654 research outputs found
Quantum fluctuation induced ordered phase in the Blume-Capel model
We consider the Blume-Capel model with the quantum tunneling between the
excited states. We find a magnetically ordered phase transition induced by
quantum fluctuation in a model. The model has no phase transition in the
corresponding classical case. Usually, quantum fluctuation breaks ordered phase
as in the case of the transverse field Ising model. However, in present case,
an ordered phase is induced by quantum fluctuation. Moreover, we find a phase
transition between a quantum paramagnetic phase and a classical diamagnetic
phase at zero temperature. We study the properties of the phase transition by
using a mean field approximation (MFA), and then, by a quantum Monte Carlo
method to confirm the result of the MFA.Comment: 7 pages, 6 figures, corrected some typo
Ordered phase and phase transitions in the three-dimensional generalized six-state clock model
We study the three-dimensional generalized six-state clock model at values of
the energy parameters, at which the system is considered to have the same
behavior as the stacked triangular antiferromagnetic Ising model and the
three-state antiferromagnetic Potts model. First, we investigate ordered phases
by using the Monte Carlo twist method (MCTM). We confirmed the existence of an
incompletely ordered phase (IOP1) at intermediate temperature, besides the
completely ordered phase (COP) at low-temperature. In this intermediate phase,
two neighboring states of the six-state model mix, while one of them is
selected in the low temperature phase. We examine the fluctuation the mixing
rate of the two states in IOP1 and clarify that the mixing rate is very stable
around 1:1.
The high temperature phase transition is investigated by using
non-equilibrium relaxation method (NERM). We estimate the critical exponents
beta=0.34(1) and nu=0.66(4). These values are consistent with the 3D-XY
universality class. The low temperature phase transition is found to be of
first-order by using MCTM and the finite-size-scaling analysis
Development and Validation of a Specific Stability Indicating High Performance Liquid Chromatographic Method for Valsartan
A stability-indicating HPLC assay method has been developed and validated for valsartan in bulk drug and pharmaceutical dosage forms. An isocratic RP-HPLC was achieved on Waters 2695 using Symmetry C18 (250mm × 4.6mm × 5μ) column with the mobile phase consisting of 0.02 mM sodium dihydrogen ortho-phosphate, pH adjusted to 2.5 using ortho-phosphoric acid (solvent A), and acetonitrile (solvent B) in the ratio of 58:42 %v/v. The stress testing of valsartan was carried out under acidic, alkaline, oxidative, thermal, and photolytic conditions. Valsartan was well resolved from its degradation products. The proposed method was validated as per ICH guidelines. The method was found to be suitable for the quality control of valsartan in bulk and pharmaceutical dosage forms as well as the stability-indicating studies
A Theory of Ferroelectric Phase Transition in SrTiO induced by Isotope Replacement
A theory to describe the dielectric anomalies and the ferroelectric phase
transition induced by oxygen isotope replacement in SrTiO is developed. The
proposed model gives consistent explanation between apparently contradictory
experimental results on macroscopic dielectric measurements versus microscopic
lattice dynamical measurements by neutron scattering studies. The essential
feature is described by a 3-state quantum order-disorder system characterizing
the degenerated excited states in addition to the ground state of TiO
cluster. The effect of isotope replacement is taken into account through the
tunneling frequency between the excited states. The dielectric properties are
analyzed by the mean field approximation (MFA), which gives qualitative
agreements with experimental results throughout full range of the isotope
concentration.The phase diagram in the temperature-tunneling
frequencycoordinate is studied by a QMC method to confirm the qualitative
validity of the MFA analysis.Comment: 26 pages, 8 figure
Self-Diffusion of a Polymer Chain in a Melt
Self-diffusion of a polymer chain in a melt is studied by Monte Carlo
simulations of the bond fluctuation model, where only the excluded volume
interaction is taken into account. Polymer chains, each of which consists of
segments, are located on an simple cubic lattice
under periodic boundary conditions, where each segment occupies unit cells. The results for
and 512 at the volume fraction are reported, where
for and L=192 for . The -dependence of the
self-diffusion constant is examined. Here, is estimated from the mean
square displacements of the center of mass of a single polymer chain at the
times larger than the longest relaxation time. From the data for , 384
and 512, the apparent exponent , which describes the apparent power
law dependence of on as , is estimated as
. The ratio seems to be a
constant for and 512, where and
denote the longest relaxation time and the mean square end-to-end distance,
respectively.Comment: 4 pages, 3 figures, submitted to J. Phys. Soc. Jp
Superconductivity in the Ferroquadrupolar State in the Quadrupolar Kondo Lattice PrTiAl
The cubic compound PrTiAl is a quadrupolar Kondo lattice system
that exhibits quadrupolar ordering due to the non-Kramers ground
doublet and has strong hybridization between and conduction electrons. Our
study using high-purity single crystal reveals that PrTiAl exhibits
type-II superconductivity at mK in the nonmagnetic
ferroquadrupolar state. The superconducting critical temperature and field
phase diagram suggests moderately enhanced effective mass of
First Results from KamLAND: Evidence for Reactor Anti-Neutrino Disappearance
KamLAND has been used to measure the flux of 's from distant
nuclear reactors. In an exposure of 162 tonyr (145.1 days) the ratio of
the number of observed inverse -decay events to the expected number of
events without disappearance is for energies 3.4 MeV. The deficit of events is
inconsistent with the expected rate for standard propagation at
the 99.95% confidence level. In the context of two-flavor neutrino oscillations
with CPT invariance, these results exclude all oscillation solutions but the
`Large Mixing Angle' solution to the solar neutrino problem using reactor
sources.Comment: 6 pages, 6 figure
Search for the Invisible Decay of Neutrons with KamLAND
The Kamioka Liquid scintillator Anti-Neutrino Detector (KamLAND) is used in a
search for single neutron or two neutron intra-nuclear disappearance that would
produce holes in the -shell energy level of C nuclei. Such holes
could be created as a result of nucleon decay into invisible modes (),
e.g. or . The de-excitation of the corresponding
daughter nucleus results in a sequence of space and time correlated events
observable in the liquid scintillator detector. We report on new limits for
one- and two-neutron disappearance: years
and years at 90% CL. These results
represent an improvement of factors of 3 and over previous
experiments.Comment: 5 pages, 3 figure
Measurement of Neutrino Oscillation with KamLAND: Evidence of Spectral Distortion
We present results of a study of neutrino oscillation based on a 766 ton-year
exposure of KamLAND to reactor anti-neutrinos. We observe 258 \nuebar\
candidate events with energies above 3.4 MeV compared to 365.2 events expected
in the absence of neutrino oscillation. Accounting for 17.8 expected background
events, the statistical significance for reactor \nuebar disappearance is
99.998%. The observed energy spectrum disagrees with the expected spectral
shape in the absence of neutrino oscillation at 99.6% significance and prefers
the distortion expected from \nuebar oscillation effects. A two-neutrino
oscillation analysis of the KamLAND data gives \DeltaMSq =
7.9 eV. A global analysis of data from KamLAND
and solar neutrino experiments yields \DeltaMSq =
7.9 eV and \ThetaParam =
0.40, the most precise determination to date.Comment: 5 pages, 4 figures; submitted to Phys.Rev.Letter
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