Síntese de fotoprotetores e sua imobilização em poli(metacrilato de metilo): um projeto integrado de química orgânica, química de polímeros e fotoquímica Sunscreen synthesis and their immobilisition on polymethylmethacrylate: an integrated project in organic chemistry, polymer chemistry and photochemistry

<abstract language="eng">Dibenzalacetone and other aldol condensation products are known sunscreens commonly used in cosmetics. This type of compounds can easily be prepared in an Organic Chemistry Lab by reaction of aldehydes with ketones in basic medium. These compounds can be incorporated in poly(methyl methacrylate) and used as UV light absorbers, for example in sunglasses. This project has the advantage of using inexpensive reagents which are readily available in Chemistry Laboratories. This experiment can also be a base starting point for discussions of organic, polymer and photochemistry topics

Triazine-Based Porous Organic Polymers: Synthesis and Application in Dye Adsorption and Catalysis

The scientific community has been developing promising materials to increase the sustainability and efficiency of production processes and pollutant environmental remediation strategies. Porous organic polymers (POPs) are of special interest, as they are insoluble custom-built materials at the molecular level, endowed with low densities and high stability, surface areas, and porosity. This paper describes the synthesis, characterization, and performance of three triazine-based POPs (T-POPs) in dye adsorption and Henry reaction catalysis. T-POPs were prepared by a polycondensation reaction between melamine and a dialdehyde (terephthalaldehyde (T-POP1) or isophthalaldehyde derivatives with a hydroxyl group (T-POP2) or both a hydroxyl and a carboxyl group (T-POP3)). The crosslinked and mesoporous polyaminal structures, with surface areas between 139.2 and 287.4 m2 g-1, positive charge, and high thermal stability, proved to be excellent methyl orange adsorbents, removing the anionic dye with an efficiency >99% in just 15-20 min. The POPs were also effective for methylene blue cationic dye removal from water, reaching efficiencies up to ca. 99.4%, possibly due to favorable interactions via deprotonation of T-POP3 carboxyl groups. The modification of the most basic polymers, T-POP1 and T-POP2, with copper(II) allowed the best efficiencies in Henry reactions catalysis, leading to excellent conversions (97%) and selectivities (99.9%)

Reduced Chitosan as a Strategy for Removing Copper Ions from Water

Toxic heavy metals are priority pollutants in wastewater, commonly present in dangerous concentrations in many places across the globe. Although in trace quantities copper is a heavy metal essential to human life, in excess it causes various diseases, whereby its removal from wastewater is a necessity. Among several reported materials, chitosan is a highly abundant, non-toxic, low-cost, biodegradable polymer, comprising free hydroxyl and amino groups, that has been directly applied as an adsorbent or chemically modified to increase its performance. Taking this into account, reduced chitosan derivatives (RCDs 1-4) were synthesised by chitosan modification with salicylaldehyde, followed by imine reduction, characterised by RMN, FTIR-ATR, TGA and SEM, and used to adsorb Cu(II) from water. A reduced chitosan (RCD3), with a moderate modification percentage (43%) and a high imine reduction percentage (98%), proved to be more efficient than the remainder RCDs and even chitosan, especially at low concentrations under the best adsorption conditions (pH 4, RS/L = 2.5 mg mL-1). RCD3 adsorption data were better described by the Langmuir-Freundlich isotherm and the pseudo-second-order kinetic models. The interaction mechanism was assessed by molecular dynamics simulations, showing that RCDs favour Cu(II) capture from water compared to chitosan, due to a greater Cu(II) interaction with the oxygen of the glucosamine ring and the neighbouring hydroxyl groups