Characterization of High Oleic Acid Biodiesel: Improving Biofuel Properties

In 2016, the world produced an amount of biofuel equivalent to 82,306,000 tonnes of oil. A portion of the biofuels produced was categorized as biodiesel. While still growing as a fuel alternative, current biodiesel fuels are at risk for causing increased engine coking, lower engine performance and durability, oil ring sticking, carbon deposits, and gelling of lubricating oil. Due to these primary issues, biodiesel cannot completely replace petroleum diesel as a fuel source. Instead, biodiesel is commonly blended with petroleum diesel at 5% and 20% (B5 and B20) in the U.S. to create a mixture that has acceptable fuel properties. Recently, genetic modifications to soybeans have made high oleic acid soybean oil commercially available. High oleic acid soybean oil has less saturated fat and more monounsaturated fat. This characteristic is hypothesized to improve the fuel properties of biodiesel. These improvements may enable better fuel performance such that higher blends of biodiesel could be used in combustion engines around the world. The research conducted in this study aimed to test the kinematic viscosity, density, flash point, cloud point, and acid number of transesterified high oleic acid soybean oil in order to have a proof of concept that high oleic acid biodiesel meets standard specifications. High oleic acid biodiesel was found to have a kinematic viscosity of 4.639 mm^2/s, a density of 0.8789 g/cm^3, a flash point \u3e110 degrees Celsius, a cloud point of -1 degree Celsius, and an acid number of 0.071 mg KOH/g which meets every ASTM standard specification range

Nonextensive diffusion as nonlinear response

The porous media equation has been proposed as a phenomenological ``non-extensive'' generalization of classical diffusion. Here, we show that a very similar equation can be derived, in a systematic manner, for a classical fluid by assuming nonlinear response, i.e. that the diffusive flux depends on gradients of a power of the concentration. The present equation distinguishes from the porous media equation in that it describes \emph{% generalized classical} diffusion, i.e. with $r/\sqrt Dt$ scaling, but with a generalized Einstein relation, and with power-law probability distributions typical of nonextensive statistical mechanics

Moving boundary approximation for curved streamer ionization fronts: Solvability analysis

The minimal density model for negative streamer ionization fronts is investigated. An earlier moving boundary approximation for this model consisted of a "kinetic undercooling" type boundary condition in a Laplacian growth problem of Hele-Shaw type. Here we derive a curvature correction to the moving boundary approximation that resembles surface tension. The calculation is based on solvability analysis with unconventional features, namely, there are three relevant zero modes of the adjoint operator, one of them diverging; furthermore, the inner/outer matching ahead of the front has to be performed on a line rather than on an extended region; and the whole calculation can be performed analytically. The analysis reveals a relation between the fields ahead and behind a slowly evolving curved front, the curvature and the generated conductivity. This relation forces us to give up the ideal conductivity approximation, and we suggest to replace it by a constant conductivity approximation. This implies that the electric potential in the streamer interior is no longer constant but solves a Laplace equation; this leads to a Muskat-type problem.Comment: 22 pages, 6 figure

Thermostatistics of overdamped motion of interacting particles

We show through a nonlinear Fokker-Planck formalism, and confirm by molecular dynamics simulations, that the overdamped motion of interacting particles at T=0, where T is the temperature of a thermal bath connected to the system, can be directly associated with Tsallis thermostatistics. For sufficiently high values of T, the distribution of particles becomes Gaussian, so that the classical Boltzmann-Gibbs behavior is recovered. For intermediate temperatures of the thermal bath, the system displays a mixed behavior that follows a novel type of thermostatistics, where the entropy is given by a linear combination of Tsallis and Boltzmann-Gibbs entropies.Comment: 4 pages, 2 figure

Consequences of the H-Theorem from Nonlinear Fokker-Planck Equations

A general type of nonlinear Fokker-Planck equation is derived directly from a master equation, by introducing generalized transition rates. The H-theorem is demonstrated for systems that follow those classes of nonlinear Fokker-Planck equations, in the presence of an external potential. For that, a relation involving terms of Fokker-Planck equations and general entropic forms is proposed. It is shown that, at equilibrium, this relation is equivalent to the maximum-entropy principle. Families of Fokker-Planck equations may be related to a single type of entropy, and so, the correspondence between well-known entropic forms and their associated Fokker-Planck equations is explored. It is shown that the Boltzmann-Gibbs entropy, apart from its connection with the standard -- linear Fokker-Planck equation -- may be also related to a family of nonlinear Fokker-Planck equations.Comment: 19 pages, no figure

Logarithmic diffusion and porous media equations: a unified description

In this work we present the logarithmic diffusion equation as a limit case when the index that characterizes a nonlinear Fokker-Planck equation, in its diffusive term, goes to zero. A linear drift and a source term are considered in this equation. Its solution has a lorentzian form, consequently this equation characterizes a super diffusion like a L\'evy kind. In addition is obtained an equation that unifies the porous media and the logarithmic diffusion equations, including a generalized diffusion equation in fractal dimension. This unification is performed in the nonextensive thermostatistics context and increases the possibilities about the description of anomalous diffusive processes.Comment: 5 pages. To appear in Phys. Rev.

Generalized Diffusion

The Fokker-Planck equation for the probability $f(r,t)$ to find a random walker at position $r$ at time $t$ is derived for the case that the the probability to make jumps depends nonlinearly on $f(r,t)$. The result is a generalized form of the classical Fokker-Planck equation where the effects of drift, due to a violation of detailed balance, and of external fields are also considered. It is shown that in the absence of drift and external fields a scaling solution, describing anomalous diffusion, is only possible if the nonlinearity in the jump probability is of the power law type ($\sim f^{\eta }(r,t)$), in which case the generalized Fokker-Planck equation reduces to the well-known Porous Media equation. Monte-Carlo simulations are shown to confirm the theoretical results.Comment: 29 pages, 8 figure

Scaling dependence on the fluid viscosity ratio in the selective withdrawal transition

In the selective withdrawal experiment fluid is withdrawn through a tube with its tip suspended a distance S above a two-fluid interface. At sufficiently low withdrawal rates, Q, the interface forms a steady state hump and only the upper fluid is withdrawn. When Q is increased (or S decreased), the interface undergoes a transition so that the lower fluid is entrained with the upper one, forming a thin steady-state spout. Near this transition the hump curvature becomes very large and displays power-law scaling behavior. This scaling allows for steady-state hump profiles at different flow rates and tube heights to be scaled onto a single similarity profile. I show that the scaling behavior is independent of the viscosity ratio.Comment: 33 Pages, 61 figures, 1 tabl

Fluid Flows of Mixed Regimes in Porous Media

In porous media, there are three known regimes of fluid flows, namely, pre-Darcy, Darcy and post-Darcy. Because of their different natures, these are usually treated separately in literature. To study complex flows when all three regimes may be present in different portions of a same domain, we use a single equation of motion to unify them. Several scenarios and models are then considered for slightly compressible fluids. A nonlinear parabolic equation for the pressure is derived, which is degenerate when the pressure gradient is either small or large. We estimate the pressure and its gradient for all time in terms of initial and boundary data. We also obtain their particular bounds for large time which depend on the asymptotic behavior of the boundary data but not on the initial one. Moreover, the continuous dependence of the solutions on initial and boundary data, and the structural stability for the equation are established.Comment: 33 page

Absence of squirt singularities for the multi-phase Muskat problem

In this paper we study the evolution of multiple fluids with different constant densities in porous media. This physical scenario is known as the Muskat and the (multi-phase) Hele-Shaw problems. In this context we prove that the fluids do not develop squirt singularities.Comment: 16 page