The Theoretical Description for Chlorantraniliprole Electrochemical Determination, Assisted by Squaraine Dye – Nano-CuS Composite

The theoretical description for the chlorantraniliprole electrochemical determination, assisted by the hybrid composite of squaraine dye with CuS nanoparticles has been described. The correspondent reaction mechanism has been proposed, and the correspondent mathematical model has been developed and analyzed by means of linear stability theory and bifurcation analysis. It has been shown that the chlorantraniprole electrochemical anodical determination on high potential may be efficiently provided by cupper sulfide nanoparticles, stabilized by the squaraine dye. On the other hand, the oscillatory and monotonic instability is also possible, being caused by DEL influences of the electrochemical stage. DOI: http://dx.doi.org/10.17807/orbital.v13i3.151

The Theoretical Description for Magnesium Chlorate Electrochemical Determination on a Magnezone-XC Modified Electrode

An interesting electroanalytical process for magnesium chlorate electrochemical determination has been described theoretically. The process involves the complex formation of magnesium cation with the azo dye Magnezone XC and the electropolymerization of the resulting complex compound in the presence of the chlorate-ion by two parallel mechanisms. The correspondent mathematical model has been developed and analyzed by means of linear stability theory and bifurcation analysis. It has been shown that from both electroanalytical and electrosynthetical points of view the system is efficient. The linear dependence between the electrochemical parameter and salt concentration is obtained easily, and the material formed during the electroanalytical process is highly conductive and catalytic. On the other hand, the oscillatory behavior in this system will be caused by double electric layer influences on both complexation and electropolymerization stages. DOI: http://dx.doi.org/10.17807/orbital.v12i4.1534</p

THE THEORETICAL EVALUATION FOR THE ASSISTED ELECTROPOLYMERIZATION OF A MONOMER, OBTAINED BY AN INDIRECT ELECTROCHEMICAL SYNTHESIS

In this work, the possibility for indirect electropolymerization of a monomer, synthetized by an indirect electrosynthesis, has been evaluated. The correspondent mathematical model, based on the reaction mechanism, has been developed and analyzed by means of linear stability theory and bifurcation analysis. It has been shown that in the case of indirect monomer electrosynthesis and electropolymerization, the polymer deposition is far more stable than for direct participation of the monomer in the electrochemical stage. The surface tends to be more developed. Yet the electrochemical oscillations are expected to be less probable than in the case of the direct anodic process

The Theoretical Description for Fluoxetine Electrochemical Determination, Assisted by CoO(OH)-Nanoparticles, Deposited Over the Squaraine Dye

The theoretical description of the fluoxetine electrochemical determination over a CoO(OH) – Squaraine Dye composite has been carried out in this work. The correspondent mathematical model has been developed and analyzed by means of the linear stability theory and bifurcation analysis. It has been shown that the cobalt(III) oxyhydroxide, stabilized by squaraine dye layer, may be efficient electrode modifier for fluoxetine electrochemical determination. The possibility for the oscillatory and monotonic instabilities has also been verified. DOI: http://dx.doi.org/10.17807/orbital.v13i1.1573</p