduce the temperature differential of the electron gas across the device. (C) 2007 Elsevier B.V. All rights reserved
Nonlinear thermovoltage and thermocurrent in quantum dots
Quantum dots are model systems for quantum thermoelectric behavior because of their ability to control and measure the effects of electron-energy filtering and quantum confinement on thermoelectric properties. Interestingly, nonlinear thermoelectric properties of such small systems can modify the efficiency of thermoelectric power conversion. Using quantum dots embedded in semiconductor nanowires, we measure thermovoltage and thermocurrent that are strongly nonlinear in the applied thermal bias. We show that most of the observed nonlinear effects can be understood in terms of a renormalization of the quantum-dot energy levels as a function of applied thermal bias and provide a theoretical model of the nonlinear thermovoltage taking renormalization into account. Furthermore, we propose a theory that explains a possible source of the observed, pronounced renormalization effect by the melting of Kondo correlations in the mixed-valence regime. The ability to control nonlinear thermoelectric behavior expands the range in which quantum thermoelectric effects may be used for efficient energy conversion