5,627 research outputs found

    Strangeness in Compact Stars and Signal of Deconfinement

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    Phase transitions in compact stars are discussed including hyperonization, deconfinement and crystalline phases. Reasons why kaon condensation is unlikely is reviewed. Particular emphasis is placed on the evolution of internal structure with spin-down of pulsars. A signature of a first order phase transition in the timing structure of pulsars which is strong and easy to measure, is identified.Comment: 17 pages, 15 figures, Latex. (Invited Talk at the International Symposium on ``Strangeness In Quark Matter 1997'', Thera (Santorini), Hellas, April 14-18, 1997, To be published in Journal of Physics G (Organizers: A Panagiotou and J. Madsen

    Adsorption of cobalt on graphene: Electron correlation effects from a quantum chemical perspective

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    In this work, we investigate the adsorption of a single cobalt atom (Co) on graphene by means of the complete active space self-consistent field approach, additionally corrected by the second-order perturbation theory. The local structure of graphene is modeled by a planar hydrocarbon cluster (C24_{24}H12_{12}). Systematic treatment of the electron correlations and the possibility to study excited states allow us to reproduce the potential energy curves for different electronic configurations of Co. We find that upon approaching the surface, the ground-state configuration of Co undergoes several transitions, giving rise to two stable states. The first corresponds to the physisorption of the adatom in the high-spin 3d74s23d^74s^2 (S=3/2S=3/2) configuration, while the second results from the chemical bonding formed by strong orbital hybridization, leading to the low-spin 3d93d^9 (S=1/2S=1/2) state. Due to the instability of the 3d93d^9 configuration, the adsorption energy of Co is small in both cases and does not exceed 0.35 eV. We analyze the obtained results in terms of a simple model Hamiltonian that involves Coulomb repulsion (UU) and exchange coupling (JJ) parameters for the 3dd shell of Co, which we estimate from first-principles calculations. We show that while the exchange interaction remains constant upon adsorption (≃1.1\simeq1.1 eV), the Coulomb repulsion significantly reduces for decreasing distances (from 5.3 to 2.6±\pm0.2 eV). The screening of UU favors higher occupations of the 3dd shell and thus is largely responsible for the interconfigurational transitions of Co. Finally, we discuss the limitations of the approaches that are based on density functional theory with respect to transition metal atoms on graphene, and we conclude that a proper account of the electron correlations is crucial for the description of adsorption in such systems.Comment: 12 pages, 6 figures, 2 table

    Interfacial interactions between local defects in amorphous SiO2_2 and supported graphene

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    We present a density functional study of graphene adhesion on a realistic SiO2_2 surface taking into account van der Waals (vdW) interactions. The SiO2_2 substrate is modeled at the local scale by using two main types of surface defects, typical for amorphous silica: the oxygen dangling bond and three-coordinated silicon. The results show that the nature of adhesion between graphene and its substrate is qualitatively dependent on the surface defect type. In particular, the interaction between graphene and silicon-terminated SiO2_2 originates exclusively from the vdW interaction, whereas the oxygen-terminated surface provides additional ionic contribution to the binding arising from interfacial charge transfer (pp-type doping of graphene). Strong doping contrast for the different surface terminations provides a mechanism for the charge inhomogeneity of graphene on amorphous SiO2_2 observed in experiments. We found that independent of the considered surface morphologies, the typical electronic structure of graphene in the vicinity of the Dirac point remains unaltered in contact with the SiO2_2 substrate, which points to the absence of the covalent interactions between graphene and amorphous silica. The case of hydrogen-passivated SiO2_2 surfaces is also examined. In this situation, the binding with graphene is practically independent of the type of surface defects and arises, as expected, from the vdW interactions. Finally, the interface distances obtained are shown to be in good agreement with recent experimental studies.Comment: 10 pages, 4 figure

    Graphene adhesion on mica: Role of surface morphology

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    We investigate theoretically the adhesion and electronic properties of graphene on a muscovite mica surface using the density functional theory (DFT) with van der Waals (vdW) interactions taken into account (the vdW-DF approach). We found that irregularities in the local structure of cleaved mica surface provide different mechanisms for the mica-graphene binding. By assuming electroneutrality for both surfaces, the binding is mainly of vdW nature, barely exceeding thermal energy per carbon atom at room temperature. In contrast, if potassium atoms are non uniformly distributed on mica, the different regions of the surface give rise to nn- or pp-type doping of graphene. In turn, an additional interaction arises between the surfaces, significantly increasing the adhesion. For each case the electronic states of graphene remain unaltered by the adhesion. It is expected, however, that the Fermi level of graphene supported on realistic mica could be shifted relative to the Dirac point due to asymmetry in the charge doping. Obtained variations of the distance between graphene and mica for different regions of the surface are found to be consistent with recent atomic force microscopy experiments. A relative flatness of mica and the absence of interlayer covalent bonding in the mica-graphene system make this pair a promising candidate for practical use.Comment: 6 pages, 3 figure

    Adsorption of diatomic halogen molecules on graphene: A van der Waals density functional study

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    The adsorption of fluorine, chlorine, bromine, and iodine diatomic molecules on graphene has been investigated using density functional theory with taking into account nonlocal correlation effects by means of vdW-DF approach. It is shown that the van der Waals interaction plays a crucial role in the formation of chemical bonding between graphene and halogen molecules, and is therefore important for a proper description of adsorption in this system. In-plane orientation of the molecules has been found to be more stable than the orientation perpendicular to the graphene layer. In the cases of F2_2, Br2_2 and I2_2 we also found an ionic contribution to the binding energy, slowly vanishing with distance. Analysis of the electronic structure shows that ionic interaction arises due to the charge transfer from graphene to the molecules. Furthermore, we found that the increase of impurity concentration leads to the conduction band formation in graphene due to interaction between halogen molecules. In addition, graphite intercalation by halogen molecules has been investigated. In the presence of halogen molecules the binding between graphite layers becomes significantly weaker, which is in accordance with the results of recent experiments on sonochemical exfoliation of intercalated graphite.Comment: Submitted to PR

    Deconfinement transition in protoneutron stars: analysis within the Nambu-Jona-Lasinio model

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    We study the effect of color superconductivity and neutrino trapping on the deconfinement transition of hadronic matter into quark matter in a protoneutron star. To describe the strongly interacting matter a two-phase picture is adopted. For the hadronic phase we use different parameterizations of a non-linear Walecka model which includes the whole baryon octet. For the quark matter phase we use an SU(3)fSU(3)_f Nambu-Jona-Lasinio effective model which includes color superconductivity. We impose color and flavor conservation during the transition in such a way that just deconfined quark matter is transitorily out of equilibrium with respect to weak interactions. We find that deconfinement is more difficult for small neutrino content and it is easier for lower temperatures although these effects are not too large. In addition they will tend to cancel each other as the protoneutron star cools and deleptonizes, resulting a transition density that is roughly constant along the evolution of the protoneutron star. According to these results the deconfinement transition is favored after substantial cooling and contraction of the protoneutron star

    XMM-Newton observation of the ULIRG NGC 6240: The physical nature of the complex Fe K line emission

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    We report on an XMM-Newton observation of the ultraluminous infrared galaxy NGC 6240. The 0.3-10 keV spectrum can be successfully modelled with: (i) three collisionally ionized plasma components with temperatures of about 0.7, 1.4, and 5.5 keV; (ii) a highly absorbed direct power-law component; and (iii) a neutral Fe K_alpha and K_beta line. We detect a significant neutral column density gradient which is correlated with the temperature of the three plasma components. Combining the XMM-Newton spectral model with the high spatial resolution Chandra image we find that the temperatures and the column densities increase towards the center. With high significance, the Fe K line complex is resolved into three distinct narrow lines: (i) the neutral Fe K_alpha line at 6.4 keV; (ii) an ionized line at about 6.7 keV; and (iii) a higher ionized line at 7.0 keV (a blend of the Fe XXVI and the Fe K_beta line). While the neutral Fe K line is most probably due to reflection from optically thick material, the Fe XXV and Fe XXVI emission arises from the highest temperature ionized plasma component. We have compared the plasma parameters of the ultraluminous infrared galaxy NGC 6240 with those found in the local starburst galaxy NGC 253. We find a striking similarity in the plasma temperatures and column density gradients, suggesting a similar underlying physical process at work in both galaxies.Comment: 8 pages including 9 figures. Accepted for publication in A&

    Characterization and Modeling of Non-Uniform Charge Collection in CVD Diamond Pixel Detectors

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    A pixel detector with a CVD diamond sensor has been studied in a 180 GeV/c pion beam. The charge collection properties of the diamond sensor were studied as a function of the track position, which was measured with a silicon microstrip telescope. Non-uniformities were observed on a length scale comparable to the diamond crystallites size. In some regions of the sensor, the charge drift appears to have a component parallel to the sensor surface (i.e., normal to the applied electric field) resulting in systematic residuals between the track position and the hits position as large as 40 Ό\mum. A numerical simulation of the charge drift in polycrystalline diamond was developed to compute the signal induced on the electrodes by the electrons and holes released by the passing particles. The simulation takes into account the crystallite structure, non-uniform trapping across the sensor, diffusion and polarization effects. It is in qualitative agreement with the data. Additional lateral electric field components result from the non-uniform trapping of charges in the bulk. These provide a good explanation for the large residuals observed.Comment: Accepted by Nucl. Instr. and Met

    Direct Urca neutrino rate in colour superconducting quark matter

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    If deconfined quark matter exists inside compact stars, the primary cooling mechanism is neutrino radiation via the direct Urca processes d->u+e+antinu_e and u+e->d+nu_e. Below a critical temperature, T_c, quark matter forms a colour superconductor, one possible manifestation of which is a condensate of quark Cooper pairs in an electric-charge neutralising background of electrons. We compute the neutrino emission rate from such a phase, including charged pair-breaking and recombination effects, and find that on a material temperature domain below T_c the pairing-induced suppression of the neutrino emission rate is not uniformly exponential. If gapless modes are present in the condensed phase, the emissivity at low temperatures is moderately enhanced above that of completely unpaired matter. The importance of charged current pair-breaking processes for neutrino emission both in the fully gapped and partially gapped regimes is emphasised.Comment: 5 pages, 2 figures; to appear in Phys. Rev. C (Rapid Comm.
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